90Mo电磁跃迁几率的测量

利用束流能量为116MeV的⁵⁹Co(³⁵Cl,2p2n)⁹⁰Mo反应布居⁹⁰Mo的高自旋态.用10台反康普顿HPGe探测器组成的探测阵列进行γγ符合测量.通过多普勒展宽峰的形状分析测定⁹⁰Mo高自旋态的寿命.在正宇称衰变系观察到增强的M1跃迁,推断I=13以上是扁椭形变.负宇称高自旋态具有大的B(E2)值,并随自旋增大而起伏变化.正、负宇称态之间的跃迁显示增大的E1跃迁,似有八极关联的可能.但是,⁹⁰Mo并不处在理论预言的存在八极形变的核区内.     

双阱势能级研究

本文通过作图研究了一维无限深势阱中引入势垒后的能级变化情况.随着双阱势中势垒高度V0的不断增大,相邻的奇宇称能级与偶宇称能级逐渐接近,当V0→∞时,二者相等,能级由原来的非简并变成了简并.文章还讨论了V0可以看成微扰的范围.     

84Rb的高自族态研究

利用75MeV的¹⁸O束流,通过⁷⁰Zn(¹⁸O,p3n)反应布居了⁸⁴Rb核的高自旋态,测量了激发函数,γ–γ符合及DCO比值,新观察到了40个能级,50多条γ跃迁,建立了到目前为止最完整的能级纲图,其正负宇称分别推高到了17⁺和17^－.通过与Rb各奇–奇同位素核和N=47的各奇–奇核比较,发现它们的结构非常相似.     

Novel Fe_3O_4@SiO_2@Ag@Ni trepang-like nanocomposites:High-efficiency and magnetic recyclable catalysts for organic dye degradation

A facile step-by-step approach is developed for synthesizing the high-efficiency and magnetic recyclable Fe_3O_4@SiO_2@Ag@Ni trepang-like nanocomposites.This method involves coating Fe_2O_3 nanorods with a uniform silica layer,reduction in 10%H_2/Ar atmosphere to transform the Fe_2O_3 into magnetic Fe_3O_4,and finally depositing Ag@Ni core-shell nanoparticles on the L-lysine modified surface of Fe_3O_4@SiO_2 nanorods.The fabricated nanocomposites are further characterized by x-ray diffraction,transmission electron microscopy,scanning electron microscope,Fourier transform infrared spectroscopy,and inductively coupled plasma mass spectroscopy.The Fe_3O_4@SiO_2@Ag@Ni trepang-like nanocomposites exhibit remarkably higher catalytic efficiency than monometallic Fe_3O_4@SiO_2@Ag nanocomposites toward the degradation of Rhodamine B(RhB) at room temperature,and maintain superior catalytic activity even after six cycles.In addition,these samples could be easily separated from the catalytic system by an external magnet and reused,which shows great potential applications in treating waste water.     

Multi-polar resistance switching and memory effect in copper phthalocyanine junctions

Copper phthalocyanine junctions, fabricated by magnetron sputtering and evaporating methods, show multi-polar （unipolar and bipolar） resistance switching and the memory effect. The multi-polar resistance switching has not been observed simultaneously in one organic material before. With both electrodes being cobalt, the unipolar resistance switching is universal. The high resistance state is switched to the low resistance state when the bias reaches the set voltage. Generally, the set voltage increases with the thickness of copper phthalocyanine and decreases with increasing dwell time of bias. Moreover, the low resistance state could be switched to the high resistance state by absorbing the phonon energy. The stability of the low resistance state could be tuned by different electrodes. In Au/copper phthalocyanine/Co system, the low resistance state is far more stable, and the bipolar resistance switching is found. Temperature dependence of electrical transport measurements demonstrates that there are no obvious differences in the electrical transport mechanism before and after the resistance switching. They fit quite well with Mott variable range hopping theory. The effect of A1203 on the resistance switching is excluded by control experiments. The holes trapping and detrapping in copper phthalocyanine layer are responsible for the resistance switching, and the interfacial effect between electrodes and copper phthalocyanine layer affects the memory effect.     

~(84)Rb的高自族态研究

利用75MeV的18O束流，通过70Zn（18O，p3n）反应布居了84Rb核的高自旋态，测量了激发函数，γ－γ符合及DCO比值，新观察到了40个能级，50多条γ跃迁，建立了到目前为止最完整的能级纲图，其正负宇称分别推高到了17+和17-．通过与Rb各奇-奇同位素核和N＝47的各奇-奇核比较，发现它们的结构非常相似．     

NdFeB纳米复合永磁材料的交换耦合相互作用和有效各向异性

以Nd₂Fe₁₄B/αFe为例，采用立方体晶粒结构模型，研究了纳米复合永磁材料中不同磁性晶粒间的交换耦合相互作用和有效各向异性.纳米复合永磁材料的有效各向异性Keff等于软、硬磁性相各向异性的统计平均值，每个晶粒的各向异性由晶粒表面交换耦合部分和晶粒内部未交换耦合部分的各向异性共同确定.计算结果表明，软、硬磁性相晶粒尺寸分布显著地影响有效各向异性Keff的值.当软、硬磁性晶粒尺寸D相同时，Keff随晶粒尺寸和硬磁性相体积分数的降低而减小, 当D<20nm 时，K 关键词： 纳米复合永磁材料 交换耦合相互作用 有效各向异性 晶粒尺寸     

奇奇核170Ta高自旋态及旋称反转研究

用97MeV的¹⁹F束通过¹⁵⁵Gd(¹⁹F,4n)¹⁷⁰Ta反应布居了奇奇核¹⁷⁰Ta的高自旋态,将¹⁷⁰Ta的3个转动带推向了更高的自旋态,并观测到了半退耦带的旋称反转点,将其自旋值定在了19.5h.首次比较系统地总结了稀土区半退耦带的旋称反转系统规律,并比较了该核区半退耦带与晕带的系统性差异,特别是这两个带在能量劈裂程度上存在着系统性差异.从这一现象出发,探讨了半退耦带与晕带旋称反转系统性差异的成因,指出p-n剩余相互作用在这一现象中起着非常重要的作用.     

纳米Nd2Fe14B永磁材料的有效各向异性随晶粒尺寸的变化

以纳米Nd2Fe14B硬磁材料为例, 从Herzer的随机各向异性理论出发, 采用立方体晶粒结构模型, 建立了纳米硬磁性晶粒之间的部分交换耦合模型, 研究了材料的有效各向异性随晶粒尺寸的变化关系.结果表明: 晶粒之间的交换耦合相互作用随晶粒尺寸的减小而增强, 材料的有效各向异性Keff随晶粒尺寸的减小逐渐下降. Keff随晶粒尺寸的变化规律与矫顽力的变化规律基本相似, 纳米Nd2Fe14B硬磁材料矫顽力的下降主要由有效各向异性的减小引起.     

(Nd,Dy)13.5Fe80B6.5合金铸片的微结构研究

研究了铸片工艺制备的(Nd,Dy)13.5Fe80B6.5铸片的微结构。结果表明:铸片主要由2∶14∶1相片状晶组成且存在明显的择优取向,晶粒沿[00l]方向择优生长;取向度随轮速改变发生明显的变化,在v=1.5～2m·s-1时取最大值。当v=2m·s-1时铸片由厚度约3μm、且被0.2～0.5μm的富Nd相薄层隔开的2∶14∶1相片状晶组成,铸片中不存在α Fe枝状晶。