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排序方式: 共有143条查询结果,搜索用时 93 毫秒
1.
Yupeng Xing Xiaoke Wang Shuhua Hao Xueli Zhang Xiao Wang Wenxuan Ma Gang Zhao Xijin Xu 《中国化学快报》2021,32(1):13-20
g-C3N4 have been widely used in the fields of photocatalytic hydrogen production,photocatalytic degradation of dyes and oxidative degradation of toxic gases due to their excellent performance.It has attracted extensive attention in recent years due to its highly efficient photocatalytic capacity of hydrogen generation,water oxidation,carbon dioxide reduction and degradation of organic pollutants.Because of the abundant carbon and nitrogen composition of the earth,large-scale production and industrial applications of this material are possible.The modification of this material makes its performance more excellent so that this new material can obtain a steady stream of vitality.These outstanding works have become important materials and milestones on the road to mankind's photocatalytic hydrogen production.This review will begin with the basic idea of designing,synthesizing and improving g-C3N4 based photocatalytic materials,and introduce the latest development of g-C3N4 photocatalysts in hydrogen production from four aspects of controlling the carbon/nitrogen ratio,morphology,element doping and heterojunction structure of g-C3N4 materials. 相似文献
2.
此篇论文将介绍一个用于半导体光罩上图样设计以及可用于实际生产的光刻反向计算技术(ILT)。在论文中将讨论有关ILT的最新发展,包括在超成像极限协助图样(SRAF)的生成,可增加制程宽容度的ILT,以及如何生成满足光罩生产标准的图样等方面。从内部的研究结果和客户的使用结果可以看出,ILT已经不再只是一种用于研究的工具,而是已经可以用于先进半导体制程的大规模生产。在对各个环节优化之后,ILT可以增加制程的宽容度,同时将光罩的成本控制在可以接受的水平。 相似文献
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本文利用F~-诱导Si-O键断裂原理,以亚胺香豆素为荧光母体,成功合成了一种比色和荧光增强型F~-探针。由于探针分子结构的自由度较大,探针分子在乙腈溶液中几乎没有荧光,但随着F~-的加入探针分子经历Si-O键断裂及成环反应,生成具有较大共轭结构的环化产物,其荧光光谱在452nm处呈现出显著的荧光峰(荧光增强46倍),溶液的最大吸收峰由315nm红移至410nm(红移95nm),溶液的颜色由无色变为黄色,适用于裸眼检测F~-。同时,相对于其他阴离子(Cl~-、Br~-、I~-、NO_3~-、HSO_4~-、ClO_4~-、Ac~-、H_2PO_4~-),探针分子表现出对F~-较高的选择性和专一性,为F~-浓度的监测提供了一种高效灵敏的分析方法。 相似文献
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The composition of the surface film formed on pure iron was investigated in a solution of 0.05 M NaOH and 0.05 M NaCl. Raman spectra of the film were recorded in situ during anodic polarisation over the passive region after addition of the NaCl to the electrolyte, under conditions of preresonance enhancement using excitation at 636.4 nm. Multivariate curve resolution with alternating least squares analysis was applied to the spectra to measure the relative amounts of different iron oxide and oxyhydroxides in the film at different potentials. The water content was also determined in this way from Raman spectra recorded using excitation at 514.5 nm. It was found that the composition of the film and the amount of incorporated water were influenced by the applied anodic potential. The results show that stable pitting can occur when the composition changes from the primary constituents β‐FeOOH and Green Complex (a hydrated, amorphous magnetite) with smaller amounts of γ‐Fe2O3 and γ‐FeOOH, to δ‐FeOOH and Green Complex, simultaneously with a reduction in water content. These changes result in conditions that favour the rate of localised breakdown of the film by Cl− ions over the rate of repassivation by water in the passive film. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
6.
基于烧结工艺和丝网印刷技术,研发了一种新的沟槽形冷阴极.底部绝缘层由黑色绝缘浆料被烧结后制成,且在底部绝缘层中存在倾斜面.将银浆丝网印刷在条形电极上,依次经烘烤和烧结工艺后形成银电极.利用细砂纸,对银电极进行适当的抛光工艺,以便获得光滑的电极表面.由于特有的银电极形状,从而易于获得更大的场增强因子.将碳纳米管制备在银电极上,形成场发射极.致密的碳纳米管层完全覆盖银电极表面,特有的边缘场增强效应能够使得碳纳米管发射出更多的电子.顶部绝缘层则用于抑制碳纳米管的横向电子发射.结合沟槽形冷阴极,制作了三极结构的场致发射显示器,该显示器具有良好的场致发射特性及优良的发光图像均匀性.与普通冷阴极场致发射显示器相比,沟槽形冷阴极场致发射显示器能够将开启电场从1.86V/μm降低到1.78V/μm,将最大场致发射电流从1 537μA增加到2 863μA,且将最大发光图像亮度从1 386cd/m2提高到1 865cd/m2.该制作技术在场致发射显示器中具有较强的实际应用性. 相似文献
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J. E. Beasley R. L. Anderson J. P. Dickie F. R. Dollish E. C. Tynan Teh Fu Yen 《光谱学快报》2013,46(5):149-156
A Digital Equipment Corporation PDP 8/S Computer is interfaced with an EPR Spectrameter to achieve signal enhancement. A computer-based system for spectrum accumulation and noise averaging of EPR or NMR signals has been designed and implemented. The computer-based system was chosen over other perhaps more conventional systems because of its greater flexibility in the processing of spectra, especially after the accumulation is complete.(1) 相似文献
9.
Young-Geun Han Won-Taek Han Byeong Ha Lee Un-Chul Paek Youngjoo Chung Chang-Seok Kim 《Fiber and Integrated Optics》2013,32(6):591-600
We will present in this work the quantitative analysis of the relationship between the doping concentrations of GeO 2 and B 2 O 3 in the core and cladding regions and the temperature sensitivity of the resonance wavelength shift in long-period fiber gratings (LPFGs). Based on this analysis, the temperature sensitivity was suppressed and enhanced to 0.002 nm/C and 0.28 nm/C, respectively. We will also discuss the effect of the residual mechanical stress on the optical and mechanical properties of LPFGs. In particular, we will present the measurement results of the dependence of the refractive index change and mechanical strength on the residual mechanical stress in the boron-doped fibers with depressed clad and matched clad. 相似文献
10.
Fluorescence spectroscopic properties of the complex formation between six new C-pivot16-crown-5 ethers bearing fluorescence side arms and metal ions are studied. Six new C-pivot 16-crown-5 ethers that carry fluorescence side arms were synthesized. The research also included the examination of different fluorescent behavior of the new lariat ethers in the presence of silver and sodium ions (Ag+ and Na+) in methanol. Because of the good fit of the cavity size of these 16-crown-5 ethers with the Ag+ and Na+ ions, remarkable change in fluorescent spectra were observed. The results showed that the new lariat crown ethers exhibited enhanced selectivity towards sodium ion, but silver ion show quenching abilities towards the ligands. Cooperative participations of the C-pivot side arm oxygen with the ring oxygen molecules in complexation was also confirmed by the single crystal X-ray crystallography of the complex, (C27H30O7)·NaClO4. The freezing of crown ring conformation and the diminishment of the chance of sidearm oscillation that occurred upon complexation with sodium ion are the main causes of fluorescent enhancement. The quenching caused by the addition of silver ion was found to explainable by the photo-induced electron transfer that results in the reduction of silver ions. 相似文献