驾驶员预估效应下车流能耗演化机理研究

考虑实际交通中驾驶员预估效应对车辆跟驰行为的影响, 提出了一个改进跟驰模型. 采用线性稳定性理论获得了该模型的线性稳定性判据. 运用数值仿真的方法, 系统研究了驾驶员预估效应下车流的整体平均能耗和单车能耗的演化机理. 研究结果表明, 驾驶员预估效应能显著提高车流稳定性, 且随着驾驶员预估时长的增加, 车流的整体平均能量损耗和单车能量损耗将逐渐降低.     

5-L-孟氧基4-苄氨基丁烯内酯的不对称合成和晶体结构研究

温和条件下,苄胺与手性合成子5-(L)-孟氧基3-溴-2(5)呋喃酮通过串联的不对称迈克尔加成/分子内消除反应合成了一种新手性化合物:5-L-孟氧基-4-苄胺基丁烯内酯。产物经过IR、1H-NMR、MS谱学表征,并经X-ray单晶衍射测定了其结构。新化合物属于正交晶系,P212121空间群,a=5.2945(4),b=14.2829(10),c=26.0769(18),Mr=343.45,Z=4,V=1972.0(2)3,Dc=1.157g/cm3,μ(MoKα)=0.076mm-1,F(000)=744,R=0.0387,wR=0.0880。     

A new coupled map car-following model considering drivers’ steady desired speed

Based on the pioneering work of Konishi et al., in consideration of the influence of drivers＇ steady desired speed ef/ect on the traffic flow, we develop a new coupled map car-following model in the real world. By use of the control theory, the stability condition of our model is derived. The validity of the present theoretical scheme is verified via numerical simulation, confirming the correctness of our theoretical analysis.     

一种适用于193nm光刻胶的硫盐光产酸剂的制备与性质

制备了一种阳离子含有萘基,阴离子分别为对 甲苯磺酸、甲磺酸及三氟甲磺酸的硫盐.它们有高的热解温度和在常用有机溶剂中较好的溶解性.测定了此类光产酸剂在水溶液及聚乙二醇固体膜层中的紫外吸收特性.结果表明,阴离子不含苯基时,在193nm处有很好的透明性.考察了其在低压汞灯照射下的光解性质,在254nm附近的吸收峰随光解进行迅速减弱.此类光产酸剂适用于氟化氩激光(193nm)等的化学增幅型光致抗蚀剂.     

在表面活性剂存在下用T(4-TAP)P作显色剂导数光度法同时测定铜和锌

前言卟啉类试剂在光度法中作为高灵敏显色对金属离子的测定有很多报导,一般都采用常规光度法进行单个元素的测定,其ε值均在1×10~5—4×10~5之间。用卟啉作显色剂的导数光度法测定微量金属离子,文献曾报导过,但尚未见到在表面活性剂存在下,用卟啉作显示剂的导数光度进行二种金属离子用时测定的报道。导数光度法是测量吸光度对波长的导数输出信息d~n/dλ~n,对提高光度法的灵敏度、准确度、选择性,或实现多元素连测等方面都较常规光度法优越。本文试验表明:T(4-TAP)P     

矿石中微量铍的快速测定——铬天菁R-溴代十六烷基吡啶光度法

近年来已应用萤光光度法测定铍,而作为提高二元络合物灵敏度的胶束增溶法也日益增多。本文提出了在溶液pH为4.3—6.0的条件下,Be~2+与依来铬天菁R及溴代十六烷基吡啶生成三元络合物,其最大吸收波长在590毫微米处,克分子吸收系数达9×10~4。采用环己二胺四乙酸作掩蔽剂时,可消除大多数共存干扰离子的影响。因此,本法无需分离,可直接用于矿石中微量铍的测定,结果良好。     

Cochinchin from Dracaena cochinchinensis

A new compound, Cochinchin (1), together with 7,4‘-dihydroxyflavone (2), 7-hydroxy-4‘-methoxyflavane (3),7-hydroxy-3-(4-hydroxybenzyl)chroman (4), 4‘-hydroxy-2,4-dirnethoxydihydrochalcone (5) and 4‘-hydroxy-2,4,6-trimethoxydihydrochalcone (6) was isolated from the resin (trivial name, “dragon‘s blood“) of Dracaena cochinchinensis (Lour.) S. C. Chert. The structure of 1 was elucidated on the basis of spectroscopic data as (2,3-trans)-6-allyl-2-(3,5-dimethoxyphenyl)-3-(4-hydroxyphenyl)-2,3-dihydrobenzo[1,4]dioxin which is a natural product possessing a new framework.     

锰-meso-四(对磺基苯)卟啉高分子季铵盐胶束增敏显色反应的研究

本文研究了meso~-四(对磺基苯)卟啉(TPPS_4或H_2L~(4-))在高分子季铵盐存在下与锰的胶束增敏显色反应。探讨了一些有机碱对锰与TPPS_4作用增速的机理。实验表明,TPPS_4与高分子季铵盐在有辅助络合剂存在下,pH7.8-11.0的碱性介质中,可以与锰迅速地形成灵敏度极高(ε:3.2×10~5)的三元络合物。其最大吸收峰位于442nm。采用EDTA和TEA作掩蔽剂,45种金属离子和18种非金属物无干扰。本法为目前锰的光度法中灵敏度最高的方法。不需分离可直接测定化探样、矿石、生铁和合金钢中痕量的锰。     

炉内配风方式对锅炉经济性的影响

本文以炉内配风方式对锅炉经济性的影响为研究对象。当机组负荷为300 MW时,省煤器出口的最佳氧量为3.4％左右;当机组负荷为225 MW时,省煤器出口的最佳氧量为4.6％左右;就二次风的组合方式而言,在高温区保持适宜的氧气浓度,可以提高反应速度,保证煤粉颗粒的燃尽,提高锅炉的经济性,而燃尽风的风门开度选择主要考虑降低锅炉的气体排放物(丰要是NOx),对炉内燃烧效果影响不大。     

Feedback control scheme of traffic jams based on the coupled map car-following model

Based on the pioneering work of Konishi et al. [Phys. Rev. E （1999） 60 4000], a new feedback control scheme is presented to suppress traffic jams based on the coupled map car-following model under the open boundary condition. The effect of the safe headway on the traffic system is considered. According to the control theory, the condition under which traffic jams can be suppressed is analyzed. The results are compared with the previous results concerning congestion control. The simulations show that the suppression performance of our scheme on traffic jams is better than those of the previous schemes, although all the schemes can suppress traffic jams. The simulation results are consistent with theoretical analyses.