Upper Critical Fields and Anisotropy of BaFe1.9Ni0.1As2 Single Crystals

Temperature dependence of the upper critical magnetic field （Hc2） near Tc of 20 K in a BaFe1.9 Ni0.1 As2 single crystal is determined via magneto-resistance measurements, for the out-plane （H ⊥ab） and in-plane （H ｜｜ ab） directions in magnetic fields of up to 8 T. The upper critical fields at zero temperature estimated by the Werthamer-Helfand- Hohenberg （WHH） formula are μ0H^｜｜ c2（0） = 137 T and μ0H⊥c2（0） = 51 T, both exceeding the weak-coupling Pauli paramagnetic limit （μ0Hp = 1.84Tc）. However, the WHH formula could overestimate the μ0H^｜｜12（0） value. The anisotropy of upper critical fields is around 3 in the temperature range close to Tc. The result is very similar to the Co-doped 122 superconductor BaFe2-x Cox As2, indicating that electron-doped 122 superconductors exhibit similar superconducting properties.     

NaxCoO2晶体的制备、结构和物性

本文以氢氧化钠(NaOH)为溶剂,用高温溶液电解法成功生长出了α相和γ相的NaxCoO2单晶.通过少量SrCO3的添加,可以人为控制晶体产品的晶体学相.以NaOH为溶剂生长出γ相NaxCoO2晶体,添加SrCO3则生长出α相NaxCoO2晶体.对单晶样品的电阻率的测量发现,α相NaxCoO2的电阻率随温度降低而升高,呈半导体特性,而γ相NaxCoO2的电阻率则随温度降低而降低,呈金属性.α相NaxCoO2的热电势低于同温度下γ相NaxCoO2热电势,在300K时分别为30μV/K和70μV/K左右,但均随温度降低而减小,即热电势的温度关系均表现为金属型行为.     

横向交、直流电流对蓝青铜K0.3 MoO3的 I-V特性的调制效应

通过I-V特性测量,研究了横向交、直流电流对蓝青铜K0.3MoO3中电荷密度波(CDW)动力学行为的影响.实验结果表明,无论是直流还是交流,随着横向调制电流的增大,CDW滑移的阈值电场均会相应地减小;但横向交流电流的调制效应较小,可能更接近本征的效应.考察了横向交流电流的调制效应与其频率的依赖关系.     

横向交、直流电流对蓝青铜K0.3MoO3的I-V特性的调制效应

通过I-V特性测量，研究了横向交、直流电流对蓝青铜K_0.3MoO₃中电荷密度波(CDW)动力学行为的影响.实验结果表明，无论是直流还是交流，随着横向调制电流的增大，CDW滑移的阈值电场均会相应地减小；但横向交流电流的调制效应较小，可能更接近本征的效应.考察了横向交流电流的调制效应与其频率的依赖关系. 关键词： 0.3MoO₃单晶')" href="#">K_0.3MoO₃单晶 电荷密度波 横向电流调制效应     

Zn掺杂的YBa2(Cu1-xZnx)3O7-δ(x=0, 0.01, 0.02)体系的反常霍尔效应

利用脉冲激光沉积(PLD)方法制备了c轴取向的高质量YBa2(Cu1-xZn)3O7-δ(x=0, 0.01, 0.02)外延薄膜.超导临界温度随Zn掺杂量增加而较快地下降,与单晶样品的结果相符.在强磁场下的输运测量发现YBa2(Cu1-xZn)3O7-δ系列样品在Tc附近均出现反常的Hall电阻率符号反向,但其Hall电导率σxy随磁场的变化关系与氧欠掺杂的YBa2Cu3O6.66存在很大差异,说明Zn掺杂和氧掺杂对混合态中的磁通涡旋性质的影响有显著不同.     

La1.8Sr0.2CuO4/La1.9Sr0.1CuO4超导双层薄膜的制备及电学输运性能研究

采用Nd:YAG固体激光器在SrTiO3(STO)衬底上成功制备了具有c轴取向的过掺杂La1.8Sr0.2CuO4和欠掺杂La1.9Sr0.1CuO4超导薄膜。分别对薄膜的晶体结构、电学输运性能进行了研究。通过晶体结构分析表明超导薄膜沿<001>晶向生长,沉积后的薄膜超导转变温度(TC)随着薄膜厚度(20～200 nm)的增加而逐渐升高,显示薄膜由二维特征向三维特征过渡。在双层薄膜La1.8Sr0.2CuO4/La1.9Sr0.1CuO4结构中,其电学输运性能和所加电场的方向有很大关联,反映出电场的方向影响了超导薄膜中空穴载流子的扩散,进而影响了薄膜的超导转变温度和电学输运性能。     

高温超导体中的能斯特效应与类涡旋激发

简要地介绍了通常金属的能斯特(Nernst)效应,指出Ⅱ类超导体在混合态的磁通运动产生的能斯特效应远大于正常载流子的贡献.接着介绍了高温超导的La 2-xSrxCuO4(LSCO)单晶中涡旋运动产生的大的能斯特信号从Tc一直延续到远高于Tc的温度T0,并报道在Zn掺杂的YBa2Cu3O7-8(YBCO)外延薄膜中观测到的Tc和T0随Zn质量分数的变化.这些体系的能斯特效应结果充分地显示出高温超导体中在Tc以上可能存在着类磁通涡旋.根据预超导配对的理论图像对实验结果进行了讨论.     

界面自组装的金/氧化石墨烯复合材料的表面增强拉曼散射行为研究

采用Frens法制备金纳米粒子溶胶,通过界面自组装技术在掺磷的非晶碳衬底表面构筑三维的金/氧化石墨烯/金复合结构.以罗丹明B为探针分子,考察金/氧化石墨烯/金复合材料的表面增强拉曼散射活性.结果表明,由于氧化石墨烯的化学增强和金纳米粒子的电磁场增强的协同作用,在该三维复合材料上获得了很强的罗丹明B拉曼信号.所设计的三维金/氧化石墨烯/金复合材料在生物分析、环境监测、疾病防控、食品安全等领域具有潜在的应用价值.     

First-principles investigation of the electronic structure and magnetism of eskolaite

The electronic structure and magnetism of eskolaite are studied by using first-principles calculations where the on-site Coulomb interaction and the exchange interaction are taken into account and the LSDA+U method is used. The calculated energies of magnetic configurations are very well fitted by the Heisenberg Hamiltonian with interactions in five neighbour shells; interaction with two nearest neighbours is found to be dominant. The Néel temperature is calculated in the spin-3/2 pair-cluster approximation. It is found that the measurements are in good agreement with the calculations of lattice parameters, density of states, band gap, local magnetic moment, and the Néel temperature for the values of U and J that are close to those obtained within the constrained occupation method. The band gap is of the Mott--Hubbard type.     

Structural and magnetic properties of LiNi0.5Mn1.5O4 and LiNi0.5Mn1.5O4-δ spinels： A first-principles study

<正>Structural and magnetic properties of LiNi_0.5Mn_1.5O₄ and LiNi_0.5Mn_1.5O_4-δ are investigated using densityfunctional theory calculations.Results indicate that nonstoichiometric LiNi_0.5Mn_1.5O_4-δ and stoichiometric LiNi_0.5Mn_1.5O₄ exhibit two different structures,i.e.,the face-centred cubic（Fd-3m） and primitive,or simple,cubic （P4₃32） space groups,respectively.It is found that the magnetic ground state of LiNi_0.5Mn_1.5O₄（P4₃32 and Fd-3m） is a ferrimagnetic state in which the Ni and Mn sublattices are ferromagnetically ordered along the[110]direction whereas they are antiferromagnetic with respect to each other.We demonstrate that it is the presence of an O-vacancy in LiNi_0.5Mn_1.5O_4-δ with the Fd-3m space group that results in its superior electronic conductivity compared with LiNi_0.5Mn_1.5O₄ with the P4₃32 space group.