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采用固相萃取-气相色谱/质谱联用技术,建立了一种同时测定卷烟主流烟气中香兰素和乙基香兰素的方法。方法优化了萃取条件,考察了萃取溶剂、萃取时间对检测结果的影响。通过硅藻土固相萃取柱净化并浓缩后,选取DB-HeavyWAX毛细管柱进行目标物分离,以香兰素-d3作为内标,对香兰素和乙基香兰素进行定量分析。结果表明,香兰素和乙基香兰素在浓度0.2~20.0 mg/L范围内具有良好的线性关系,其检出限分别为9.1 ng/支和6.5 ng/支,回收率均在96.3%~107.7%之间。 相似文献
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香兰素在玻碳电极上的电化学行为及其循环伏安测定 总被引:1,自引:0,他引:1
在pH 7.5的Tris-HCl缓冲介质的底液中,在循环伏安图上在峰电位+0.54 V处可见到香兰素的灵敏的氧化峰.其峰电流Ip与香兰素的浓度在3.286×10-6~3.944×10-4mol·L-1范围内呈线性关系,检出限(3S/N)为1.643×10-6mol·L-1.据此提出了循环伏安测定香兰素的方法,并应用于测定巧克力中香兰素的含量.在巧克力试样中加入不同浓度的香兰素标准,按方法测定以求测定方法的回收率,研究了香兰素在玻碳电极上的电化学行为,结果表明:香兰素的电极过程具有吸附性和不可逆性. 相似文献
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建立了同时测定牛奶中香兰素与乙基香兰素含量的高效液相色谱法。首先对样品进行超声提取,再经酸沉淀蛋白质后进行分析。采用Ultimate XB–C18色谱柱,流动相为甲醇–0.01 mol/L磷酸溶液(体积比为30∶70),流速为1.0 mL/min,检测波长为276 nm。香兰素与乙基香兰素在0.5~10μg/mL范围内线性良好,检出限分别为5.68μg/L和12.8μg/L,平均加标回收率分别为99.8%,98.4%。该方法简便,准确度高,重现性好,可用于牛奶中香兰素与乙基香兰素的日常检测。 相似文献
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以香兰素和1,2-丙二醇为原料,以介孔分子筛MCM-41负载磷钨酸为催化剂,环己烷为带水剂,合成了香兰素1,2-丙二醇缩醛.考察了醛醇物质的量比、反应时间、带水剂用量、催化剂用量及负载量对产率的影响.实验表明,介孔分子筛MCM-41负载磷钨酸是合成香兰素1,2-丙二醇缩醛的理想催化剂,较优反应条件为:n(香兰素)∶n(1,2-丙二醇)=1∶2.4,负载量为50%,催化剂用量为反应物总质量的2.0%,带水剂环己烷15mL,回流反应2.0h,香兰素1,2-丙二醇缩醛的收率达92%以上. 相似文献
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乙基麦芽酚、香兰素和乙基香兰素是重要的食品添加剂,广泛用作糖果、饼干、饮料等的增香剂。然而,大剂量使用香兰素等香料有害健康。因此,测定食品中的这些香料具有重要意义。目前,国内外测定这些香料的方法主要有光度法、高效液相色谱法和电化学法等,且大多只进行单组分分析,而该3组分的同时测定尚未见报道。本实验在pH2.87的缓冲溶液中,应用偏最小二乘(PLS)法对乙基麦芽酚、香兰素和乙基香兰素重叠光谱进行解析,据此建立了简便、快速同时测定样品中香料3组分的新方法。 相似文献
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The electrical conductivity of hydrosols of ultradispersed diamonds was studied. The electromembrane method for cleaning and concentrating of ultradispersed diamonds in hydrosols was considered. The influence exerted by the concentration of the dispersed phase on the electrical characteristics of the cleaning process was analyzed. A mathematical relation making it possible to evaluate the output characteristics of the process and to determine the geometrical characteristics of the apparatus was proposed. 相似文献
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Katsuhiko Shinyama Yoshifumi Magari Tadayoshi Tanaka Hiroshi Nakamura Toshiyuki Nohma Ikuo Yonezu 《Research on Chemical Intermediates》2006,32(5):419-429
The effects of electroless nickel plating of a hydrogen-absorbing alloy on the cycle characteristics of a nickel-metal hydride
battery were investigated. The cycle life was improved by employing an electroless nickel-plated hydrogen-absorbing alloy
for the negative electrode, which retained the same high-rate level and low-temperature characteristics compared to a cell
using a non-plated hydrogen-absorbing alloy. The electroless nickel-plated hydrogen-absorbing alloy provided better electrochemical
characteristics when its surface was partly and tightly covered by nickel particles under optimal electroless plating conditions. 相似文献
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N. I. Afanas’ev S. B. Selyanina N. V. Selivanova 《Russian Journal of Applied Chemistry》2008,81(10):1851-1855
The influence of the initial wood species and polymolecular characteristics on the characteristics of the surface of solid-phase lignin was estimated, and the correlation of these parameters with the ability of kraft lignins to stabilize the oleic acid-water emulsion was examined. The kinetics of breakdown of emulsions stabilized with kraft lignin was studied. 相似文献
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The strength and rheological characteristics of polymer composite materials based on synthetic copolymers and various fillers were studied. The influence of the filler on the characteristics of composites was revealed. 相似文献
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Amit Ron Nick Fishelson Irena Shur Nathan Croitoru Dafna Benayahu Yosi Shacham-Diamand 《Colloids and surfaces. B, Biointerfaces》2009,74(1):127-135
The dielectric dispersion characteristics of cellular suspensions are fundamentally determined based on the analogy to composite dielectric materials when periodically and discrete arrangement of cells is assumed. However, under native physiological conditions, when flocculation and clamping events usually occur, those assumptions are usually not valid. In the framework of this study, an examination of irregularity effect on the dispersion characteristics of spherical cellular suspensions is presented. Here, the permittivity spectra of the suspensions have been determined by both measurements of living K562 cell suspensions and finite numerical simulations. Based on the measured and simulated spectra, the dispersion characteristics of the suspensions, for several destinies and arrangements of cells, have been quantitatively analyzed using the Havriliak–Negami empirical formula. Generally, a strong correlation between the low dispersion characteristics was observed as the concentration and density of the cells was increased. In addition, all characteristics found to be significantly deviated in comparison to the characteristics of a periodically arrayed suspension. However, when low-dense arrangement was assumed, the correlation found to be much lower when all characteristics found to be less perturbated. Based on a simple model of interacting cells, it is suggested that those deviations are related to intercellular interactions between adjacent cells. 相似文献
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The chromatographic behavior of adamantane derivatives as sorbates and sorbents was studied. The retention characteristics of adamantane derivatives and some organic compounds on an adamantylsilicone stationary phase were determined. The effect of various substituents on the chromatographic behavior of the compounds was examined. Correlations between the sorption and structural characteristics of adamantane derivatives were found. 相似文献
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The use of polymeric surfactants as stabilizers in miniemulsion polymerization was reviewed. The structural characteristics of reported polymeric surfactants were detailed and compared. The concept of multi-functional polymeric surfactants was evidenced. The specificities brought by polymeric surfactants in the process of miniemulsion polymerization in comparison to molecular surfactants were analysed for the stability of the initial monomer emulsion, polymerization kinetics and characteristics of the obtained latexes. The contribution of polymeric surfactants to the control of the characteristics of the obtained nanoparticles was detailed with regard to the nature of the core material and to the surface coverage. Polymeric surfactants can be seen as powerful tools for the design of original nanoparticles. On the basis of the available data, possible research topics are suggested. 相似文献
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The purpose of this study was to develop a new sustained-release phenylpropanolamine hydrochloride (PPA) bilayer caplets that consists of an immediate-release portion and a prolonged-release portion containing a hydroxypropylmethylcellulose 2208 (HPMC2208) matrix. Since PPA is a highly water-soluble drug, incorporation of 60% HPMC2208 level in the matrix was required for giving the product a PPA-slow releasing property. Difference in the viscosity grade of HPMC2208 in the matrices did not greatly influence the PPA dissolution characteristics from the matrices. Therefore, we formulated the prolonged-release portion consisting of 10% PPA, 30% excipients, and 60% HPMC2208 (Metolose 90SH4000) into the sustained-release PPA bilayer caplets. The PPA dissolution characteristics from the formulated bilayer caplets showed the prolonged dissolution profile after rapid dissolution and was close to the targeted profile calculated from PPA pharmacokinetics study. The manufacturing methods of the prolonged-release portion and the filling order of the prolonged-release portion in bilayer compression did not significantly affect the PPA dissolution characteristics from the bilayer caplets. The PPA dissolution characteristics from the bilayer caplets was pH independent. Moreover, the PPA dissolution characteristics from the bilayer caplets was not affected by mechanical shear. The sustained-release PPA bilayer caplets is expected to present constant prolonged-release of PPA after rapid dissolution in vivo without dissolution change due to pH and mechanical shear. 相似文献
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S. N. Yashkin B. A. Murashov Yu. N. Klimochkin 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2011,85(4):677-683
The thermodynamic characteristics of adsorption of iodobenzene, 2-iodothiophene, and 1- and 2-iodoadamantanes on the surface
of graphitized thermal carbon black were determined experimentally. The influence of the special features of the molecular
structure of the adsorbates on the thermodynamic characteristics of adsorption was studied. The atom-atom approximation of
the semiempirical molecular-statistical theory of adsorption was used to calculate the thermodynamic characteristics of adsorption
of the adsorbates using the newly determined potential function parameters of pair intermolecular interaction (φ(r)) of I with C atoms of the basal graphite face. For the example of isostructural monohalogenated benzenes, thiophenes, and
adamantanes, a comparative analysis of the contributions of the F, Cl, Br, and I atoms to the thermodynamic characteristics
of adsorption was performed for the nonspecific adsorption of these compounds on a plane graphitized carbon black surface. 相似文献
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C. V. Barros Leite G. B. Baptista E. C. Montenegro A. S. Paschoa 《Journal of Radioanalytical and Nuclear Chemistry》1985,90(1):145-150
A graphical method was developed to relate data from Rutherford backscattering spectrometry to sample characteristics, such as thickness and concentration profiles. The method was then applied to analyze these characteristics of a gold film. 相似文献