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对准二维电荷密度波导体磷酸钨青铜(PO2)4(WO3)2m(m=6)在2—300K温区内的磁电阻及在2K时的Δρ/ρ0-B关系进行了 实验研究.利用电子磁击穿模型对其低温端的磁阻增强行为进行了分析解释,理论和实验相 符合,并估算出高温端第一个Peierls能隙的大小为3.0meV,电子在低温下的迁移率为0.0 42m2V-1s-1
关键词:
低维导体磁电阻
电荷密度波 相似文献
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通过I-V特性测量,研究了横向交、直流电流对蓝青铜K0.3MoO3中电荷密度波(CDW)动力学行为的影响.实验结果表明,无论是直流还是交流,随着横向调制电流的增大,CDW滑移的阈值电场均会相应地减小;但横向交流电流的调制效应较小,可能更接近本征的效应.考察了横向交流电流的调制效应与其频率的依赖关系.
关键词:
0.3MoO3单晶')" href="#">K0.3MoO3单晶
电荷密度波
横向电流调制效应 相似文献
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根据描述电子声子相互作用的Fr?hlich哈密顿量,推导出了金属螺旋型碳纳米管(n1,n2)的Peierls相变温度的一般表达式,并利用该式计算了(6,3)的Peierls相变温度.结果表明金属螺旋型碳纳米管在远离室温下都不会发生Peierls相变,仍然保持其金属性
关键词:
螺旋型碳纳米管
电子声子相互作用
Peierls相变 相似文献
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根据建立在电子-声子相互作用基础上的Peierls 相变理论,利用形变势模型和半经验晶体轨道方法计算的能带结构数据,对一维有机导体tetrathiafulvalene-tetracyanoquinodimethane的Peierls相变温度进行了计算.并对其金属-绝缘体相变机制进行了讨论.
关键词:
电子-声子相互作用
Peierls相变温度
一维有机导体 相似文献
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在80—280K范围内对准二维钾、钠紫青铜单晶的热电势与温度的关系进行了研究,发现:(1)对钾紫青铜,在105K附近热电势有符号变化,并且在高温正常金属相,热电势S具有较小的负值,可以用经验关系S=AT+B来描述,自由电子为支配载流子;而在T<105K的低温CDW态,S为正值,可表示为S=A′T+B′/T的形式,载流子的声子曳引热电势占支配作用.(2)对钠紫青铜,在T>80K范围内S与T具有很好的线性关系,没有观察到Peierls相变,电子为支配载流子.对造成两者差异的根源,也作了初步探讨
关键词: 相似文献
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测量了Ni52Mn24Ga24单晶样品在磁场加载和未加载情 况下马氏体相变时的相变应变.分析结果表明:用提拉法生长单晶时在晶体内部引入了单一取向的内应力,该取向内应力可诱导马氏体变体择优取向,从而导致马氏体相变时产生大的相变应变.从理论上计算了该内应力的大小.另外,对样品在马氏体态单纯磁诱导应变的热动力学研究,表明取向内应力在马氏体态依然存在.
关键词:
马氏体相变
磁感生应变
内应力 相似文献
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F. Güell 《Journal of luminescence》2004,106(2):109-114
Up-conversion blue emissions of trivalent thulium ions in monoclinic KGd(WO4)2 single crystals at 454 and 479 nm are reported for a single pump laser source at 688 nm. We grew thulium-doped KGd(WO4)2 single crystals at several concentrations from 0.1% to 10%. We recorded a polarized optical absorption spectrum for the 3F2+3F3 energy levels of thulium at room temperature and low temperature (6 K). From the low temperature emission spectra we determined the splitting of the 3H6 ground state. The blue emissions are characterized as a function of the dopant concentration and temperature from 10 K to room temperature. To our knowledge, this is the first time that sequential two-photon excitation process (STEP) generated blue emissions in thulium-doped single crystals with a single excitation wavelength. 相似文献
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稀土倍半氧化物单晶光纤材料凭借超高的熔点(~2400℃)、稳定的物化性能以及灵活的结构被认为是极具潜力的高温传感介质。本文采用激光加热基座(LHPG)法,成功生长了透明无开裂Dy^(3+)离子掺杂的倍半氧化物单晶光纤Lu_(2)O_(3)和Y_(2)O_(3)。依据Dy^(3+)离子的^(4)I_(15/2)和^(4)F_(9/2)能级为一对热耦合能级对(TCLs),测试得到了430~520 nm波长范围内的下转换荧光光谱。荧光强度比(FIR)结果显示,晶体在298~673 K温度范围内的荧光强度具有良好的温度相关性。其中Dy∶Lu_(2)O_(3)在该范围内的最大相对灵敏度和绝对灵敏度分别为0.97%·K^(-1)(315 K)和1.62×10^(-4) K^(-1)(673 K),展现出更为优异的温度传感性能。 相似文献
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Photoluminescence of X-irradiated CaF2:Co single crystals is reported. The emission spectrum shows four peaks at 505, 550, 640 and 685 nm, all of them with an excitation band at 275 nm. The same emission spectrum, plus a band at 280 nm, is found in X-ray excited luminescence measurements. Thermoluminescence of 80 K X-irradiated crystals gives a glow curve with five peaks at 100, 125, 145, 190 and 225 K. The spectral distribution of these glow peaks is similar to that of the X-ray excited luminescence. The 280 nm band is associated with electron—hole recombination. The other four bands are associated with electron transitions among excited states of Co2+ produced by recombination of holes and Co+-ions created by X-irradiation. 相似文献
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I. N. Ogorodnikov A. Yu. Kuznetsov A. V. Kruzhalov V. A. Maslov 《Radiation measurements》1995,24(4):423-426
The results of study on luminescence and recombination processes in the large LiB3O5 single crystals are reported. It was shown that the luminescence at 295 nm is excited by photons with energy exceeding the band gap energy, by an electron beam, and also in recombination processes. Four peaks of thermoluminescence at 130, 180, 240 and 330 K are revealed, their parameters are fixed, and the origin of the trapping and recombination centers are determined. The most acceptable models of recombination processes and the origin of the LiB3O5 luminescence are discussed. 相似文献
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利用红外光源浮区法生长出大尺寸、高质量的磁失措自旋冰化合物Dy2Ti2O7单晶体.X射线衍射实验证实晶体具有面心立方结构,空间群为Fd3m,晶胞参数a=1.0112(2) nm,[111]和[400]方向X射线衍射摇摆曲线半高宽分别仅为0.07°和0.05°.直流磁化率与温度关系测量给出晶体的Van Vleck顺磁因子为2.46×10-5 m3/mol,有效磁矩μeff=10.24(4)μB,Cure-Weiss温度ΘCW=1.1 K,揭示Dy2Ti2O7具有弱的铁磁性.对磁性起源的综合分析表明,该自旋冰晶体磁性质主要来源于磁偶极相互作用,且相关最近邻长程偶极相互作用能量标度Dnn=3.00 K.
关键词:
2Ti2O7')" href="#">Dy2Ti2O7
浮区法晶体生长
关联电子系统
自旋冰 相似文献
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Magnetic measurements on hexagonal single crystals of M2Mo3O8 (M = Mn, Fe, Co and Ni) are reported. The Mn compound orders ferrimagnetically at Tc = 41.5 K; the Fe and Co compounds antiferrimagnetically at TN = 59.5 K and 40.8 K, respectively. No magnetic ordering was found in the Ni compound down to 2 K. All the compounds showed strong magnetic anisotropy when ordered, the results indicating that the magnetic spins' preferred orientation is along the hexagonal axis. Mn2Mo3O8 shows a temperature dependence of the spontaneous magnetization in the ferrimagnetic regime which is rarely observed: as T → 0, Ms → 0. 相似文献
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利用嵌入反应合成了有机-无机嵌入化合物Fe0.95PS3(MV)0.1 1(MV为1,1′- 二甲基-4,4′-联吡啶阳离子),对其结构和磁性进行了研究.x射线衍射数据表明,此嵌入化 合物的晶体结构仍为单斜晶系,空间群为C2/m,晶胞参数a=0.879 nm, b=0.944 nm, c=1.07 0 nm, β=114.76°.相对于纯FePS3, 层间距离增大0.33 nm.磁化率研究表明, 从室温降 到4.2 K
关键词:
嵌入化合物
Mssbauer谱
磁相互作用
分子磁体 相似文献