共查询到19条相似文献,搜索用时 140 毫秒
1.
2.
3.
4.
采用1H-1H COSY,HMQC、HMBC等2D NMR技术对化合物(Et4N)2[Pd2(mp)2(μ-mpH)2]进行1H、13C NMR谱数据分析与归属,表明它在DMSO溶液中仍保持原有固体状态的分子结构. 相似文献
5.
利用1H-1H COSY,1H-13C HMQC,HMBC等2D NMR技术对一种新的配体1-(2-羧基苯基甲酰基)氨基硫脲(H3L)进行1H、13C NMR谱数据分析与归属,对于它与Cu+离子配位的化合物[Cu2(H3L)2Cl2](H2O)3也作了1H、13C NMR的测定,简单讨论了它的配位行为,粗略确定了它的结构. 相似文献
6.
7.
8.
吉士脱酮的1H及13C NMR研究 总被引:1,自引:1,他引:0
Gestodene是避孕药物18甲基炔诺酮的衍生物,动物实验表明它的孕激素活性为18甲基炔诺酮的3~5倍.本文采用各种2D NMR技术,包括:1H-1H COSY,1H-13C COSY和HMBC等,归属了它的1H和13C的谱线,并得到了有关质子间的偶合常数. 相似文献
9.
10.
11.
Kempgens P Raya J Elbayed K Granger P Rosé J Braunstein P 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,142(1):64-73
The first investigation and analysis of (59)Co 2D NMR homonuclear chemical shift correlation spectra are reported for the tetrahedral mixed-metal cluster HFeCo(3)(CO)(11)PPh(2)H. For this cluster in solution, the (59)Co 2D COSY and DQF COSY NMR spectra prove the existence of a scalar coupling between (59)Co nuclei. In order to obtain a value of this coupling, the 2D COSY and DQF COSY NMR spectra for a three-spin 7/2 AX(2) system have been simulated by numerical density matrix calculations. The comparison between experimental and theoretical 2D NMR spectra gives a spin-coupling constant |(1)J((59)Co - (59)Co)| = (115 +/- 20) Hz for this cluster. Experimental measurements of T(1) and of the line widths for cobalt 59 as well as theoretical (59)Co 1D NMR spectra are reported and support our findings. 相似文献
12.
Wail Al Zoubi Abbas Ali Salih Al‐Hamdani I Putu Widiantara Rehab Ghalib Hamoodah Young Gun Ko 《Journal of Physical Organic Chemistry》2017,30(12)
New ligand 4‐((2‐Hydroxy1‐naphthyl) methylene amino)‐1.5‐dimethyl‐2‐phenyl‐1H‐pyrazol‐3(2H)‐one (HL) was synthesized from the reaction of 2‐hydroxy‐1‐naphthaldehyde and 4‐aminophenaz one. A complexes of this ligand [VO(II)(HL)(SO4)], [Pt(IV)(L)Cl3], [Re(V)(L)Cl3]Cl, and [M(II)(L)Cl] (M═Pd(II), Ni(II), Cu(II)) were synthesized. The resulted compounds were characterized by IR, NMR (1H and 13C), mass spectrometry, element analysis, and UV‐Vis spectroscopy. Additionally, the spectroscopic studies revealed octahedral geometries for the Re(V), Pt(IV) complexes, and square pyramidal for VO(II), square planar for Pd(II) complex, and tetrahedral for the Ni(II) and Cu(II) complexes. Thermodynamic parameters (ΔE*, ΔH*, ΔS*, ΔG*, and K) were calculated using from the TGA curve Coats‐Red fern method. Therefore, hyper Chem‐8 program has been used to predict structural geometries of compounds in the gas phase. Finally, the synthesized Schiff base and its metal complexes were screened for their biological activity against bacterial species, 2 Gram‐positive bacteria (Bacillus subtilis and Staphylococcus aureus) and 2 Gram‐negative bacteria (Escherichia coli and Pseudomonas aeruginosa). 相似文献
13.
Meissner A Sorensen OW 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,143(2):431-434
J couplings between (13)C(alpha) and (1)H(N) across hydrogen bonds in proteins are reported for the first time, and a two- or three-dimensional NMR technique for their measurement is presented. The technique exploits the TROSY effect, i.e., the degree of interference between dipolar and chemical shift anisotropy relaxation mechanisms, for sensitivity enhancement. The 2D or 3D spectra exhibit E.COSY patterns where the splittings in the (13)CO and (1)H(N) dimensions are (1)J((13)C(alpha), (13)CO) and the desired (3h)J((13)C(alpha), (1)H(N)), respectively. A demonstration of the new method is shown for the (15)N,(13)C-labeled protein chymotrypsin inhibitor 2 where 17 (3h)J((13)C(alpha), (1)H(N)) coupling constants ranging from 0 to 1.4 Hz where identified and all of positive sign. 相似文献
14.
稀土配合物RE(TPTZ)Cl_3的合成、表征及荧光性能研究 总被引:1,自引:0,他引:1
首次以2,4,6-三吡啶基三嗪(TPTZ)与Sm, Eu, Tb和Dy氯化物反应,合成四种单一稀土配合物以及Tb分别1∶1掺Gd, Y, La的三种异核配合物。经元素分析、稀土络合滴定、摩尔电导率、红外光谱、紫外光谱和差热-热重测定表明,配合物的组成分别为RE(TPTZ)Cl3·3H2O(RE=Sm, Eu, Tb, Dy)和Tb0.5Ln0.5(TPTZ)Cl3·3H2O(Ln=Gd, Y, La);TPTZ作为三齿配体与稀土离子配位,即中心环提供一个N原子,两个吡啶环分别提供一个N原子;配合物中3个水分子与稀土离子配位,1个Cl-在外界,2个在内界,为1∶1型电解质;配合物内外界可能为[RE(TPTZ)(H2O)3Cl2] Cl,稀土离子的配位数为8。配合物的荧光光谱测试表明,四种单一稀土配合物中,Tb配合物发光最强;三种1∶1掺杂异核Tb配合物荧光强度大于纯Tb配合物,表明Y3+, La3+和Gd3+都可以敏化Tb3+的发光,其中Gd3+的敏化作用最强,Y3+次之,La3+最差。 相似文献
15.
Degradation of azo dye Acid black 1 using low concentration iron of Fenton process facilitated by ultrasonic irradiation 总被引:3,自引:0,他引:3
A combination of ultrasonic and low concentration iron (<3 mgL(-1)) of Fenton process (US/Fenton) has been used to treat wastewater containing Acid black 1 (AB1). The results show that the oxidation power of low concentration iron of Fenton could be significantly enhanced by ultrasonic irradiation. The degradation of AB1 in aqueous solution by US/Fenton can receive better results compared with either Fenton oxidation or ultrasonic alone. Many operational parameters, such as ultrasonic power density, the pH value, the Fe(2+) dosage, the H(2)O(2) dosage, AB1 concentration and the temperature, affecting the degradation efficiency were investigated. Also, the effects of various inorganic anions (such as Cl(-), NO(3)(-), CO(3)(2-), etc.) on the oxidation efficiency of US/Fenton were studied. Under the given test conditions, 98.83% degradation efficiency was achieved after 30 min reaction by US/Fenton. The effect of various inorganic anions was in the following decreasing order: SO(3)(2-)>CH(3)COO(-)>Cl(-)>CO(3)(2-)>HCO(3)(-)>SO(4)(2-)>NO(3)(-). The results show that the US/Fenton can be an effective technology for the treatment of organic dyes in wastewater. 相似文献
16.
17.
Solid state 13C, 31P and 195Pt NMR has been employed to study the electronic and geometric structure of the dimeric and polymeric sigma-acetylide complexes of platinum, trans-[ClPt(PnBu3)2-C identical to C-p-C6H4-C identical to C-Pt(PnBu3)2Cl] and trans-[-Pt(PnBu3)2-C identical to C-p-C6H4-C identical to C-]n. The 195Pt shielding tensor has been measured and analysed to reveal details about the electronic properties of the Pt-ligand bonds. 相似文献
18.
19.