Control of electron localization in the dissociation of H2+ and its isotopes with a THz pulse

The molecular dissociation with a two-laser-pulse scheme is theoretically investigated for the hydrogen molecular ion(H+2)and its isotopes(HD+and HT+).The terahertz pulse is used to steer the electron motion after it has been excited by an ultrashort ultraviolet laser pulse and an unprecedented electron localization ratio can be achieved.With the coupled equations,the mass effect of the nuclei on the effective time of the electron localization control is discussed.     

Effect of initial chirp on near-infrared supercontinuum generation by a nanosecond pulse in a nonlinear fiber amplifier

Theoretical and experimental research on the effect of initial chirp on near-infrared supercontinuum generation by a nanosecond pulse in a nonlinear fiber amplifier is carded out. The complex Ginzburg-Landau equation is used to simulate the propagation of the pulse in the fiber amplifier and the results show that pulses with negative initial chirp produce the widest supercontinuum and pulses with positive initial chirp produce the narrowest supercontinuum when the central wavelength of the pump lies in the normal dispersion region of the gain fiber. A self-made line width narrowing system is utilized to control the initial chirp of the nanosecond pump pulse and a four-stage master oscillator power amplifier configuration is adopted to produce a high power near-infrared suppercontinuum. The experimental results are in good agreement with simulations which can provide some guidance on further optimization of the system in future work.     

H2+在阿秒以及双色飞秒激光脉冲中解离时电子位置的相干控制

通过求解含时薛定谔方程, 提出了利用三束激光脉冲控制H₂⁺解离以及解离过程中电子位置的方案. 第一束阿秒激光脉冲将H₂⁺从1sσ_g激发至2pσ_u, 在H₂⁺的解离过程中, 引入两束波长分别为800 nm 与400 nm 的飞秒激光脉冲控制电子在分子内部的运动. 通过改变两束激光脉冲的绝对相位, H₂⁺解离后电子的位置可以得到有效控制(最大有86%的概率使得电子附着在某一个原子核上). 现有的激光技术条件可以在实验上实现这一理论方案. 关键词： 相干控制 电子位置 不对称性参数 2⁺')" href="#">H₂⁺     

In-situ study of Ag nanoparticle hydrosol optical spectra evolution during laser ablation/fragmentation

The results of in-situ monitoring of a laser fragmentation process of a largely polydisperse and morphologically heterogeneous citrate-reduced Ag hydrosol containing a fraction of Ag nanowires are presented. The laser fragmentation was performed using several wavelengths of the incident laser pulses (1064, 532 and 355 nm). Surface plasmon extinction spectra monitoring the nanoparticle fragmentation process were acquired pulse by pulse and related to transmission electron microscopy (TEM) images and statistical TEM image analysis of Ag nanoparticles collected in selected stages of the fragmentation. It was found that, due to different interactions of the laser pulses of various wavelengths with a specific fraction of the Ag nanoparticles in the hydrosol, the course of the fragmentation process depends on the wavelength, leading to different size distributions of the nanoparticles in the resulting hydrosol. The laser pulses of 532 nm wavelength are the most effective for the fragmentation process of the citrate-reduced Ag hydrosol, yielding the narrowest size distribution and the smallest mean radius of the Ag nanoparticles. PACS 81.07.-b; 73.21.-b; 81.16.-c     

激光导致水击穿和等离子体形成过程的物理分析

对短脉冲激光作用水介质中引起光学击穿的机制进行了分析,通过自由电子密度速率方程的数值解确定激光的击穿阈值.将数值计算结果与波长在可见光和近红外波段,脉宽为ns、ps和fs的激光脉冲在纯净水和含有杂质的水中的实验测量的击穿阈值作了比较.还计算了等离子体中自由电子密度的演化、等离子体吸收系数和能量密度.通过解自由电子密度速率方程得到结果与实验测量的值符合得很好.     

High-order harmonic generation from organic molecules in ultra-short pulses

We have studied high-order harmonic generation (HHG) from organic molecules irradiated with near-infrared high intensity laser pulses of 70 fs and 240 fs duration. The molecular systems studied were the aromatics benzene and naphthalene and the alkanes cyclopropane and cyclohexane (cyclic) and n-hexane (linear). Harmonic intensities were measured both as a function of laser intensity (in the range 5×10¹³-5×10¹⁵ W cm^-2) and as a function of ellipticity of the laser field polarisation. The results were compared with those from the xenon atom. For 70 fs pulses, harmonic generation from the organic systems was similar to that of xenon, revealing an atom-like behaviour for molecules when the laser pulse duration is shorter than the fragmentation timescale of the molecule. We note significant differences between molecules with respect to HHG efficiencies and the suppression of HHG in larger species. We discuss these differences in the context of the molecular properties, electronic structure and behaviour of ionisation and fragmentation that result in enhancement of field ionisation in larger systems. Study of the polarisation ellipticity dependence of HHG shows that the harmonic yield in molecules is less sensitive to the polarisation than for atoms (xenon). This is consistent with the expected behaviour given the larger recollision cross-section presented by the core in the molecular system compared to the atom. Our results suggest that study of HHG from molecules exposed to ultra-short pulses is potentially a powerful tool for understanding the electron dynamics of molecules exposed to an intense field. Received 14 September 2000 and Received in final form 6 December 2000     

High-resolution indirect pulse shaping by parametric transfer

The phase and amplitude profile of a shaped pulse in the visible is transferred to a pulse in the near-infrared via an optical parametric amplification (OPA) process. Complex shaped pulses, such as multiple-pulse trains and pulses with high-order phase chirp, are produced at 1.2mum . Theoretical conditions necessary for high-fidelity parametric shape transfer are discussed. Similar schemes can be implemented for other OPA systems pumped at near-infrared wavelengths to generate high-resolution shaped pulses in the mid-infrared.     

Generation of intense highly coherent femtosecond pulses in the mid infrared

Highly coherent mid-infrared femtosecond pulses, tunable between 2.5 and 4.4 mum, and with an average energy and duration between 2.6 and 3.6 microm of 11 microJ and 200fs, respectively, have been produced by an optical parametric amplifier setup driven at 1kHz by a 400- microJ , 800-nm pulse from a Ti:sapphire amplifier. In this system, first tunable moderate-energy femtosecond pulses in the near infrared are produced by continuum amplification in beta -barium borate, and subsequently the near-infrared pulses are amplified and frequency mixed with 800-nm radiation in potassium titanyl phosphate to produce intense tunable mid-infrared pulses. The time-bandwidth product of the mid-infrared pulses is 0.28+/-0.02 over the whole high-energy tuning range. Experimental results are compared with numerical simulations and a simple model.     

Attosecond control in photoionization of hydrogen molecules

We report experiments where hydrogen molecules were dissociatively ionized by an attosecond pulse train in the presence of a near-infrared field. Fragment ion yields from distinguishable ionization channels oscillate with a period that is half the optical cycle of the IR field. For molecules aligned parallel to the laser polarization axis, the oscillations are reproduced in two-electron quantum simulations, and can be explained in terms of an interference between ionization pathways that involve different harmonic orders and a laser-induced coupling between the 1sσ(g) and 2pσ(u) states of the molecular ion. This leads to a situation where the ionization probability is sensitive to the instantaneous polarization of the molecule by the IR electric field and demonstrates that we have probed the IR-induced electron dynamics with attosecond pulses.     

Monoenergetic electronic beam production using dual collinear laser pulses

The production of monoenergetic electron beams by two copropagating ultrashort laser pulses is investigated both by experiment and using particle-in-cell simulations. By proper timing between guiding and driver pulses, a high-amplitude plasma wave is generated and sustained for longer than is possible with either of the laser pulses individually, due to plasma waveguiding of the driver by the guiding pulse. The growth of the plasma wave is inferred by the measurement of monoenergetic electron beams with low divergence that are not measured by using either of the pulses individually. This scheme can be easily implemented and may allow more control of the interaction than is available to the single pulse scheme.     

磁芯材料脉冲间叠加复位研究

 介绍了通过反向叠加长脉冲的方法，在双脉冲间隔小于1 μs的情况下对直线感应加速器磁芯进行的脉冲间复位实验，复位后波形幅度得到了明显改善，在最大伏秒值280 kV×100 ns的单脉冲感应腔上得到了两个伏秒值为200 kV×100 ns的感应脉冲。实验表明：当主脉冲脉宽小于100 ns，间隔大于500 ns时，采用脉冲间叠加复位的方法,将主脉冲叠加在一个反向的长脉冲上（脉宽大于10 μs，最大幅度约为主脉冲的20%）形成正负脉冲串，能有效提高感应加速腔磁芯的利用率，且对感应主脉冲没有明显影响，使单脉冲直线感应加速器的多脉冲改造成为可能。     

In situ observation of photo-bleaching in human single living cell excited by a NIR femtosecond laser

The photo-bleaching of single living cells excited by femtosecond laser irradiation was observed in situ to study the nonlinear interaction between ultrafast laser pulses and living human breast MDA-MB-231 cells. We conducted a systematic study of the energy dependence of plasma-mediated photo-disruption of fluorescently labeled subcellular structures in the nucleus of living cells using near-infrared (NIR) femtosecond laser pulses through a numerical aperture objective lens (0.75 NA). The behavior of photo-bleached living cells with fluorescently labeled nuclei was observed for 18 h after femtosecond laser irradiation under a fluorescence microscope. The photo-bleaching of single living cells without cell disruption occurred at between 470 and 630 nJ. To study the photo-disruption of subcellular organelles in single living cells using the nonlinear absorption excited by a NIR femtosecond laser pulse, the process of photo-bleaching without photo-disruption provides key information for clarifying the nonlinear interaction between NIR ultrashort, high-intensity laser light and transparent fluorescently labeled living cells.     

Plasma channel formed by ultraviolet laser pulses at 193 nm in air

The propagation of picosecond deep ultraviolet laser pulse at wavelength of 193 nm in air is numerically investigated. Long plasma channel can be formed due to the competition between Kerr self-focusing and ionization induced defocusing. The plasma channel with electron density of above 10^13/cm^3 can be formed over 70 m by 50-ps, 20-mJ laser pulses. The fluctuation of laser intensity and electron density inside ultraviolet （UV） plasma channel is significantly lower UV laser by air is considered in the simulation and it the limit of the length of plasma channel. than that of infrared pulse. The linear absorption of is shown that the linear absorption is important for the limit of the length of plasma channel.     

Theoretical investigations of material modification using temporally shaped femtosecond laser pulses

We present a two-dimensional model, based on a drift–diffusion approach, developed to describe the dynamics of electronic excitation and lattice heating in several dielectric materials with different electron–phonon coupling properties (e.g. fused silica and sapphire) under the action of femtosecond near-infrared laser pulse trains with variable separation time between pulses. The modeling approach was aimed to describe the mechanisms that enable the spatial modulation of the structures induced by temporally modulated laser excitation and ablation of wide-band-gap dielectric materials. The possible geometric contours of the laser-induced craters on the target surfaces are discussed on the basis of the lattice-temperature profiles obtained by modeling. It was found that the observed difference in the crater shapes generated in fused silica and sapphire is conditioned by the difference in dynamics of electron excitation and recombination channels characteristic of these two materials. This effect can be used to convert a given temporal pulse modulation into spatial modulation, opening up new perspectives for material processing in order to obtain desired structure profiles. PACS 79.20.Ds; 42.62.-b     

Control of atomic ionization by two-color few-cycle pulses

We have studied the ionization of Rydberg atoms by few-cycle radio-frequency pulses and used two-color fields to control the ionization dynamics. We show that the number of times that electrons are emitted during a pulse can be limited and that the duration of the electron emission can be shortened. These results, once they are transposed to the optical domain, may inspire new strategies for the production of single attosecond pulses.     

Progress in sub-femtosecond control of electron localization in molecules

Recent advances in controlled generation of intense, ultrashort laser pulses in the femtosecond and attosecond time-scales have pushed new avenues of research in the coherent control of ultrafast electron dynamics in atoms and molecules. We present a topical review on the phenomenon of control of electron localization in small dissociating molecules. By creating and controlling coherent superposition of the symmetric and antisymmetric electronic states, it becomes possible to confine the evolving electron cloud onto a preferred nucleus, thereby steering the molecule towards a desired dissociation route. We discuss the origin of the idea and various mechanisms to achieve electron localization in small molecules. To highlight recent experimental progress, we explain how one can employ few-cycle IR pulses and different attosecond extreme ultraviolet (EUV) pulses in various ways to successfully demonstrate the control of electronic dynamics. Future research opportunities and challenges on this topic are envisioned.     

Amplitude and phase control of ultrashort pulses by use of an acousto-optic programmable dispersive filter: pulse compression and shaping

We demonstrate experimentally that an arbitrary phase and amplitude profile can be applied to an ultrashort pulse by use of an acousto-optic programmable dispersive filter (AOPDF). Our filter has a large group-delay range that extends over 3 ps and a 30% diffraction efficiency over 150 THz. Experiments were conducted on a kilohertz chirped-pulse amplification laser chain capable of generating 30-fs pulses without additional pulse shaping. Compensating for gain narrowing and residual phase errors with an AOPDF in place of the stretcher results in 17-fs transform-limited pulses. Arbitrary shaping of these 17-fs pulses is also demonstrated in both the temporal and the spectral domains.     

Frequency-resolved optical gating of isolated attosecond pulses in the extreme ultraviolet

The pulse shape and phase of isolated attosecond extreme ultraviolet (XUV) pulses with a duration of 860 asec have been determined simultaneously by using frequency-resolved optical gating based on two-photon above-threshold ionization with 28-eV photons in He. From the detailed characterization, we succeeded in shaping isolated XUV pulses on an attosecond time scale by precise dispersion control with Ar gas density or by changing the driving pulse width. These results offer a novel way to excite and observe an electron motion in atoms and molecules.     

Moving and Interaction of Compact-like Pulses in Klein-Gordon Lattice System

We study the moving and interaction of the compact-like pulses in the system of an anharmonic lattice with a double well on-site potential by a direct algebraic method and numerical experiments. It is found that the localization of the compact-like pulse is related to the nonlinear coupling parameter Cnl and the potential barrier height V0 of the double well potential. The velocity of the moving compact-like pulse is determined by the linear coupling parameter Cl, the localization parameter q (the nonlinear coupling parameter Cnl) and the potential barrier height Vo.Numerical experiments demonstrate that appropriate Cl is not detrimental to a stable moving of the compact-like pulse.However, the head on interaction of two compact-like pulses in the lattice system with comparatively small Cl leads to the appearance of a discrete stationary localized mode and small amplitude nonlinear oscillation background, while moderate Cl results in the emergence of two moving deformed pulses with damping amplitude and decay velocity and radiating oscillations, and biggish Cl brings on the appearing of four deformed kinks with radiating oscillations and different moving velocities.