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1.
The properties of meso-tetraphenylporphine (TPP) aggregates formed in acidic aqueous-organic solutions are investigated by UV-vis spectroscopy. According to the absorption spectra, the Q band absorption of the aggregated TPP shows red shift and intensity enhancement, and a model that includes the participation of water molecules in a porphyrin aggregation complex is proposed, then a qualitative explanation based on Gouterman's excition coupling theory is presented. Calculations including eigenenergies, eigenstates and the transition dipole strength of the coupled states are carried out.  相似文献   

2.
Effects of configuration interaction on dielectronic recombination of Cu-fike gold ions through the 3d + e→4l′4l″ capture process are studied in the models of isolated configurations approximation, configuration mixing within 3d^94s4l′4″, and configuration mixing within 3d^94l4l′4l″ (l≥ 0), employing a relativistic distorted-wave approximation. Nonresonant raditive stabilizing transitions and decays to autoionizing levels followed by radiative cascades, as well as resonant stabilizing transitions from the resonant levels, are taken into account. The additional mixing with 3d^94l4l′4l″ (0 〈 l 〈 l′ 〈l″≤ 3) shifts slightly the peaks of cross section towards low energy. The rate coefficient at low temperature is dramatically changed. The rate coefficient at temperature above 100 eV is enhanced by a factor between 26% and 13%.  相似文献   

3.
We propose a quantum teleportation scheme for tripartite entangled coherent state (ECS) with continuous variable. Our scheme is feasible and economical in the sense that we need only linear optical devices such as beam splitters, phase shifters and photon detectors and employ three bipartite maximally ECSs as quantum channels. We also generalize the tripartite scheme into multipartite ease and calculate the minimum average fidelity for the schemes in tripartite and multipartite cases.  相似文献   

4.
The geometrical and electronic structures of nitrogen-doped β-SiC are investigated by employing the first principles of plane wave ultra-soft pseudo-potential technology based on density functional theory. The structures of SiC1-xNx (x = 0, 1/32, 1/16, 1/8, 1/4) with different doping concentrations are optimized. The results reveal that the band gap of β-SiC transforms from an indirect band gap to a direct band gap with band gap shrinkage after carbon atoms are replaced by nitrogen atoms. The Fermi level shifts from valence band top to conduction band by doping nitrogen in pure β-SiC, and the doped β-SiC becomes metallic. The degree of Fermi levels entering into the conduction band increases with the increment of doping concentration; however, the band gap becomes narrower. This is attributed to defects with negative electricity occurring in surrounding silicon atoms. With the increase of doping concentration, more residual electrons, more easily captured by the 3p orbit in the silicon atom, will be provided by nitrogen atoms to form more defects with negative electricity.  相似文献   

5.
By performing first-principles calculations, we study Li doping in a double-wall carbon nanotube where a (5,0) tube is confined inside a (14,0) tube. There are three possible sites for Li doping and two of them are energetically favorable. The change of energy band structure is closely related to the doping sites and the charge transfer is investigated. Bader charge analysis indicates that Li prefers to donate its electron to the inner (5,0) tube. Moreover, the Li capacity of the system can reach LIC4.75 which makes it a promising candidate for Li-ion battery materials.  相似文献   

6.
7.
Based on the multi-configuration Dirac-Fock method, theoretical calculations are carried out for the dielectronic recombination (DR) rate coefficients and the collision excitation rate coefficients of Sn^10+ ions. It is found that the total DR rate coefficient has its maximum value between 10eV and 100eV and is greater than either the radiative recombination or three-body recombination rate coefficients (the number of free electrons per unit is 10^21 cm^3) for the ease of Te 〉 1 eV. Therefore, DR can strongly influence the ionization balance of laser produced multi-charged tin ions. The related dieleetronie satellite cannot be ignored at low temperature Te 〈 5 eV.  相似文献   

8.
Adaptive optics can be used to compensate for the wave aberration of the human eyes to achieve high-resolution imaging in real time. However the correction & partial due to the limitation of hardware. We propose a kind of hybrid image post-processing method, which uses the blind deconvolution combined with the residual data in wavefront sensor to restore the partially adaptive optics corrected retinal image. This method is applied in the image restoration of the vivid human retinal images. The results show that it is effective to improve the retinal image quality.  相似文献   

9.
The Raman signal of gas molecules is very weak due to its small scattering cross section. Here, a near-confocal cavity-enhanced Raman detection system is demonstrated. In the cavity, a high power light of 9W is achieved by using a cw 200mW 532nm laser, which greatly enhances the detection sensitivity of gas species. A photomultiplier tube connected to a spectrometer is used as the detection system. The Raman spectra of the mixed gases separated from transformer oil has been observed. The relationship of absolute Raman intensity and gas pressure is also obtained. To our knowledge, this is the first Raman system to detect the gases separated from transformer oil.  相似文献   

10.
A hypothesis is brought forward that the materials with low propagation loss in both optical and microwave band may exhibit good performance in terahertz (THz) band because THz wave band interspaces those two wave bands. For the purpose-of exploring a kind of low-loss material for THz waveguide, Lu2.1Bi0.9Fe5O12(LuBiIG) garnet films are prepared by liquid phase epitaxy (LPE) method on a gadolinium gallium garnet (GGG) substrate from lead-free flux because of the good properties in both optical and microwave bands. In microwave band, the ferromagnetic resonance (FMR) linewidth of the film 2△H = 2.8-5.1Oe; in optical band, the optical absorption coefficient is 600cm^-1 at visible range and about 100-170cm^-1 when the wavelength is longer than 800nm. In THz range, our hypothesis is well confirmed by a THz-TDS measurement which shows that the absorbance of the film for THz wave is 0.05-0.3 cm 1 and the minimum value appears at 2.3 THz. This artificial ferromagnetic material holds a great promise for magnetic field tunable THz devices such as waveguide, modulator or switch.  相似文献   

11.
Spiral spectra of vortex beams with coma aberration are studied. It is shown that the orbital angular momentum (OAM) states of vortex beams with coma aberration are different from those aberration-free vortex beams. Spiral spectra of beams with coma aberration are spreading. It is found that in the presence of coma aberration, the vortex beams contain not only the original OAM component but also other components. A larger coma aberration coefficient and/or a larger beam waist will lead to a wider spreading of the spiral spectrum. The results may have potential applications in information encoding and transmittance.  相似文献   

12.
With the help of the homogeneous balance method, the Jacobi elliptic expansion method and the auxiliary equation method, the first elliptic function equation is used to obtain the Jacobi doubly periodic wave solutions of the (2+1)-dimensional B-type Kadomtsev-Petviashvili (BKP) equation and the generalized Klein-Gordon equation. The method is also valid for other (1+1)-dimensional and higher dimensional systems.  相似文献   

13.
We investigate the fragmentation of 158A GeV ^207Tpb projectiles with Bi, Pb, Cu and AI targets using CR-39 nuclear track detectors. The exposures were made at SPS-CERN. After the etching, the detectors were scanned using an optical microscope to collect the data of etched cone diameters and lengths. We measured the partial charge-changing cross sections using the data of etched cone lengths. The predicted cross sections are compared to similar measurements reported in literature and their dependences on projectile and target mass are described.  相似文献   

14.
We present a new filter scheme for magnetocardiogram (MCG) signal processing based on the quasi-periodic characteristic of the signals. The key points of this scheme are to determine the exact numbers of data points in each cardiac cycle by using electrocardiogram (ECG) data acquired simultaneously with the MCG signal and to normalize the MCG data sequence in each cycle into an identical length. Compared with conventional filters, the scheme has the advantage of more powerful noise suppression with less signal distortion. The desire for having high quality output signals from raw MCG data acquired in a simple shielded room or even in unshielded environment may be realized with the scheme.  相似文献   

15.
By a method of hybrid physical-chemical vapour deposition (HPCVD) on three metal substrates of stainless steel, copper and niobium, we deposit MgB2 superconducting films over 1 μm thickness. All of them have zero resistance temperatures To(O) 〉 36 K and critical current densities Jc (IOK, OT) 〉106 A/cm^2. Meanwhile, in the bending test, all the MgB2 superconducting films adhere strongly to the metal substrates without peeling off. Therefore, the MgB2 superconducting films supplied by the HPCVD method exhibit preferable electrical, magnetic and mechanical properties, and have potential applications in future.  相似文献   

16.
The spontaneous evolution from ultracold Rydberg atoms to plasma is investigated in a caesium MOT by using the method of field ionization. The plasma transferred from atoms in different Rydberg states (n = 22-32) are obtained experimentally. Dependence of the threshold time of evolving to plasma and the threshold number of initial Rydberg atoms on the principal quantum number of initial Rydberg states is studied. The experimental results are in agreement with hot-cold Rydberg-Rydberg atom collision ionization theory.  相似文献   

17.
We propose to utilize the leading pulse of a petawatt class laser to create a conic plasma channel in the dense plasmas. This plasma channel could serve as a natural cone to guide the main pulse to the cone tip, as behaves similarly to the physical Au cone. We estimate that the leading pulse of a petawatt laser could create a natural cone with cone tip only about 100 μm away from the edge of compressed core plasma. The natural cone formation should be compatible for a good uniform compression and efficient fast heating of the imploded fuel.  相似文献   

18.
The translocation of polymer chain through a small pore from a high concentration side (cis side) to a low concentration side (trans side) is simulated by using Monte Carlo technique. The effect of the polymer--pore interaction on the translocation is studied. We find a special interaction at which the decay of the number of polymer chain, N, at the cis side obeys Fick's law, i.e. N decreases exponentially with time. The behaviour is analogous to the diffusion of hard sphere.  相似文献   

19.
A closed-form model for electrostatic potential distribution in the direction normal to the channel for double-gate (DG) MOSFETs is presented. The effects of doping (NA for nMOS) and minority carriers both are taken into account for the first time, in solving Poisson's equation analytically. Excellent agreement between model-predicted results and numerical device simulation is achieved for a wide range of body thickness, light or high channeldoping, under various bias conditions. This complete closed form for position-dependent potential distribution has wide applications for MOS compact modelling and device design.  相似文献   

20.
Based on the Hirota method and the perturbation technique, the N-soliton solution of a generalized Hirota-Satsuma coupled KdV equation is obtained. Further, the N-soliton solution of a complex coupled KdV equation is given by reducing.  相似文献   

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