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1.
王辉  林春江  李盛涛  李建英 《物理学报》2013,62(8):87702-087702
CaCu3Ti4O12介电损耗较大且损耗机理尚不明确, 因此限制了其应用.本文采用固相法和共沉淀法合成CaCu3Ti4O12陶瓷, 利用宽带介电温谱研究在交流小信号作用下, 双Schottky势垒耗尽层边缘深陷阱的电子松弛过程、 载流子松弛过程以及CaCu3Ti4O12陶瓷的介电损耗性能. 研究发现, 在低频下以跳跃电导和直流电导的响应为主, 而高频下主要为深陷阱能级的松弛过程所致, 特别是活化能为0.12 eV的深陷阱浓度, 这是决定CaCu3Ti4O12陶瓷高频区介电损耗的重要因素.降低直流电导, 有利于降低低频区介电损耗; 而高频区介电损耗的降低, 需要降低深陷阱浓度或增大晶粒尺寸. 共沉淀法制备的CaCu3Ti4O12陶瓷, 有效降低直流电导及控制深陷阱浓度, 介电损耗降低明显. 关键词: 3Ti4O12陶瓷')" href="#">CaCu3Ti4O12陶瓷 介电损耗 松弛过程 Schottky势垒  相似文献   

2.
CaCu3Ti4O12陶瓷的微观结构及直流导电特性   总被引:2,自引:0,他引:2       下载免费PDF全文
杨雁  李盛涛 《物理学报》2009,58(9):6376-6380
采用传统固相反应法制备了CaCu3Ti4O12陶瓷.XRD证实其CaCu3Ti4O12相;SEM观察到明显的晶粒晶界结构,晶界区亦由小晶粒构成;结合EDS结果,判定晶界区小晶粒为CuO.在较宽的温度范围内,CaCu3Ti4O12陶瓷的介电常数保持在105左右;当频率为103 Hz温度小于150 K时,介电常数迅速下降.在173—373 K温度范围内,通过其I-V特性,得到CaCu3Ti4O12陶瓷直流电导随温度的变化:直流电导与温度的关系可分为三部分,对应的活化能分别为0.681 eV,0.155 eV和0.009 eV,这与CuO陶瓷直流电导活化能一致.可以认为晶界区的CuO小晶粒在CaCu3Ti4O12陶瓷的直流电导中占主导,这为解释CaCu3Ti4O12陶瓷反常的介电性能提供了新的思路. 关键词: 3Ti4O12')" href="#">CaCu3Ti4O12 微观结构 直流电导 介电特性  相似文献   

3.
赵学童  廖瑞金  李建英  王飞鹏 《物理学报》2015,64(12):127701-127701
在电场为3.5 kV/cm的条件下, 对CaCu3Ti4O12陶瓷进行了60 h的直流老化, 研究了老化过程对CaCu3Ti4O12陶瓷介电性能和电气特性的影响. J-E特性测试结果表明, 直流老化导致CaCu3Ti4O12陶瓷击穿场强、非线性系数和势垒高度明显降低. 介电性能测试结果表明, 低频介电常数和介电损耗明显增大, 并且介电损耗随频率的变化遵从Debye弛豫理论, 可分解为直流电导损耗和弛豫损耗, 直流老化主要导致了电导损耗的增加. 在低温233 K, 介电损耗谱中出现两个弛豫峰, 其活化能分别为0.10, 0.50 eV, 认为对应着晶粒和畴界的弛豫过程, 且不随直流老化而变化. 通过电模量谱对CaCu3Ti4O12陶瓷的弛豫过程进行了表征, 发现直流老化导致的界面空间电荷在外施交变电场的作用下符合Maxwell-Wagner极化效应, 并在低频区形成新的弛豫峰. 在高温323-473 K的阻抗谱中, 晶界弛豫峰在直流老化后明显向高频移动, 其对应的活化能从1.23 eV 下降到0.72 eV, 晶界阻抗值下降了约两个数量级. 最后, 建立了CaCu3Ti4O12陶瓷的阻容电路模型, 分析了介电弛豫过程与电性能之间的关联.  相似文献   

4.
贾然  顾访  吴珍华  赵学童  李建英 《物理学报》2012,61(20):466-472
具有巨介电常数的CaCu3Ti4O12陶瓷是一种理想的高储能密度电容器材料.本文以草酸为沉淀剂、以乙酸铵为调节pH值的定量缓冲剂,获得制备CaCu3Ti4O12陶瓷的简化共沉淀法.确定了pH=30为制备前驱粉料的最佳反应条件.通过显微分析和介电性能测量,发现在1040℃—1100℃范围内,随着烧结温度的提高,陶瓷的品粒尺寸增大,非线性系数上升,电位梯度和介电损耗下降,1100℃烧结的试样tanδ最低达到0.04.认为CaCu3Ti4O12陶瓷介电损耗包含直流电导分量、低频松弛损耗和高频松弛损耗.低频松弛活化能为0.51 eV.,对应于晶界处的Maxwell-Wagner松弛极化;高频松弛过程活化能为0.10 eV,对应晶粒内部的氧空位缺陷.烧结温度的升高导致晶界电阻下降.  相似文献   

5.
慕春红  刘鹏  贺颖  张丹  孟玲  边小兵 《物理学报》2008,57(4):2432-2437
采用固相反应法制备了CaCu3Ti4-xFexO12(0≤x≤0.2)陶瓷,通过X射线衍射、扫描电子显微镜、介电频谱和阻抗谱等手段研究了Fe对CaCu3Ti4O12陶瓷的结构和介电性能的影响.研究发现:CaCu3Ti4-xFex关键词: 巨介电常数 双阻挡层电容模型 界面极化  相似文献   

6.
曹蕾  刘鹏  周剑平  王亚娟  苏丽娜  刘成 《物理学报》2011,60(3):37701-037701
采用固相反应法制备了一系列CaCu3Ti4O12-xMgTiO3(x = 0, 0.25, 0.5, 1.0)复相陶瓷,研究了MgTiO3掺杂对CaCu3Ti4O12(CCTO)陶瓷相结构、显微组织、介电性能和I-V非线性特征的影响.研究发现:MgTiO3掺杂不仅使CC 关键词: I-V非线性系数')" href="#">I-V非线性系数 巨介电常数 压敏电压  相似文献   

7.
刘鹏  贺颖  李俊  朱刚强  边小兵 《物理学报》2007,56(9):5489-5493
采用固相反应法制备了CaCu3Ti4-xNbxO12(x=0,0.01,0.04,0.08,0.2)陶瓷,样品在x取值范围内形成了连续固溶体.在40Hz—110MHz频率范围对样品进行了介电频谱分析,实验结果表明,与纯CaCu3Ti4O12不同,含Nb试样除了在频率大于10kHz范围内出现的德拜弛豫 关键词: 巨介电常数 德拜弛豫 阻挡层电容 等效电路  相似文献   

8.
CaCu3Ti4O12陶瓷的介电特性与弛豫机理   总被引:2,自引:0,他引:2       下载免费PDF全文
成鹏飞  王辉  李盛涛 《物理学报》2013,62(5):57701-057701
本文采用Novocontrol宽频介电谱仪在-100 ℃–100 ℃温 度范围内、0.1 Hz–10 MHz频率范围内测量了表面层打磨前 后CaCu3Ti4O12陶瓷的介电特性, 分析了CaCu3Ti4O12陶瓷的介电弛豫机理. 首先, 基于对宏观“壳-心”结构的定量分析, 排除了巨介电常数起源于表面层效应的可能性; 其次, 基于经典Maxwell-Wagner夹层极化及其活化能物理本质的分析, 排除了巨介电常数起源于经典Maxwell-Wagner极化的可能性; 最后, 依据晶界Schottky势垒与本征点缺陷的本质联系, 提出了巨介电常数起源于Schottky势垒边界陷阱电子弛豫的新机理. 陷阱电子弛豫机理反映了CaCu3Ti4O12陶瓷本征点缺陷、 电导、介电常数之间的本质关系. 关键词: 3Ti4O12')" href="#">CaCu3Ti4O12 介电弛豫 Schottky势垒 点缺陷  相似文献   

9.
采用固相烧结法合成了单相巨介电常数氧化物CaCu3Ti4O12(CCTO).用阻抗分析仪分析了10—420 K温度范围内的介电频谱和阻抗谱特性,并结合ZVIEW软件进行了模拟.结果表明:温度高于室温时,频谱出现两个明显的弛豫台阶,低频弛豫介电常数随温度升高而显著增大,表现出热离子极化特点;温度低于室温时,频谱表现出类德拜弛豫,且高、低平台介电常数值基本不随温度变化,表现出界面极化特点和较好的温度稳定性.频谱中依次出现的介电弛豫对应于阻抗谱中 关键词: 3Ti4O12')" href="#">CaCu3Ti4O12 介电频谱 阻抗谱 Cole-Cole半圆弧  相似文献   

10.
利用传统的固相反应工艺,在不同的烧结温度下制备了一系列的CaCu3Ti4O12陶瓷样品,考察了其微观结构以及介电和复阻抗方面的电学性质.研究发现这些样品在微观结构方面可分为三种类型,高介电性与微观结构有着密切的关联性.室温下,样品的低频介电常数随陶瓷晶粒尺寸的增大而提高.随着测试温度的升高,不同微观结构类型的样品呈现出不同的电学性质的变化,但其中也存在着一些相同的特征.高温下,介电频谱呈现出一个低频介电响应和两个类Debye型弛豫色散,复阻抗谱呈现出三个Cole-Cole半圆弧.将实验上观测到的电学性质的起因归于陶瓷多晶微结构中的晶畴、晶界和晶粒内的缺陷. 关键词: 3Ti4O12')" href="#">CaCu3Ti4O12 微观结构 电学性质  相似文献   

11.
Investigations have been performed on lanthanum-modified layered ferroelectric bismuth titanate for composition Bi3.25La0.75Ti3O12 (BLT) using impedance spectroscopy to understand the role of microstructure on the dielectric properties of this important material. A wide range of frequency and a wide range of temperature passing through the Curie point were chosen for the measurement. The frequency dependence suggested an interfacial polarization controlled Maxwell–Wagner type relaxation at low frequencies, and the impedance spectrum correlated with the mathematical fitting indicated the presence of two types of interfaces, which were attributed to the metallurgical boundaries and the twinned planes parallel to the bismuth oxide layers inherent to the crystal structure within the metallurgical grains. A careful analysis of the dielectric properties, particularly the ac-conductivity analysis revealed that the grain boundaries did also follow their own Jonscher-like relaxation, and the overall relaxation of the sample changed to a purely grain boundary-limited response at low frequency to a pure grain-limited response at higher frequencies. And overall admittance of the ceramic sample neither follow unmodified nor modified Jonscher's law rather its behaviour can be well described by series addition of Jonscher's admittance corresponding to grain boundary and grain. It was demonstrated that the frequency response of the ac conductivity was related to the microstructure exactly in the same way as any other dielectric function, like the impedance or dielectric constant, a fact, which is not much emphasized in the open literature.  相似文献   

12.
A new layered perovskite compound, Ag2La2Ti3O10, was synthesized by an ion-exchange reaction of M2La2Ti3O10 (M = Na,K) with a AgNO3 molten salt. The crystal structure and the ionic conductivity of the ion-exchanged compound were investigated. The ionic conductivities attributed to the interlayer silver ions were observed at high temperatures. The ionic conductivity of Ag2La2Ti3O10 was much higher than that of Na2La2Ti3O10, while the interlayer sodium ions in Na2La2Ti3O10 and silver ions in Ag2La2Ti3O10 have almost the same rock-salt type coordination. The higher conductivity of Ag2La2Ti3O10 is probably due to the higher polarizability of silver ions.  相似文献   

13.
H Mahfoz Kotb  Mohamad M Ahmad 《中国物理 B》2016,25(12):128201-128201
We report on the measurements of the electrical and dielectric properties of Na_(1/2)La_(1/2)Cu_3Ti_4O_(12)(NLCTO) ceramics prepared by high energy ball-milling and conventional sintering without any calcination steps. The x-ray powder diffraction analysis shows that pure perovskite-like CCTO phase is obtained after sintering at 1025?C–1075?C. Higher sintering temperatures result in multi-phase ceramics due to thermal decomposition. Scanning electron microscope observations reveal that the grain size is in a range of ~ 3 μm–5 μm for these ceramics. Impedance spectroscopy measurements performed in a wide frequency range(1 Hz–10 MHz) and at various temperatures(120 K–470 K) are used to study the dielectric and electrical properties of NLCTO ceramics. A good compromise between high ε(5.7 × 10~3 and 4.1 × 10~3 at 1.1 k Hz and 96 k Hz, respectively) and low tan δ(0.161 and 0.126 at 1.1 k Hz and 96 k Hz, respectively) is obtained for the ceramic sintered at 1050℃. The observed high dielectric constant behavior is explained in terms of the internal barrier layer capacitance effect.  相似文献   

14.
陈延彬  张帆  张伦勇  周健  张善涛  陈延峰 《物理学报》2015,64(9):97502-097502
基于纳米尺寸下复合铁电材料和反铁磁性材料是一个探索多铁性材料有效的方法. 利用激光脉冲沉积制备出LaFeO3-YMnO3人工超晶格和掺入不同层LaFeO3, BiFeO3的Bi4Ti3O12的外延薄膜. 通过系统的X射线衍射、透射电子显微术、扫描透射电子显微术下的能量损失谱表征证明这些样品具有原子尺寸上清晰的界面和完整的层状结构. 磁性测试证明这些材料具有亚铁磁性. 特别是在0.5和1.5LaFeO3-Bi4Ti3O12中的亚铁磁性甚至能保持到室温. 就铁电性而言, 铁电性测试显示出LaFeO3-YMnO3和插入BiFeO3的Bi4Ti3O12样品中存在较大的漏电流, 而在0.5LaFeO3-Bi4Ti3O12样品中存在铁电性. 因此在0.5LaFeO3-Bi4Ti3O12中能够实现亚铁磁和铁电共存. 其次发现当掺入多层的钙钛矿(3层SrTiO3或2.5层LaFeO3)后, Bi4Ti3O12 的层状结构将出现结构失稳现象. 这些工作对于利用纳米复合开发新颖多铁性提供一些实例.  相似文献   

15.
钛酸盐因其优异的物理化学性能,可作为高放射性核废物(HLW)和锕系元素(钚)的重要候选固化材料之一。采用传统的陶瓷烧结工艺制备了多晶的Lu2Ti2O7和Lu2TiO5陶瓷材料。在室温下,用800 keVKr2+对两种材料进行辐照,辐照后的样品采用GIXRD进行表征,观察到两种样品都经历了先肿胀、然后再发生非晶相变的过程。不同的是Lu2Ti2O7的晶格肿胀程度大于Lu2TiO5。另外,Lu2TiO5样品的辐照到2×1014 ions/cm2时非晶含量达95.54%,而Lu2Ti2O7样品在此剂量下非晶含量只有74.66%。通过第一性原理计算了Lu2Ti2O7晶体的晶格肿胀随反位浓度的变化关系,结果表明,Lu2Ti2O7出现非晶前的晶格肿胀主要由阳离子反位导致,而Lu2TiO5是无序的萤石结构,其辐照所导致的晶格肿胀不含阳离子反位的贡献,晶格肿胀程度较低。  相似文献   

16.
The polycrystalline sample of LiFe1/2Ni1/2VO4 was prepared by a standard solid-state reaction technique and confirmed by X-ray diffractometry. LiFe1/2Ni1/2VO4 has orthorhombic crystal structure whose dielectric and electric modulus properties were studied over a wide frequency range (100 Hz–1 MHz) at different temperatures (296–623 K) using a complex impedance spectroscopy (CIS) technique. The frequency and temperature dependence of dielectric constant (εr) and tangent loss (tan δ) of LiFe1/2Ni1/2VO4 are studied. The variation of εr as a function frequency at different temperatures exhibits a dispersive behavior at low frequencies. The variation of the εr as a function of temperature at different frequencies shows the dielectric anomaly in εr at 498 K with maximum value of dielectric constant 274.49 and 96.86 at 100 kHz and 1 MHz, respectively. Modulus analysis was carried out to understand the mechanism of the electrical transport process, which indicates the non-exponential type of conductivity relaxation in the material. The activation energy calculated from electric modulus spectra is 0.38 eV.  相似文献   

17.
A tungsten-bronze ceramic oxide, Pb0.68K0.64Nb2O6, has been prepared by a standard solid-state reaction technique. Compound formation and phase identification has been confirmed by X-ray diffraction (XRD) studies. The dielectric permittivity and the loss tangent of the sample have been measured in a frequency range 45 Hz–5 MHz and a temperature range 35–590 °C. Electrical properties of the material were studied using an impedance spectroscopic technique. Detailed analysis of the impedance spectrum suggested that the electrical properties of the material are strongly temperature dependent. The Nyquist plots clearly showed the presence of bulk and grain boundary effect in the compound. The imaginary part of modulus at different temperatures shows a relaxation peak and its position shifts to higher frequency with increase in temperature. This suggests a temperature-dependent relaxation. The frequency dependent ac conductivity at different temperatures indicated that the conduction process is thermally activated process.  相似文献   

18.
沈杰  周静  石国强  杨文才  刘韩星  陈文 《物理学报》2013,62(11):117702-117702
通过对克劳修斯-莫索蒂方程的近似, 分析了钙钛矿结构微波介质陶瓷频率温度系数 (τf) 的主要影响因素, 发现改变材料介电响应中离子位移极化和电子位移极化的比例, 可调节频率温度系数的正负与大小. 通过电子结构计算和容忍因子分析, 预测引入(Zn1/3Nb2/3)4+对具有正温度系数 的CaTiO3进行B位取代将提高材料电子极化响应比例, 调节τf由正变负. 采用偏铌酸盐为前驱体, 通过固相反应法合成了Ca[(Zn1/3Nb2/3)xTi(1-x)]O3钙钛矿结构陶瓷, 并对其进行结构分析和性能测试, 实验结果与理论分析一致, 获得了具有近零频率温度系数的Ca[(Zn1/3Nb2/3)0.7Ti0.3]O3介质陶瓷材料. 关键词: B位复合钙钛矿陶瓷 谐振频率温度稳定性 极化机理 6八面体倾斜')" href="#">BO6八面体倾斜  相似文献   

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