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本文以低碳烷烃的选择催化氧化反应为对象,对几种CO2选择氧化低碳烷烃的反应工艺进行了归纳总结,重点分析讨论了催化氧化反应中CO2作为氧化剂的作用机制,并提出了研究展望。 相似文献
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镍基催化剂:制备及水相催化糠醛加氢脱氧反应性能 总被引:1,自引:0,他引:1
以SiO2-Al2O3、γ-Al2O3为载体采用浸渍法制备了不同负载量的镍基催化剂,以XRD、H2-TPR、NH3-TPD与低温N2吸附等技术对催化剂特性进行了表征,并进行了水相催化糠醛加氢脱氧实验研究以制备以C5为主要成分的生物汽油。重点考察了催化剂的镍负载量、载体种类及反应温度对糠醛转化率、目标产物C5选择性的影响,并对催化剂的重复利用性能和糠醛水相加氢脱氧反应机理进行了探讨。结果表明,Ni/SiO2-Al2O3催化性能明显优于Ni/γ-Al2O3。在140 ℃、氢冷压3.0 MPa的优化反应条件下,14wt% Ni/SiO2-Al2O3催化糠醛反应的转化率为63%,C5选择性高达93%。升高反应温度可以提高糠醛的转化率,但反应产物的选择性降低。催化剂在第3次重复使用时糠醛的转化率明显降低,催化剂表面有明显的残留有机聚合物和积碳,达到25wt%左右。 相似文献
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全氟烷基磺酰亚胺盐催化芳香化合物硝化反应的研究 总被引:8,自引:0,他引:8
利用系列全氟烷基磺酰亚胺盐[M(NPf2)n]作为一种新型的Lewis酸催化剂,用于催化芳香化合物与等摩尔65% (m∶m)硝酸的硝化反应. 通过考察不同的催化剂、反应时间、反应温度和反应介质效应等因素对甲苯硝化的影响,以及比较1 mol% Yb[N(C4F9SO2)2]3催化不同结构的取代芳烃硝化反应的效果,表明全氟烷基磺酰亚胺盐不仅具有环境友好和原子经济的特点,而且是一类比常规Lewis酸更有效的、芳香化合物硝化反应的催化剂. 相似文献
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A new reaction-controlled phase-transfer catalyst system, lacunary Keggin polyoxotungstate [C7H7N(CH3)3]9PW9O34 has been synthesized and used for catalytic epoxidation of olefins with H2O2 as the oxidant. Infrared spectra were used to analyze the behavior of the phase transfer of catalyst. In this system, the catalyst not only can act as homogeneous catalyst but also as heterogeneous catalyst to be easily filtered and reused. The epoxidarion reaction is clean and exhibits high conversion and selectivity as well as excellent catalyst stability. 相似文献
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Tang H Arulsamy N Radosz M Shen Y Tsarevsky NV Braunecker WA Tang W Matyjaszewski K 《Journal of the American Chemical Society》2006,128(50):16277-16285
Atom transfer radical polymerization (ATRP) generally requires a catalyst/initiator molar ratio of 0.1 to 1 and catalyst/monomer molar ratio of 0.001 to 0.01 (i.e., catalyst concentration: 1000-10,000 ppm versus monomer). Herein, we report a new copper-based complex CuBr/N,N,N',N'-tetrakis(2-pyridylmethyl)ethylenediamine (TPEN) as a versatile and highly active catalyst for acrylic, methacrylic, and styrenic monomers. The catalyst mediated ATRP at a catalyst/initiator molar ratio of 0.005 and produced polymers with well-controlled molecular weights and low polydispersities. ATRP occurred even at a catalyst/initiator molar ratio as low as 0.001 with copper concentration in the produced polymers as low as 6-8 ppm (catalyst/monomer molar ratio = 10(-5)). The catalyst structures were studied by X-ray diffraction and NMR spectroscopy. The activator CuIBr/TPEN existed in solution as binuclear and mononuclear complexes in equilibrium but as a binuclear complex in its single crystals. The deactivator CuIIBr2/TPEN complex was mononuclear. High stability and appropriate KATRP (ATRP equilibrium constant) were found crucial for the catalyst working under high dilution or in coordinating solvents/monomers. This provides guidance for further design of highly active ATRP catalysts. 相似文献
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制备高碳醇用Cu-Zn-Zr催化剂的研究 总被引:7,自引:0,他引:7
研究了制备高碳醇用新的催化体系CuZnZr.CuZnZr催化剂可用Cu(NO3)2,Zn(NO3)2,ZrOCl2和Na2CO3为原料,采用并流共沉淀法制备.研究结果表明,CuZnZr催化剂对脂肪酸甲酯加氢制备高碳脂肪醇具有很高的活性.催化剂的活性测定结果及XRD和TPR表征结果表明,Cu和Zn都是该催化剂的活性组分,Cu0和ZnO是其活性物相,Zr组分以ZrO物相存在,对活性组分起着间隔分散作用.用ASAP2000型物理吸附仪测定了催化剂的比表面积、比孔容、孔结构和孔径分布,揭示了在不同条件下制备的CuZnZr催化剂活性差异的原因 相似文献
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Cuong Duong-Viet Housseinou Ba Yuefeng Liu Lai Truong-Phuoc Jean-Mario Nhut Cuong Pham-Huu 《催化学报》2014,35(6):906-913
A hierarchical metal-free catalyst consisting of nitrogen-doped carbon nanotubes decorated onto a silicon carbide (N-CNTs/SiC) macroscopic host structure was prepared. The influence of N-CNTs incorporation on the physical properties of the support was evaluated using different characterization techniques. The catalyst was tested as a metal-free catalyst in the selective oxidation of H2S and steam-free dehydrogenation of ethylbenzene. The N-CNTs/SiC catalyst exhibited extremely good desulfurization performance compared to a Fe2O3/SiC catalyst under less conducive reaction conditions such as low temperature, high space velocity, and a low O2-to-H2S molar ratio. For the dehy-drogenation of ethylbenzene, a higher dehydrogenation activity was obtained with the N-CNTs/SiC catalyst compared to a commercial K-Fe/Al2O3 catalyst. The N-CNTs/SiC catalyst also displayed good stability as a function of time on stream for both reactions, which was attributed to the strong anchoring of the nitrogen dopant in the carbon matrix. The extrudate shape of the SiC support allowed the direct macroscopic shaping of the catalyst for use in a conventional fixed-bed reactor without the problems of catalyst handling, transportation, and pressure drop across the catalyst bed that are encountered with nanoscopic carbon-based catalysts. 相似文献
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Recent progress on the chemical immobilization of heteropolyacid (HPA) catalyst on inorganic mesoporous material is reported in this review. Mesostructured cellular foam silica, mesoporous carbon, and nitrogen-containing mesoporous carbon were used as supporting materials. The mesoporous materials were modified to have a positive charge, and thus, to provide sites for the immobilization of HPA catalyst. By taking advantage of the overall negative charge of heteropolyanion, the HPA catalyst was chemically immobilized on the surface-modified mesoporous material as a charge-compensating component. Characterization results showed that the HPA catalyst was finely and molecularly dispersed on the surface of mesoporous material via strong chemical immobilization, and that the pore structure of mesoporous material was still maintained even after the immobilization of HPA catalyst. The supported HPA catalysts were applied to the model vapor-phase ethanol conversion, 2-propanol conversion, and methacrolein oxidation reactions. The supported HPA catalyst showed a better oxidation catalytic activity than the unsupported HPA catalyst in the model reactions. The enhanced oxidation catalytic performance of the supported HPA catalyst was attributed to the finely dispersed HPA catalyst, which was chemically immobilized on the positive site of mesoporous material by sacrificing its proton (Brönsted acid site). The HPA catalyst chemically immobilized on mesoporous material served as an excellent oxidation catalyst. 相似文献
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Dehalogenation of Aryl Halides Catalyzed by Montmorillonite Immobilized Bimetal Catalyst in Aqueous System 下载免费PDF全文
Erli Zheng Xuezhong Zheng 《天然气化学杂志》2006,15(1):70-72
A novel bisupported bimetal catalyst PVP-PdCl2-FeSO4/Al-Mont-PEG600 was prepared by immobilization of PVP (poly (N-vinyl-2-pyrrolidone)) supported bimetallic catalyst using alumina pillared inartificial montmorillonite as the carrier. This catalyst has good dehalogenation activity and selectivity to aryl halides-o-chlorotoluene in aqueous system in the presence of phase transfer catalyst (PEG) and sodium formate as hydrogen source. The catalyst also shows good reusability. 相似文献
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Shinya Iimura 《Tetrahedron》2004,60(35):7673-7678
It has been revealed that a hydrophobic polymer-supported scandium(III) catalyst prepared from sulfonated polystyrene resin is an effective catalyst for carbon-carbon bond-forming reactions such as Mukaiyama aldol reactions in water. According to studies on loading levels of scandium, hydrophobicity of the catalyst is a key for the efficient catalysis. The scandium catalyst was successfully recovered and reused. Several ketones instead of aldehydes were also used as substrates in the aldol reactions. Some 1,4-addition reactions also occurred using the scandium catalyst in water. 相似文献
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Hossein Naeimi Fatemeh Kiani Mohsen Moradian 《Green Chemistry Letters and Reviews》2018,11(3):361-369
Microwave assisted synthesis of 1-substituted-1H-tetrazoles was developed using zinc sulfide nanoparticles as heterogeneous catalyst under solvent free conditions. The tetrazole derivatives were easily prepared through hterocyclization of primary amines with triethyl orthoformate and sodium azide in the presence of ZnS NPs. The experimental results were shown that a series of 1-substituted tetrazoles were synthesized under microwave irradiation by ZnS NPs as an effective and reusable heterogeneous catalyst in excellent yields. This protocol has advantages rather than other reported methods such as non-acidic catalyst, solvent free conditions and greener process as well as a solid recyclable catalyst. The catalyst was recovered and reused for several cycles with consistent activity. 相似文献