《化学教育》2005年载文和作者的统计分析

运用文献计量学的统计方法,对《化学教育》2005年出版的共12期载文和作者进行了统计分析,从中归纳了我国化学教育教学研究的发展状况以及《化学教育》在载文和作者等方面的特点。     

2003年《化学教育》载文情况的统计分析

运用文献计量学的统计方法,对2003年出版的 12期《化学教育》载文情况进行了统计分析,并从中归纳了我国化学教育研究的发展状况以及《化学教育》在载文和作者等方面的特点。     

2009年《化学教育》载文及作者统计分析

运用文献计量学的统计方法,对2009年出版的12期《化学教育》载文情况进行了统计分析,并从中归纳了我国化学教育研究的发展状况以及《化学教育》在载文和作者等方面的特点。     

2006年3种中等化学教育类期刊载文和作者的统计分析与比较

运用文献计量学的统计方法,对2006年《化学教育》、《化学教学》、《中学化学教学参考》(简称《中化参》)3种中等化学教育类期刊载文和作者的情况进行统计分析与比较,从中归纳我国中等化学教学研究的发展状况以及3种期刊在载文和作者等方面的各自特点。     

2005～2006年《化学教育》载文和作者的统计分析与比较

运用文献计量学的统计方法,对2005～2006年《化学教育》出版的共24期载文和作者进行了系统分析与比较,从中归纳了我国化学教育教学研究的发展状况以及《化学教育》在载文和作者等方面连续生长的特点.     

2009—2018年《化学教育》“问题讨论与思考”栏目分析与研究

以 2009—2018 年《化学教育》期刊“问题讨论与思考”栏目的载文为研究对象,采用系统查阅年度总目录与阅读原始文献相结合的方法,从载文的数量、内容、作者、引文等 4 个方面进行统计分析。发现近 10 年《化学教育》“问题讨论与思考”栏目的年均载文量为33篇;研究内容涉及化学知识讨论、教学讨论、实验探究、教材讨论、习题讨论等;载文作者所属地区、机构分布不均衡;研究方法以思辨和化学实验为主;作者之间的合作研究成为一种趋势;引文数量呈现逐渐增多的趋势。     

《化学教育》中化学史文献的统计分析——基于2007—2016年载文的研究

以2007—2016年《化学教育》杂志中“化学史与化学史教育”栏目中文章作为研究分析对象,从载文情况、作者情况、引文情况等3个方面进行统计,分析近十年来化学史教育教学研究的趋势和薄弱环节,并提出几个参考性的建议。     

从中国作者在英国《化学教育研究与实践》上发表的论文看中国化学教育研究

对中国作者在英国《化学教育研究与实践》上的发文情况进行了较为全面的统计分析，包括发文数量、作者区域、作者机构、合作程度以及论文内容等；旨在揭示我国化学教育的国际化程度及其特点，以期为我国化学学科教育研究提供一些参考与启示，提升我国化学教育研究的国际化水平。     

《化学教育》“调查报告”栏目文献的统计分析——基于1980-2008年的载文研究

以<化学教育>"调查报告"栏目29年来的载文为研究对象,采用系统查阅年度总目录与阅读原始文献相结合的方法,从载文的年度分布、内容、调查研究类型、作者等4方面进行统计分析,在一定程度上反映了改革开放以来关于我国化学教育的调查研究发展历程、现状及趋势,并针对其存在的问题提出了建议.     

三种中等化学教育类期刊信息技术应用研究论文统计与分析

以《化学教育》、《化学教学》、《中学化学教学参考》3种中等化学教育教学类期刊为研究对象,对有关信息技术应用的论文进行统计。从计量学角度出发,对论文的数量、内容、作者单位、作者所在区域以及作者合作情况等方面进行统计分析,以期为我国信息技术与化学课程整合研究提供一个视角方面的参考。     

利用手持技术改进测定乙醇分子结构实验

利用压强传感器代替排水集气法,改进测定乙醇分子结构实验的仪器装置,并探索最佳反应条件。另外,设计两个空白实验,结合压强变化曲线对实验误差进行相关讨论。     

Neutral diterpenoids of oleoresins of five species of conifers of Transcarpathia

The compositions of the neutral diterpenoids of the oleoresins of five species of conifers growing in the Transcarpathia have been studied. It has been found that the oleoresins ofAbies alba M.,Larix decidua M., andPicea excelsa L. contain more than 50% of neutral diterpenoids. The group and qualitative compositions of the oxygen-containing diterpenoids have been determined. In the oleoresins ofAbies alba,Picea excelsa, andPicea abies tertiary alcohols — cis-abienol and isocembrol — predominate, while inLarix decidua the main component is the hydroxy ester larixyl acetate. Primary alcohols related to the resin acids have been found in all the oleoresins investigated. Features of the distribution of diterpenoids according to the species of conifers have been revealed. The results obtained are necessary for the chemotaxonomy of conifers of the family Pinceae.Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR. Translated from Khimiya Prirodynkh Soedinenii, No. 6, pp. 812–816, November–December, 1988.     

光谱仪测试范围的扩展

由于石化行业的生产需要，其材质的使用具有多样性和广泛性，经常会出现顾客委托的测试样品的一个或几个元素跨越光谱仪现有测试程序测量范围的情况。本法通过对光谱仪测试原理的认识，根据光谱仪的测试能力及标样的采集，实现了一个或几个元素测量范围的扩展，并对其测量的影响因素进行了研究。     

Dichroism of absorption and polarization of phosphorescence of molecules of the closed form of nitrobenzospirothiopyran

The spectral-polarization characteristics of absorption and phosphorescence of molecules of the initial form of nitro-substituted indolinospirobenzothiopyran were studied in oriented polyethylene films and in solutions with different polarity. An oscillator model of the electron transitions responsible for the formation of absorption and luminescence spectra was suggested. It was established that the principal differences in the spectral and photophysical properties of the compound studied and its oxygen-containing analog are associated with the fact that the electronegativity of the S atom is lower than that of the O atom. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1143–1146, June, 1997.     

Influence of viscosity of medium on processes of oxygen quenching of excited states of mesoporphyrin

The oxygen quenching rate constants for singlet and triplet excited states of the dimethyl ester of mesoporphyrin IX increase with decreasing viscosity of the medium and reach a maximum at a viscosity of approximately 0.4 mPa·sec, after which the rate constants begin to decrease. The drop in rate constant with increasing fluidity of the medium may be related to a nonequilibrium character of the elementary act in the interaction of the reactants in the solvent cage. In viscous media such as isopropyl alcohol, isobutyl alcohol, and isoamyl alcohol, the reaction radius is greater than the sum of the radii of the reacting particles. The long-range character of these processes is due to the relatively weak dependence of the quenching probability on distance.Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 25, No. 2, pp. 161–167, March–April, 1989.     

Determination of heats of detonation and influence of components of composite explosives on heats of detonation of high explosives

The heats of detonation of 20 simple high explosives and explosive mixtures were determined by means of an adiabatic detonation calorimeter designed by the authors. The results indicated that the performance of the instrument was reliable and the experimental data were very accurate. For explosive mixtures, there was a linear accumulative relationship between the heats of detonation of the explosive mixture and its components. Accordingly, the heats of detonation of explosive mixtures could be calculated directly from the heats of detonation of simple explosives and the characteristic heats of other components. The experiments showed that the gold or brass shell of the cylindrical charge could be substituted by a thick-walled porcelain shell, which had the advantage of cheapness.

     

物质分配系数的测定实验改进

实验教学目的是从解决实际问题出发,以实验技术训练和实验设计思想培养为目标。介绍了将单一的物质分配系数测定实验改进为综合实验,提高了实验效果及实验资源利用率。     

Calculation of enthalpies of hydrogenation of hydrocarbons

Sets of hydrogen molecule equivalents have been developed which permit the calculation of hydrogenation of different types of carbon-carbon bonds from ab initio total energies (3-21G and 6-31G* basis sets, and, to a more limited extent, for MP2/6-31G* data) of reactants and products. The calculated enthalpies of hydrogenation are in good agreement with experiment for unstrained molecules, with average errors on the order of 2 kcal/mol. The 6-31G* equivalents allow the enthalpies for strained molecules to be calculated accurately, but the 3-21G equivalents do not. The equivalents for both basis sets have been tested by calculating the enthalpies of hydrogenation of carbon-carbon bonds in nitrogen- and oxygen-containing organic molecules, free radicals, and classical carbocations. The results are in good agreement with experiment in most cases.     

非那雄胺合成工艺改进

非那雄胺能抑制5α-还原酶的活性,明显降低二氢睾酮水平,是一种治疗良性前列腺增生的有效药品。该合成工艺以甾烯酮酸为原料,将其与氯化亚砜反应,无须分离即与叔丁胺反应得17β-酰胺化合物,再氧化开环,环合,氢化,脱氢合成了非那雄胺。经元素分析、IR、1HNMR、13CNMR、MS分析表征了其结构。该法无须使用昂贵的2,2-二吡啶二硫化物和剧毒药品苯亚硒酸酐,且以乙酸铵代替氨气,降低了对设备的要求和腐蚀,更适用于工业生产。