氢化物发生ICP-AES法同时测定纯净水中的砷和汞

本文建立了氢化物发生ICP－AES法同时测定纯净水中砷和汞的方法,检出限分别为As1.7ug/L-Hg0.1ug/L,方法精密度（RSD）为As 3.46%,Hg2.85%,回收率为As92%-110%,Hg90-113%。     

基于复合干涉的光纤低相干干涉传感系统研究

研究一种能够进行远程及绝对测量的光纤低相干干涉传感系统。该系统包含两个光纤干涉仪,其中一个光纤干涉仪置于被测场中感应被测量的变化,可实现远程测量;另一个光纤干涉仪解调被测量的值。运用波分复用技术,使用于解调的光纤干涉仪同时工作于低相干干涉和高相干干涉状态。用低相干干涉信号决定被测量的幅值,对被测量实现绝对测量,并使测量量程不受波长限制;同时,用高相干干涉信号对被测量进行高精度的测量。系统的测量量程为6mm,测量分辨率小于1nm,位移实验结果的线性相关系数R为0.99。     

Microscopic derivation of fluctuation formulas for calculating dielectric constants by simulation

A microscopic derivation using the average Maxwell electric field is given for fluctuation formulas for the dielectric constant of a simulation sample for both periodic and reaction field boundary conditions. The reaction field case is for a spherical cavity reaction field. The derivations put both boundary conditions on an equal footing of microscopic theory and the only nonrigorous part of the derivation is the assumption that the region used to average the electric field is large enough. The fluctuation formula for reaction field boundary conditions is rather different from that used heretofore. The method is applied to a subregion of an isolated spherical system.     

Helium-3 adsorption refrigerator cooled with a closed-cycle cryocooler

A helium-3 adsorption refrigerator cooled with a pulse-tube cryocooler is developed. The refrigerator has two stages of adsorption pumping. The first stage is designed for the condensing and pumping of helium-4, whose cooling capacity is used for the condensation of helium-3. The second stage is designed for pumping helium-3. The final temperature reached by the refrigerator is 0.305 K. This temperature is retained for at least 24 h. The time required for helium recondensation and the obtainment of low temperature is 1.5 h. The cryostat is a self-contained instrument, as it contains no external gas-supply pipelines and the working gas is stored directly within the working volume of the refrigerator. The work is performed in the Frank Laboratory of Neutron Physics of the Joint Institute for Nuclear Research.     

Influence of periodie and random two-dimensional nuclei distribution on the recrystallization kinetics

The recrystallization process is modeled by using both a periodic lattice and a random array of nuclei for the two-dimensional, instantaneous nucleation case. Recrystallization kinetics is obtained with analytical expressions for the periodic model and computer-generated results for the random situation. The resulting kinetics shows some disagreement with the classical Johnson-Mehl-Avrami-Kolmorogav kinetics, and stresses the fact that there is a finite time for the completion of the whole process. The time for completion is calculated for the two-dimensional and three-dimensional cases.     

1H pulse NMR analysis of silane-treated layers on glass fiber surfaces

The surface treatment of a glass fiber using mercapto-functional silane coupling agent having a di- or trialkoxy group has been studied. The surface of silane-treated fiber is observed by scanning electron microscopy. The treated layer looks hard like glass for the trialkoxy silane-treated, whereas it looks soft for the dialkoxy silane-treated. Molecular mobility of the treated layer is analyzed by ¹H pulse nuclear magnetic resonance spectroscopy. The amount of silane loading increases with increased silane concentration in the treatment solution. The relaxation time for the surface layer is longer for the dialkoxy structure than for the trialkoxy structure. The silane chain is flexible in the dialkoxy structure, but is rigid for the trialkoxy structure, independent of the loading amount of silane. The relaxation behavior for the mixture of the di- and trialkoxy structures is between those of the pure dialkoxy and trialkoxy structures and depends on the mixing ratio. The network density of silane chains on the glass fiber can be controlled by varying the mixing ratio of the di- and trialkoxy compounds.     

自治广义Birkhoff系统的平衡稳定性

研究广义Birkhoff系统的平衡稳定性问题.建立了自治广义Birkhoff系统的平衡方程;给出了自治广义Birkhoff系统的一次近似方程,利用Lyapunov一次近似理论,建立了系统平衡状态稳定性的判据;构建了Lyapunov函数,利用Lyapunov直接法,建立了自治广义Birkhoff系统平衡状态稳定性的判据.给出了若干算例以说明结果的应用.     

Beyond Einstein's radiation theory

Einstein's radiation mechanism is generalized to account for the possibility of population inversion by placing a nonlinear bound on the growth of an unstable perturbation. The nonstationary linear mechanism of relaxation to blackbody radiation below threshold is studied. The nonstationary photon distribution is the negative binomial distribution, and casting it as a law of error, for which the most probable value is the mean value, gives the expression for the statistical entropy. The second law yields a nonequilibrium generalization of Planck's radiation law. The nonlinear mechanism leading to the transformation from the negative binomial probability distribution, for chaotic light, to a Poisson probability distribution, for coherent light, is then analyzed. A criterion for lasing is given in terms of the chemical potential of radiation which is compared to the inequality for the transition from quantum to classical statistics.     

哈特曼法检测渐进多焦点镜片

介绍了哈特曼法检测眼镜片的测量原理及对远轴光线的屈光度补偿，采用哈特曼法对渐进多焦点镜片进行检测。提出了实验总体方案并得到CCD采样图，通过后续图像处理，理论上可以得到镜片的屈光度分布图。结果表明，哈特曼法检测渐进多焦点镜片结构简单，方便可行。     

KBA显微镜成像系统的成像模拟及X光成像实验的研究

KBA显微镜是一种非轴对称、非共轴的掠入射成像系统。其结构复杂,调节精度要求很高,在实际成像实验操作中难以掌握其成像特性。利用光学设计软件模拟其成像,对系统的调节和成像分析提供有益的参考。利用光学设计软件ZEMAX模拟了KBA显微镜对点源的成像过程,给出了KBA显微镜成像系统的焦深约为1 mm,景深为50 mm左右。并且由模拟可知,掠入射角对成像的影响很大。对像素尺寸约10μm的探测设备,模拟得出KBA成像系统的空间分辨力上限为3μm左右。基于星光Ⅱ装置对周期为20μm的网格靶成像,获得了KBA显微镜较为清晰的X光图像。该项工作为进一步开展掠入射成像系统的研究奠定了基础。     

耦合双原子Jaynes-Cummings模型的腔场谱H

研究了处于激发态的两原子与高Q腔场相互作用单光子过程的腔场谱,给出了初始光场为光子数态、相干态、压缩真空态时的腔场谱数值计算结果,分析了原子间偶极-偶极相互作用强度gα对腔场谱结构的影响.发现真空场Rabi峰,当gα较弱时为4峰,gα较强时为3峰结构;弱场数态(n＞0)时为5峰,强场时为3峰结构.相干态和压缩真空态时,谱结构与光子数分布有关,一般为复杂的多峰结构.结果表明,gα对峰位峰高都有影响,破坏了谱结构的对称性,但这种影响只在真空场和弱场时才较明显.     

Monte Carlo analysis of the internal structure of light scattering particles with slit-scan illumination

An algorithm based upon a Monte Carlo procedure for calculating the scattering and absorption by a host particle containing a distribution of particulate inclusions is described. The host particle is sufficiently large so that ray optics can be applied. The inclusions are too small for ray optics but sufficiently large so that the full boundary-value formalism must be used. A major consideration is to determine whether the internal structure is better resolved when slit-scan illumination is utilized rather than plane wave illumination. The algorithm is tested for a layered sphere for which the boundary value solution is available.     

Z箍缩初级实验平台的激光触发系统

介绍了Z箍缩初级实验平台激光触发系统的设计和单路样机验证实验结果.采用12台激光器、24个激光触发主开关来实现24路电流脉冲的精确同步,由Nd:YAG四倍频脉冲激光来触发开关,采用水平分光将一台激光器的激光脉冲等分为两束激光,激光聚焦后分别触发相邻的两路主开关.单路样机验证实验获得的激光脉冲的抖动极差小于等于3 ns.主开关的抖动极差小于等于5 ns,3台激光器之间的抖动极差小于等于3 ns.实验结果表明:在主Marx充电电压小于等于75 kV时,光路管道双隔离气室具有良好的绝缘性和密封性;激光光路系统稳定可靠;能量为100 mJ、脉冲宽度为7 ns的266 nm激光经过分光后,能够满足Z箍缩初级实验平台的设计要求.     

Electron scattering studies of DMS,DMDS and DMSO homologous series

The present paper reports ionisation, elastic and total cross section for the first three members of dimethyl sulphide, dimethyl disulphide and dimethyl sulphoxide family of molecules. The multi-scattering centre spherical complex optical potential formalism is applied for integral elastic and inelastic cross section calculations. From the inelastic part, ionisation cross section is derived using complex scattering potential-ionisation contribution method. The total cross section is then obtained from the sum of elastic and inelastic contributions. A reasonably good agreement is obtained for elastic cross section, wherever comparison is available. The ionisation and total cross section calculation for the complete set of molecules has been performed for the first time.     

钼盐涂覆—无火焰原子吸收法测定肿瘤患者血清中微量铝的研究

用钼盐涂覆石墨管并以Ｋ２Ｃｒ２Ｏ７和Ｔｒｉｔｏｎ Ｘ－１００为基体改进剂，ＧＦＡＡＳ法测定肿瘤癌患血清中微量铝，大幅度提高测定灵敏度和准确度。避免了沾污。特征浓度２１．１５ｐｇ／０．００４４Ａ·Ｓ。加标平均加收率１０４．９２％。相对标准偏差小于８．１７％。     

Flux Induced by Multiplicative Dichotomous Noise

The transport of particles induced by multiplicative dichotomous noise for a system is investigated. The stationary probability current is derived. It is shown that, for the system studied by us, the spatial asymmetry is the ingredient for the nonzero stationary current.     

哈特曼-夏克传感器在非球面加工中的应用

论述了哈特曼-夏克传感器的测量原理，对它的测量精度进行了标定。同时还介绍了哈特曼-夏克传感器的在光学车间实际测量大口径非球面系统的情况，表明哈特曼-夏克传感器是一种非常有效的光学车间检测手段。     

铝粉点火微观机理的光谱研究

 铝粉是一种含能高的材料，它被广泛地添加到含能材料中。利用3台单色谱仪和OMA谱仪等多种谱仪技术，研究了铝粉在几种不同环境下的快速反应微观特性。研究表明：铝粉冲击波点火的临界条件和铝粉的物理状态相关。微米铝粉点火的临界温度为2 100 K，它接近Al₂O₃的熔化温度。它表明，在空气中容易氧化的微米铝粉点火，必须使铝粉表面的氧化层熔化。在气相反应中，微米铝粉和氧的反应是主要的；和水的反应是次要的。减小微米铝粉的颗粒尺寸，可以明显提高快速反应温度。 含铝复合燃料中的液体燃料反应后的铝粉才能参与反应；铝粉添加至气相反应介质后将明显提高反应温度。     

基于DSP的直线感应电机模糊矢量控制系统研究

针对直线感应电机强耦合、多变量、非线性、时变的控制特点,将模糊控制策略应用到转差频率直线感应电机矢量控制系统中。建立了计及端部效应的直线感应电机等效数学模型,设计了基于DSP的直线感应电机模糊控制系统的软硬件,采用磁链开环、速度和电流闭环的矢量控制系统,对速度模糊控制器进行了设计。对直线感应电机在起动和负载情况下的动态特性进行了仿真实验,结果表明：采用模糊控制实现的直线感应电机转差频率矢量控制系统比具有基本数学模型的传统PI控制系统具有更强的鲁棒性。