| 1-(2-羧基苯基甲酰基)氨基硫脲及其Cu+配合物的NMR研究 |
| |
| 引用本文： | 吴达旭,沈旭.1-(2-羧基苯基甲酰基)氨基硫脲及其Cu+配合物的NMR研究[J].波谱学杂志,1998,15(6):547-550. |
| |
| 作者姓名： | 吴达旭 沈旭 |
| |
| 作者单位： | 中国科学院福建物质结构研究所 结构化学国家重点实验室, 福州 350002 |
| |
| 摘 要： | 利用1H-1H COSY,1H-13C HMQC,HMBC等2D NMR技术对一种新的配体1-(2-羧基苯基甲酰基)氨基硫脲(H3L)进行1H、13C NMR谱数据分析与归属,对于它与Cu+离子配位的化合物Cu2(H3L)2Cl2](H2O)3也作了1H、13C NMR的测定,简单讨论了它的配位行为,粗略确定了它的结构.
|
| 关 键 词： | 1-(2-羧基苯基甲酰基)氨基硫脲 铜(I)配合物 核磁共振波谱 |
| 收稿时间： | 1998-04-20 |
NMR STUDIES ON 1 (2 CARBOXYBENZOYL) THIOSEMICARBAZIDE AND ITS COPPER(I) COMPLEX |
| |
| Wu Daxu and Shen Xu.NMR STUDIES ON 1 (2 CARBOXYBENZOYL) THIOSEMICARBAZIDE AND ITS COPPER(I) COMPLEX[J].Chinese Journal of Magnetic Resonance,1998,15(6):547-550. |
| |
| Authors: | Wu Daxu and Shen Xu |
| |
| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 |
| |
| Abstract: | In this paper 1H-1H COSY, 1H-13C HMQC and HMBC 2D NMR techniques were used to analyze and assign the 1H and 13C NMR spectra of a new ly synthesized compound 1-(2-carboxy benzoyl)-thiosemicarbazide(H3L), The 1H、13C NMR spectra of its copper (I) complex Cu2(H3L)2Cl2](H2O)3 have also been measured.Its coordination property is briefly discussed, and the structure of the complex is suggested. |
| |
| Keywords: | carboxybenzoyl) thiosemicarbazide(H 3L) Copper (I) complex NMR |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《波谱学杂志》浏览原始摘要信息 |
| 点击此处可从《波谱学杂志》下载免费的PDF全文 |
