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研究了具有菱方Th2Zn17型结构的Ce2Fe16Al化合物在居里温度TC附近的磁性和磁熵变.实验结果表明,在居里温度附近样品的磁特性符合二级相变规律,样品的居里温度为2758K.通过磁化强度与磁场和温度关系的测量,计算出临界指数β=044±001,γ=130±001,δ=383±001,临界指数β,γ,δ基本满足标度率方程γ=β(δ-1),但偏离三维Heisenberg模型的理论值.Ce2Fe16Al化合物的磁熵变在居里温度处达到峰值,2T外磁场下的最大磁熵变为195J/kg K.
关键词:
Ce2Fe16Al化合物
临界指数
磁熵变 相似文献
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用传统的固相反应法合成了Fe位掺杂Al的双钙钛矿型氧化物Sr2Fe1-xAlxMoO6 (x=00,005,010,015,03)多晶材料. x射线衍射和扫描电子显微分析显示,在Fe位掺杂Al既没有引入杂相,也没有明显改变Sr2FeMoO6多晶材料的晶粒尺寸和晶界状态. 非磁性Al离子的掺杂使晶粒内部磁有序区细化成更小的区域,同时使反铁磁区内的磁耦合作用变弱. 这一方面提高了亚铁磁区磁化方向的磁场灵敏度;另一方面也降低了反铁磁区对自旋相关电子的散射;两方面的共同作用使Sr2FeMoO6的低场磁电阻效应明显增强,但这种尺寸效应也使材料的磁电阻在高温下下降得更快.
关键词:
低场磁电阻
掺杂
自旋极化电子 相似文献
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利用固相反应烧结法制备了La067Pb033MnO3单相多晶样品.研究了其结构、磁性及输运特性.结果表明,样品呈菱面相晶体结构,空间群为R3C,居里温度TC(=353K)非常接近TMI(=360K).在居里温度附近,发生铁磁-顺磁转变,导电特性由金属特征向半导体特征过渡.磁电阻在居里点达到极大值.当H=16T时,磁电阻的极大值为145%;当H=08T时,磁电阻的极大值为9%.输运性质表明,TTMI时
关键词:
磁电阻
输运特性
磁极化子
钙钛石 相似文献
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研究了Mn5Ge2.7M0.3(M=Ga,Al,Sn)化合物的磁性和磁熵变. x射线衍射实验表明,研究的化合物均呈六角Mn5Si3型结构. 三种原子对Ge原子的替代,使得平均Mn原子磁矩下降,但居里温度没有明显的变化. 由于磁矩的降低,导致磁熵变值的下降,在磁场变化为4.0×106A·m-1时,对应于M=Ga,Al和Sn的样品,最大磁熵变值ΔSmaxM分别为6.1,6.3和5.3J·kg-1K-1,但磁熵变峰值的半高宽ΔTFWHM有所增加. 另外,Mn5Ge2.7M0.3(M=Ga,Al,Sn)化合物在高于居里温度的Arrott曲线上出现了一个不连续点,即样品在一定温度下的顺磁磁化率在某一临界磁场下发生了突变,临界磁场与温度几乎呈正比关系.这可能是由于样品在加一定磁场时3d带的费米能级发生了变化,使得有效电子数的减少所致.
关键词:
居里温度
平均Mn原子磁矩
磁熵变
Arrott图 相似文献
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报道了系列欠掺杂La2-xSrxCuO4(x=0063,0070,0 090,0110,0125)单晶的零场和加磁场情况下ab面和c方向的热导率与温度的关系曲线,测量 温度范围从2到45K. 研究发现ab面和c方向的热导率都受到磁场的压制. 而且在磁场 的作用下,热导压制率随温度变化的关系和场致反铁磁有序的增强与温度的依赖关系有高度 相似性. 认为磁场引起的ab面的热导压制主要是电子热导的变化所致,而c方向的 压制则可能主要来源于声子热导的变化,它们均可能与磁场诱导下欠掺杂La2-x SrxCuO4的某种电荷有序和磁有序的增强密切相关.
关键词:
热导
电荷有序
磁有序 相似文献
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本文报道把热能直接转换电能的热磁发电技术所用一级相变新材料Mn1.2Fe0.8P0.4Si0.6的磁性和热磁发电性能.用高能球磨机械合金化技术和固相烧结合成方法制备了Mn1.2Fe0.8P0.4Si0.6化合物.磁性测量结果表明,该化合物呈现从铁磁状态变为顺磁状态的一级相变,居里温度为337K,并伴随巨大的磁化强度的变化.根据该材料的这一特性,设计制作了热磁发电演示装置,测定了热流引起材料的相变而产生的电流,并研究了固定磁场中热致磁转变产生的电流随热流温度和样品质量的变化.研究结果表明Mn1.2Fe0.8P0.4Si0.6化合物具有很好的热磁发电性能,可作为热磁发电材料. 相似文献
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Affia Aslam Wiqar Hussain Shah S.K. Hasanain M. Nadeem 《Solid State Communications》2004,129(4):267-271
The LaxCa1−xMnO3+δ compositions close to charge ordering (x∼0.5) show a gradual relaxation from a metallic/ferromagnetic state to an insulating/antiferromagnetic state with thermal cycling. Here, we report on the magnetic relaxation in the metastable state and also the revival of the metastable state (in a relaxed sample) due to high temperature thermal treatment. We also show the changes in the magnetization and the thermoelectric power as the revived metastable state is cycled. We find that the changes in the thermoelectric power extend well into the region above the charge ordering temperatures. This suggests that the micro-structural changes accompanying the thermal cycling leave their imprint in the paramagnetic insulating state as well. 相似文献
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We have shown that ultra-thin La0.65Ca0.35MnO3 films exhibit strong metastable behavior. The resistance can vary with time significantly, suggesting that a state of dynamic phase separation exists whereby one phase grows at the expense of another. Physical properties associated with the metastable behavior have been investigated on the films grown on different substrates. We have found that ultra-thin films age much faster than the thicker counterparts and more interestingly the metastability in the resistance of these films enhanced when aged. 相似文献
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When excited by the 514.5 nm radiation of an argon ion laser at temperatures below 150 K crystalline sodium nitroprusside Na2[Fe(CN)5NO] · 2H2O can be transformed into an extremely long-living metastable state. The Raman spectra of the crystal in the metastable state and ground state are compared in the range of 50–2350 cm-1. In the metastable state the ?(NO)-stretching vibration is shifted by more than 100 cm-1 to smaller frequencies depending on the orientation of the sample with respect to the crystallographic axis. This indicates the population of the antibonding π1(NO)-orbital. In addition two new vibrations appear at 566 and 422 cm-1. The other vibrational frequencies of the molecular ion [Fe(CN)5NO]2- are scarcely shifted, but relative intensities change. 相似文献
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An infrared absorption study of the Zn vacancy passivated by two hydrogen atoms (VZnH2) is reported. The ground state of the defect VZnH2 consists of the inequivalent O–H bonds, which are aligned parallel and perpendicular to the c-axis, respectively. A metastable state of the defect was detected with two equivalent O–H bonds oriented perpendicular to the c-axis (VZnH2?). VZnH2? has two local vibration modes at 3329.0 and 3348.4 cm−1 which are the antisymmetric and symmetric combinations of the two O–H stretch modes. The metastable state of the defect is 75±9 meV above the ground state of VZnH2. An activation energy of 0.96±0.12 eV for the transition from metastable to the ground state was determined. 相似文献
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Amorphous-crystalline dual-layer structures resulting from metastable liquid phase separation in (Fe50Co25B15Si10)80Cu20 melt-spun ribbons 下载免费PDF全文
(Fe50Co25B15Si10)80Cu20 ribbons are prepared by using the single-roller melt-spinning method. A dual-layer structure consisting of a (Fe, Co)-rich amorphous phase and a Cu-rich crystalline phase forms due to metastable liquid phase separation before solidification. The magnetic hysteresis loops of the as-quenched and annealed samples are measured at room temperature. It is indicated that the coercivity of the ribbon is almost zero in the as-quenched state. The crystallization leads to the increase of coercivity and decrease of saturation magnetization. 相似文献
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From the EPR investigation, two different crystalline states were found in the VO2+ ion-doped BaCl2·H2O crystal. One is a dynamic disordered state, where the trapped VO+2 ion exhibits hindered rotational motion in a wide temperature region. This state is transformed to a static disordered state even at ambient temperature. The orientation of the doped ion reveals random distribution in the lattice sites. Such polymorphism does not come from phase transition of the host crystal, but from the existence of the metastable state of the VO2+ ion trapped in the lattice. The absence of the phase transition of pure BaCl2·2H2O was confirmed by the measurement of 137Ba NQR and by differential thermal analysis. 相似文献
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By applying an electric current to La0.8Ca0.2MnO3 films at 20 K, a high-resistive state is excited near the Curie point. Such a current induced metastable state turns out to be extremely sensitive to weak measuring currents. When the measuring current changes from 1 to 20 μA, the peak resistance near the metal-insulator transition temperature is reduced from 366 to , showing a remarkably enhanced electroresistance effect (ER=[R(0)−R(I)]/R(0)=70%). Also, in contrast to the previous reports, the metal-insulator transition shifts to a higher temperature. Our experiments show that the high-resistive state is metastable and cannot be removed by reversing the current direction. These behaviors yield a possibility to modulate the metal-insulator phase transition by using electric currents. 相似文献
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利用反应显微成像谱仪开展了56 keV/u的Ne~(4+)离子与羰基硫(OCS)气体的交叉碰撞实验,研究了Ne~(4+)离子诱导的OCS~(3+)的碎裂动力学.通过符合探测三个末态离子,重构了OCS~(3+)离子三体碎裂对应的牛顿图和Dalitz图,并明确区分了直接解离和次序解离两种碎裂过程.重构了OCS~(3+)离子解离过程的动能释放(KER)分布,发现其峰值在25 eV处,同时在18 eV处有肩膀结构的存在,其中25 eV左右的峰来源于直接解离过程,18 eV处的肩膀结构来源于次序解离和非次序解离两种过程.通过分析不同能量和不同电荷态下重离子碰撞实验所得到的KER谱,发现微扰强度不是影响态布居的主要因素.OCS~(3+)次序解离中的第二步KER的峰值在6.2 eV处.结合以往的实验结果,我们得出结论:多电离态的分子发生次序碎裂的根源在于二价离子碎片存在亚稳态,而重构得到的第二步KER可以反映亚稳态离子的电子态信息. 相似文献