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1.
实验确定了自行研制的L波段三维电子自旋共振成像(3D-ESRI)系统的检测灵敏度及成像分辨率指标. 用Tempo水溶液模型测量灵敏度结果表明: 样品体积为10 mm, 高30 mm,测量浓度1×10-4 mol/L水溶液的信噪比为S/N=4∶1;加梯度磁场后,样品浓度需>5×10-4 mol/L,样品体积为19 mm, 高30 mm时,获得的投影谱的信噪比可满足图像重建的需要. 用DPPH固体样品确定的成像分辨率结果<1 mm. 文中还对ESRI系统的
各项总体性能做了归纳总结. 相似文献
各项总体性能做了归纳总结. 相似文献
2.
本文先后用光致发光、核磁共振和电子自旋共振研究了单晶硅中硅氢键和氢致缺陷的性质。光致发光谱表明硅氢键引起了大量非辐射中心。观测和探讨了电子自旋共振测量与样品平均厚度的关系。本文克服了真空热处理中氢从表面扩散的困难,并避免了样品平均厚度大于1.00mm和小于0.85mm给电子自旋共振带来的困难,测得分别在纯氢气氛和氩气氛生长的单晶硅每立方厘米电子自旋数。对比二者,我们估算出氢的数量为4×1016/cm3,而硅氢键分离激活能约为0.1eV。前者与文献[6]和[10]符合得很好,后者比文献[11]测定的沉淀激活能低一个数量级。
关键词: 相似文献
3.
研究了掺杂纳米硅薄膜(nc∶Si∶H)中的电子自旋共振(ESR)及与之相关的缺陷态.样品是用等离子体增强化学气相沉积方法制成,为两相结构,即纳米晶粒镶嵌于非晶本体之中.对掺磷的nc-Si∶H样品,测量出其ESR信号的g值为1.9990—1.9991,线宽ΔHpp为(40—42)×10-4T,ESR密度Nss为1017cm-3数量级.对掺硼的nc-Si∶H样品,其ESR信号的g值为2.0076—2.0078,ΔH关键词:
纳米硅薄膜
微结构
电子自旋共振 相似文献
4.
用电子自旋共振(ESR)方法对非晶Ag+离子导体0.85AgI~0.15Ag4P2O7的热处理晶化过程进行研究,在样品中掺入微量(约1×10-3 g/g)的Mn2+或V4+离子作为自旋探针离子,它们的ESR谱强度随升温线性减弱,当样品完全晶化时ESR谱消失。这样测定的样品完全晶化的温度分别为98℃(掺Mn的)和108℃(掺V的).本文还对Mn2+和V4+的ESR谱进行了分析。 相似文献
5.
通过电子注入的方法制备了含氮空位色心单光子源的金刚石荧光纳米颗粒. 自旋回声测试结果表明, 纳米颗粒中氮空位色心的相干时间T2很短, 介于0.86 μs至5.6 μs之间. Ramsey干涉条纹测试结果表明, 氮空位色心NV1点的退相干时间T2* 最大, 为0.7 μs, 其电子自旋共振谱可分辨的最小线宽为1.05 MHz. 并且NV1点的电子自旋共振谱可分辨氮空位色心本身的14N核自旋与 氮空位色心电子自旋之间的2.2 MHz超精细相互作用, 这对于在金刚石纳米颗粒中实现核自旋的操控和多个量子比特的门操作具有重要意义.
关键词:
纳米颗粒
氮空位色心
电子自旋 相似文献
6.
用Na2O2-DMSO体系产生O2·的ESR研究 总被引:6,自引:0,他引:6
提出了Na2O2的二甲基亚砜(DMsO)/H2O溶液中产生超氧阴离子自由基(O2·)的新方法,用电子自旋共振仪(ESR)可直接检测到很强的O2·信号,研究了反应的条件及其O2·信号的特性,并用该法考察了茶多酚等清除剂对于超氧阴离子自由基的清除作用。结果表明本体系是产生O2·的有效方法,可用于超氧阴离子自由基清除剂的研究。 相似文献
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10.
本文用电子自旋共振研究了2,4-二[α-(羧甲硫基)乙基]次卟啉-Ⅸ及2,4-二{α-[3-(4-羧基四氢噻唑基)]乙基}次卟啉-Ⅸ在不同温度时经紫外-可见光辐照的自由电子变化情况。本文还测定了上述样品在有氧存在下及真空条件下辐照的自旋浓度(N)为1016~1017 Spin/g。本文讨论了上述样品在光辐照时的动力学行为。 相似文献
11.
We present a detailed analysis of phase sensitivity for a nonlinear Ramsey interferometer, which utilize effective mean-field interaction of a two-component Bose–Einstein condensate in phase accumulation. For large enough particle number N and small phase shift ? , analytical results of the Ramsey signal and the phase sensitivity are derived for a product coherent state | θ , 0 ? . When collisional dephasing is absent, we confirm that the optimal sensitivity scales as 2/N 3/2 for polar angle of the initial state θ = π /4 or 3π /4. The best-sensitivity phase satisfies different transcendental equations, depending upon the initial state and the observable being measured after the phase accumulation. In the presence of the collisional dephasing, we show that the N -3/2-scaling rule of the sensitivity maintains with spin operators J ^ x and J ^ y measurements. A slightly better sensitivity is attainable for optimal coherent state with θ = π /6 or 5π /6. 相似文献
12.
We report the development of a millimeter-wave electron-spin-resonance (ESR) measurement system at the University of Fukui using a 3He/4He dilution refrigerator to reach temperatures below 1 K. The system operates in the frequency range of 125–130 GHz, with a homodyne detection. A nuclear-magnetic-resonance (NMR) measurement system was also developed in this system as the extension for millimeter-wave ESR/NMR double magnetic-resonance (DoMR) experiments. Several types of Fabry–Pérot-type resonators (FPR) have been developed: A piezo actuator attached to an FPR enables an electric tuning of cavity frequency. A flat mirror of an FPR has been fabricated using a gold thin film aiming for DoMR. ESR signal was measured down to 0.09 K. Results of ESR measurements of an organic radical crystal and phosphorous-doped silicon are presented. The NMR signal from 1H contained in the resonator is also detected successfully as a test for DoMR. 相似文献
13.
The first principle method was applied to study the electronic structure and magnetic properties of the compound of Cu(HCO2)(NO3)(pyz). The density of states, the electronic structure and the spin magnetic moments are calculated. The results reveal that the compound has a ferromagnetic interaction arising from the bridging μ- HCO2− and pyz ligands, and the ferromagnetic properties come from the spin delocalization effect. The spin magnetic moment per molecule mainly comes from the Cu ion, but has little contribution from O, N and C anion. 相似文献
14.
Based upon the new designed helical resonator, the resonant radio frequency (RF) for trapping ions can be consecutively adjusted in a large range (about 12 MHz to 29 MHz) with high Q-factors (above 300). We analyze the helical resonator with a lumped element circuit model and find that the theoretical results fit well with the experimental data. With our resonator system, the resonant frequency near magic RF frequency (where the scalar Stark shift and the second-order Doppler shift due to excess micromotion cancel each other) can be continuously changed at kHz level. For 88Sr+ ion, compared to earlier results, the measurement accuracy of magic RF frequency can be improved by an order of magnitude upon rough calculation, and therefore the net micromotion frequency shifts can be further reduced. Also, the differential static scalar polarizability Δα0 of clock transition can be experimentally measured more accurately. 相似文献
15.
In previous investigations the formation of radicals induced by γ-irradiation in CR-39 samples has been studied by electron spin resonance (ESR) spectroscopy. On the other hand, all attempts fail to detect radicals in samples irradiated by particles (p, and neutrons). The present work succeeded in detection of radicals produced by charged particle radiation in CR-39 (TASTRAK). The detectors were irradiated with protons of 7 MeV and -particles of 3 MeV with fluences in the order of 1011–1012 particles/cm2. The observed ESR signal is composed of at least four different resonance lines for each of which we determined the amplitudes, g-factors, lifetimes and the G-value. The amplitude of the total ESR signal decreases rapidly with a short and a longer lifetime. About 5 days after irradiation the ESR intensity decreased to an undetectable value. The lowest detectable dose (LDD) is of the order of 1 kGy. 相似文献
16.
Luyan Li Hui Liu Xiaoguang Luo Xiao Zhang Weihua Wang Yahui Cheng Qinggong Song 《Solid State Communications》2008,146(9-10):420-424
Room-temperature ferromagnetism is found in polycrystalline CrxZn1−xO (0≤x≤0.091) films prepared by magnetron sputtering. The saturated magnetization is 0.58 μB/Cr with x=0.012, and decreases with increased Cr dopant. The Curie temperatures of the samples are above 400 K. First principles calculations based on density functional theory predict that the electrons of Cr-doped ZnO films at Fermi level are 100% spin polarized when two Zn sites are substituted by Cr atoms in the nearest neighbour configuration. The spin polarized carriers and the p–d hybridization between Cr and its four neighbouring O atoms are responsible for observed ferromagnetism. 相似文献
17.
用ESR方法对9种不同双吡啶高氯酸盐与氧化锌组成的非均相体系的光诱导电子转移过程进行了系统的研究。ZnO-PQ++-胶束-苯的分散系,经350nm~420nm的紫外光照后,PQ++被还原成PQ+。具有大共轭结构的PQ+的ESR信号较强。胶束的存在也可使ESR信号增强。当体系充氧时,PQ+信号消失,并有超氧阴离子基O2·和羟基·OH被检出。 相似文献
18.
C.I. Lee K.E. Lee Y.Y. Song H.J. Im S. Kimura Y.S. Kwon 《Infrared Physics & Technology》2008,51(5):488-490
Reflectivity spectra of CeIn3 are measured at 7, 30, 50, 100, 150, 200 and 300 K in wild energy regions from 6 meV to 30 eV. Optical conductivity spectra are obtained from a Kramers–Kronig’ relation. A hump in the optical conductivity σ1 is observed at about 500 cm−1 below 100 K, resulting from strong hybridization between conduction electrons and Ce 4f electronic states. The low frequency plasmon indicating the existence of heavy particles is also observed below coherence temperature T* 100 K. 相似文献
19.
The effects of DM interaction on the density-of-states, the dimerization and the phase diagram in the antiferromagnetic Heisenberg chain coupled with quantum phonons have been studied by a nonadiabatic analytical approach. The results show that the effect of the DM interaction is to increase the staggered antisymmetric spin exchange interaction order but to decrease the spin dimerization and their competitions result in the lattice dimerization ordering parameter to increase for large staggered DM interaction parameter β and decrease for small β. A crossover of β exists in which the dimerization ordering parameter changes non-monotonously. As the DM interaction parameter D increases, depending on the appropriate values of spin-phonon coupling, phonon frequency and β, the system undergoes phase transition from spin gapless state to gapped state or reversely and can even reenter between the two states. The relation between the phonon-staggered ordering parameter, the spin-dimer order parameter and the staggered DM interaction order parameter gives clearly their contributing weights to the lattice dimerization. 相似文献
20.
We designed a reconfigurable dual-interferometer coupled silicon nitride microring resonator.By tuning the integrated heater on interferometer's arms,the"critical coupling"bandwidth of resonant mode is continuously adjustable whose quality factor varies from 7.9×104 to 1.9×105 with the extinction ratio keeping higher than 25 dB.Also a variety of coupling spanning from"under-coupling"to"over-coupling"were achieved,showing the ability to tune the quality factor from 6.0×103 to 2.3×105.Our design can provide an adjustable filtering method on silicon nitride photonic chip and contribute to optimize the nonlinear process for quantum photonics and all-optical signal processing. 相似文献