共查询到20条相似文献,搜索用时 296 毫秒
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介电弥散和介电隔离率的温度非线性关系是弛豫铁电体的主要特征. 通过对掺杂成分以线性梯度递减的核壳结构进行热力学函数分析, 认为核壳结构能够在低温区保持较高的介电常数, 但不能导致介电隔离率与温度的非线性关系. 通过对不同浓度掺杂的铁电体扩散相变的比较, 认为掺杂浓度会影响晶粒掺杂成分的不均匀性, 在较宽的分布条件下会导致介电隔离率与温度的非线性关系. 因而在介电常数的峰值温度区域, 顺电相与铁电相的晶粒共存. 温度变化会影响两相比例及铁电畴的变化, 从而导致弛豫铁电体的介电弥散性. 核壳结构会增大介电弥散性. 铁电陶瓷的掺杂物种类、掺杂物浓度和烧结温度均会影响核壳结构的成分不均匀性和介电弥散性. 相似文献
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《化学物理学报》2018,(3)
本文基于第一性原理中的Heyd-Scuseria-Ernzerh方法研究了单层In_(1-x)Ga_xN的电子结构和光学性质.计算得到单层In_(1-x)Ga_xN的能带结构和态密度(DOS),发现随着掺杂比例的变化,体系带隙的变化范围是1.8~3.8 eV,表明通过Ga的掺杂可以实现体系带隙值的调节.并且还研究了单层In_(1-x)Ga_xN的介电函数,折射率和吸收系数等光学性质,结果表明随着Ga掺杂浓度的增加,介电函数谱的主峰和吸收谱发生了显著的蓝移.此外,基于能带结构和态密度图谱,对单层In_(1-x)Ga_xN的光学性质进行分析,预测这种材料独特的光学性质在纳米电子学和光学器件中会有广泛的应用. 相似文献
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关于非吸收晶体介电张量的对称性在. 朗道和E.M.栗弗席兹合著的《连续媒质电动力学》中已有严格的证明.因其牵涉的物理基础较多,在光学仪器专业“波动光学”课程中讲授“晶体光学”时不易采用.在M.Born和E.Wolf合著的《Principle of Optics》中,在假定了电能密度和磁能密度表达形式、以及保留了坡印廷矢量定义的前提下,证明了非吸收晶体介电张量的对称性.本文仅在保留坡印廷矢量定义的前提下,就这个问题给出适合本专业学生物理基础的证明. 根据能量守恒原理,在不导电媒质中,当不做机械功时,单位时间内电磁场能量密度W的增量应等于电磁… 相似文献
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掺Ge锐钛矿相TiO_2光学性质的计算 总被引:1,自引:1,他引:0
合理的掺杂是改善TiO_2活性,使其光催化性能在可见光照射下发挥作用的最有效途径之一,本文利用基于密度泛函理论的第一原理全电势线性缀加平面波方法计算掺Ge锐钛矿相TiO_2介电函数的实部、虚部和光学吸收系数.计算结果显示掺Ge锐钛矿相TiO_2介电函数虚部谱发生蓝移,与实验趋势相符;通过不用剪刀算符和固定晶格常数两方案研究掺Ge前后光谱的平移,得到蓝移是由于Ge原子替代Ti原子后晶胞体积减小造成. 相似文献
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基于密度泛函理论的第一性原理研究Fe,Ni单掺杂和(Fe,Ni)共掺杂纤锌矿型ZnO的能带结构、电子态密度分布、介电函数、光学吸收系数,分析了掺杂后电子结构与光学性质的变化.计算结果表明:掺杂体系的费米能级附近电子态密度主要来源于Fe 3d,Ni 3d态电子的贡献;与纯净ZnO相比,Fe,Ni单掺杂和(Fe,Ni)共掺杂ZnO的介电函数虚部均在0.46eV左右出现了一个新峰;Fe,Ni单掺杂和共掺杂ZnO的吸收光谱均发生明显的红移,并都在1.3eV处出现较强吸收峰.结合他人的计算和实验结果,给出了定性的讨
关键词:
氧化锌
掺杂
第一性原理
光学性质 相似文献
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邹江 《原子与分子物理学报》2020,37(4)
采用基于密度泛函理论的第一性原理计算方法,对未掺杂及La掺杂4H-SiC的电子结构和光学性质进行理论计算。计算结果表明,未掺杂4C-SiC其禁带宽度为2.257 eV。La掺杂后带隙宽度下降为1.1143eV,导带最低点为G点,价带最高点为F点,是P型间接半导体。掺杂La原子在价带的低能区间贡献比较大,而对价带的高能区和导带的贡献比较小。未掺杂4H-SiC在光子能量为6.25 eV时,出现一个介电峰,这是由于价带电子向导带电子跃迁产生。而La掺杂后,出现3个介电峰,分别对应的光子能量为0.47eV、2.67eV、6.21eV,前两个介电峰是由于价带电子向杂质能级跃迁产生,第三个介电峰是由于价带电子向导带电子跃迁产生。La掺杂后4H-SiC变成负介电半导体材料。未掺杂4h-SiC的静态介电常数为2.01,La掺杂的静态常数为12.01。 相似文献
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D. Knabben N. Weber B. Raab Th. Koop F.U. Hillebrecht E. Kisker G.Y. Guo 《Journal of magnetism and magnetic materials》1998,190(3):1184
The transverse magneto-optical Kerr effect (T-MOKE) was investigated for thin epitaxial Fe films grown on Ag(0 0 1) in the region of the 2p excitation threshold. The experimental reflectivity and asymmetry spectra are compared to those derived from the complex dielectric function tensor calculated by using the first-principles spin-polarized relativistic band theory. We found that the T-MOKE asymmetry in general is a mixture of both the real and imaginary parts of the off-diagonal element of the dielectric function tensor, depending sensitively on the relative magnitudes of real and imaginary parts of the diagonal element. For angles of incidence larger than about 5° the influence of the Ag-substrate is significant. The major features in experimental and calculated reflectivity and asymmetry spectra are in agreement. 相似文献
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The subwavelength tuned magneto-optical Kerr effect in L1_0-FePt films with perpendicular magnetic anisotropy 下载免费PDF全文
For L10-FePt films with strong perpendicular anisotropy covered by arrays of hexagonal close-packed polystyrene spheres(PSSs),fine structures are observed in magneto-optical Kerr rotation spectra in the visible spectral range.The reflection minima are found to be located at the same wavelengths as the Kerr rotation peaks.The Kerr rotation enhancement is attributed to the excitation of both the surface plasmon polariton in the dielectric PSS/metal interface and the guide waves(guide mode)in the PSS array.The two-dimensional PSSs/SiO2/FePt system exhibiting a tunable magneto-optical Kerr effect and a high perpendicular magnetic anisotropy will be helpful for designing and fabricating magneto-optics devices. 相似文献
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N. Richard 《The European Physical Journal B - Condensed Matter and Complex Systems》2000,16(3):411-422
This paper describes the magneto-optical effects and the reflectivity behaviors of bilayers based on magnetic and isotropic
()/anisotropic () layers under the condition of total internal reflection. In the framework of Green's dyadic technique, we show accurately
the optical properties of anisotropic layers deposited on a substrate. We present numerical simulations which account for
the variation of angle of incidence at the HeNe laser wavelength. The Kerr rotation is found to increase significantly around
the optical modes in total reflection. We also discuss the importance of anisotropic effects due to the crystallization of
the dielectric material () which occur in the reflectivity and Kerr rotation spectra.
Received 26 January 2000 相似文献
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The contour integration technique applied to calculate the optical conductivity tensor at finite temperatures in the case of inhomogeneous surface layered systems within the framework of the spin-polarized relativistic screened Korringa-Kohn-Rostoker band structure method is extended to arbitrary polarizations of the electric field. It is shown that besides the inter-band contribution, the contour integration technique also accounts for the intra-band contribution. Introducing a layer-resolved complex Kerr angle, the importance of the first, non-magnetic buffer layer below the ferromagnetic surface on the magneto-optical Kerr effect in the Co | Pt m multilayer system is shown. Increasing the thickness of the buffer Pt, the layer-resolved complex Kerr angles follow a linear dependence with respect to m only after nine Pt mono-layers. 相似文献
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Both experimental and computer-simulated magneto-optical (MO) and optical spectroscopies of Co/Pt multilayered films (MLF) with a nearly constant Pt sublayer thickness and variable Co sublayer thickness, as well as pure Co and Pt, and Co0.51Pt0.49 alloy films, have been performed in the energy range 1.1–4.7 eV. The simulations were achieved by solving the multireflection task for various models of the MLF. The comparison between experimental and computer-simulated optical properties of the Co/Pt MLF allowed us to evaluate the thickness of the interfacial regions with the alloyed components. The diagonal and off-diagonal components of the optical conductivity tensor were calculated not only for the pure Co and Co0.51Pt0.49 alloy films, and the whole Co/Pt MLF, but also for the spin-polarized Pt layers in the Co/Pt MLF. 相似文献
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Kerr activity is observed in pure Ag films in the vicinity of the plasma resonance (3.85 eV) when subjected to a strong external magnetic field. This inherent magneto-optical behaviour of Ag in a narrow wavelength range (0.12 eV) around the plasma resonance is explained utilizing the classical Lorentz-Drude model for the off-diagonal elements of the dielectric function. This activity is a consequence of a combined effect of the weakly damped free electron system and the sharp onset ofd-band transitions. The possibility of enhancing the Kerr activity of amorphous TbFeCo alloys by Ag overlayers is also investigated. 相似文献
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We present the theoretical concept of an optical isolator based on resonance splitting in a silicon ring resonator covered with a magneto-optical polymer cladding. For this task, a perturbation method is derived for the modes in the cylindrical coordinate system. A polymer magneto-optical cladding causing a 0.01 amplitude of the off-diagonal element of the dielectric tensor is assumed. It is shown that the derived resonance splitting of the clockwise and counterclockwise modes increases for smaller ring radii. For the ring with a radius of approximately 1.5μm, a 29GHz splitting is demonstrated. An integrated optical isolator with a 10μm geometrical footprint is proposed based on a critically coupled ring resonator. 相似文献