利用三级质谱与二级质谱匹配策略鉴定丹参中酚酸类成分

多级质谱信息(MS/MS information)可提供鉴定化合物结构的关键线索,多级质谱(MS/MS)图谱到结构的转换(MS/MS spectrum to structure)是精准鉴定化合物结构的重要过程。本研究提出了化合物的三级质谱(MS³)图谱与其结构单元的二级质谱(MS²)图谱匹配策略,实现了化合物结构的精准鉴定。首先,利用三重四极杆复合线性离子阱质谱仪(Qtrap-MS)的双碰撞池,采集酯类化合物酯基质谱裂解产生的特征碎片离子(c^–和y^–)在线性离子阱(LIT)内经第二次碰撞诱导解离(Collision-induced dissociation, CID)后的MS³图谱,并同步采集其结构单元化合物([M–H]^–)在LIT中经碰撞诱导解离后的MS²图谱,结果表明,酯类化合物特征碎片离子的MS³图谱与结构单元化合物的MS²图谱匹配。最后,采用HR-MS/MS对丹参总酚酸(Total ...     

Design study on very low Beta spoke cavity for China-ADS

Very low Beta superconducting spoke cavity is one of the key challenges for the China-ADS project. In this paper, a new structure of 3βλ/2 spoke cavity is first studied in detail. Its RF and mechanical properties are simulated using CST-MWS and ANSYS, and compared with the traditional βλ/2 spoke structure.     

基于小波回声状态网络的混沌时间序列预测

混沌现象普遍存在于自然界及人类社会中,因此混沌时间序列预测具有重要意义. 提出了一种新的混沌时间序列预测模型------小波回声状态网络,该模型可以有效克服传统回声状态 网络模型中普遍存在的病态矩阵问题,提高了混沌时间序列预测精度.通过对Lorenz、含噪声Lorenz 及间歇式反应釜釜温三个时间序列的预测,将小波回声状态网络与传统回声状态网络进行了比较. 结果表明,小波回声状态网络与传统回声状态网络相比,预测精度提高一倍以上且预测结果更加稳定.     

嵌入硅基多孔氧化铝中的荧光染料的发光性质研究

3种不同的荧光染料被分别嵌入硅基多孔氧化铝模板中,并且在室温下得到了蓝光、绿光和红光波长的荧光发射.实验中同时观测到上述荧光光谱的蓝移现象.研究结果表明,荧光染料沉积在不同的模板(如硅基多孔氧化铝、多孔硅)中,其相互作用的机理是不同的.模板发光机制的差异将直接影响荧光染料的发光性质.     

Development of a 325 MHz β =0.12 superconducting single spoke cavity for China-ADS

Twelve very low Beta superconducting single spoke cavities, whose Beta is only 0.12 (Spoke012) when operating at 325 MHz, are adopted in Injector I for China-ADS linac. This type of spoke cavity is believed to be one of the key challenges for its very low geometric Beta. So far, in collaboration with Peking University and Harbin Institute of Technology, IHEP has successfully designed, fabricated, and tested the Spoke012 prototype cavity. This paper presents the details of the design, fabrication and test results for Spoke012 prototype cavity.     

Design of a 325 MHz SC Spoke040 cavity at IHEP

A spoke cavity is a TEM-class superconducting resonator with particular advantages: compact structure and high shunt impedance. The 325 MHz β =0.40(β =v/c, v is the velocity of particle and c is the velocity of light)single spoke cavity(Spoke 040) is adopted for the Chinese ADS(Accelerator Driven Sub-critical System) project. The physics and mechanical design has been accomplished, and the fabrication of a prototype is currently in progress. In this paper, the optimization processes for the main radio frequency(RF) and mechanical parameters are analyzed in detail. Two kinds of cavity end-walls(flat and convex) are compared. The convex end-wall is preferred in order to improve mechanical performance of the cavity. Two prototypes of the Spoke 040 cavity are in the machining stage,and should be finished in early 2014.Vertical testing is also under preparation.     

Low beta spoke cavity multipacting analysis

The simulation and analysis for electron multipacting phenomenon in a low β spoke superconducting cavity in ADS proton accelerator are proposed. Using both CST and Track3P codes, the electron multipacting calculation for β=0.12 spoke superconducting cavity is implemented. The methods of multipacting calculation on both codes are studied and described. With the comparison between the calculation results and the cavity vertical test result, the accuracy and reliability of different codes on calculating multipacting are analyzed. Multipacting calculation can help to understand the results of vertical test and also can help to do the optimization in cavity design.     

A tuning system for BEPCⅡ

The tuning system plays a very important role when a superconducting cavity is in operation. It cooperates with other control loops to adjust the cavity frequency with high precision, reduce the reflection power, guarantee the stability of beam, and ensure the safety of the superconducting cavity. This paper focuses mainly on the tuning system working principle, the working state and problems that Beijing Electron Positron Collider (BEPC ) has encountered during operation.     

Horizontal test for BEPC 500 MHz spare cavity

The horizontal test for the BEPC 500 MHz spare cavity has been completed at IHEP. The maximum voltage of the cavity reached 2.17 MV, while Q 0 was 5.78 × 108 . The process and results of the high power horizontal test are presented and discussed in this paper.     

Horizontal test for BEPCⅡ 500 MHz spare cavity

The horizontal test for the BEPCⅡ 500 MHz spare cavity has been completed at IHEP. The maximum voltage of the cavity reached 2.17 MV, while Q₀ was 5.78× 10⁸. The process and results of the high power horizontal test are presented and discussed in this paper.