过渡金属掺杂在Bi2Te3体系中诱导产生的磁性

用从头计算方法研究了在Bi₂Te₃体系采用过渡金属掺杂从而诱导出磁性的可能性．用一个过渡金属原子置换一个Bi原子之后,可以在该体系中产生磁矩,这主要是由于过渡金属原子的3d轨道电子的自旋极化导致的．当一个Ti、V、Cr、Mn和Fe原子分别替代一个Bi原子时,体系显示的磁矩分别为0.92、1.97、2.97、4.04和4.98 μ_B．当引入两个过渡金属原子代替两个Bi原子的时候,交换耦合的特性取决于取代Bi原子的分布;代替的Bi原子的位置在Bi1和Bi5的位置时,这两个过渡金属原子之间的距离为11.52 ?, Bi_1.84TM_0.16Te₃体系能量最稳定并且表现出铁磁性耦合．     

CAFe DUMP前刮束器的设计研制

位于中国科学院近代物理研究所的超导直线加速器样机CAFe是一台质子超导直线加速器实验样机,围绕该装置的束流实验研究将为下一步设计研究加速器驱动次临界洁净核能系统(ADS)专用的超导直线加速器打下基础并提供经验。为了实现CAFe的10 mA束流指标,需要设计研制专门的束流收集器(DUMP)和对应的刮束器。本工作就CAFe DUMP前刮束器的研制进行了系统的设计和计算工作。刮束器面向束流侧的材料采用Al6063,确保束流轰击后的剩余放射性活度处于安全范围。基于蒙特卡罗粒子输运模拟,开展放射性核素及剩余剂量分析。结果表明,退役时刮束器外围剂量为可接受的百微希沃特每小时量级。通过ANSYS的热分析,计算了不同束流情况下刮束器的温度分布及温度变化,研究了刮束器在正常运行时移除热量的能力和在异常状况下应急保护的能力。计算结果表明,刮束器可以满足安全移除强流高功率束流束晕的设计需求。在CAFe高功率束流实验中,刮束器及DUMP运行正常,束流监测指标与设计一致,证明研制的刮束器实现了安全移除束晕、监测束流参数和保护DUMP的功能。     

一种应用于HIRFL-CSR上的非拦截式剩余气体电离束流剖面探测器(英文)

兰州重离子加速器冷却储存环主环（CSRm）上成功应用了一种剩余气体电离剖面探测器（IPM）,这种新型非拦截式剖面探测器的应用服役对CSRm的束流冷却研究及常规调束的实时剖面监测具有重要意义。IPM探测器通过收集束流与剩余气体之间的电离产物（气体离子或电子）,利用偏转静电场将电离产物加速至多重微通道板（MCP）,并在其上进行电子放大,放大的信号电子随后在荧光屏（P46等）上进行电子-光子转换,最终含有束流剖面信息的投影光子被真空靶室外的CCD相机获取。在正式应用于CSRm之前,IPM探测器还在分离扇回旋加速器直线（SSC Linac）上进行了束流实验,并与传统单丝扫描剖面探测器进行了对比。IPM探测器与单丝刮束器的剖面测量结果相近,并且具有较好的信噪比和约60 μm的较高空间分辨率。这种IPM探测器可以利用电阻串联进行均匀分压,较便捷地应用于真空度较低的直线加速器,还可以改造为分离电极单独供压的结构,应用在超高真空需要烘烤的环形加速器。最后还介绍了一种全新紧凑型结构的IPM探测器设计,该设计利用一套IPM探测器实现束流横向水平与垂直两个方向的剖面测量功能,这种紧凑型IPM结构尤其在空间紧缺型的强流直线加速器上具有重大的应用价值。A new non-intercepting beam profile monitor, residual gas Ionization Profile Monitor (IPM), has been developed and tested at the main Cooling Storage Ring of Heavy Ion Research Facility in Lanzhou (HIRFL-CSRm). It has been successfully used for studies of electron cooling mechanisms, as well as profile monitoring under normal-mode operation in HIRFL-CSRm. The IPM measures the distribution of ions resulting from the residual gas ionization during the beam passage. The gas ions are collected and multiplied by tandem-type MCPs and a phosphor screen, and eventually captured by a commercial CCD camera outside the vacuum chamber. Before formally applied in HIRFL-CSRm, the IPM was tested and compared with a conventional wire scanner profile monitor at Sector Separated Cyclotron Linac (SSC Linac). Both results show good agreement. Besides, the IPM has higher signal to noise ratio than the wire scanner. It also has a very high spatial resolution of around 60 μm. This monitor can be used for low vacuum like Linac with resistance for bias voltage, or for ultra-high vacuum with discrete electrodes for bias voltage where the bakeout process is essential. Furthermore, a novel and compact design of one IPM with capability of detecting both horizontal and vertical profile is proposed. This compact IPM is quite suitable for non-invasive profile diagnostics at space shortage and high-current Linac.     

阳离子空位和吸附氧的协同作用对Na0.5Bi0.5TiO3(100)表面磁性影响的第一性原理研究

The combination effect of cation vacancies and O₂ adsorption on ferromagnetism of Na_0.5Bi_0.5TiO₃(100) surface is studied by using density functional theory.An ideal Na_0.5Bi_0.5TiO₃(100) surface is non-magnetic and the cation vacancy could induce the magnetism.By comparing the formation energies for Na,Bi and Ti vacancy,the Na vacancy is more stable than the others.Therefore,we focus on the configuration and electric structure for the system of O₂ molecule adsorption on the Na_0.5Bi_0.5TiO₃(100) surface with a Na vacancy.Among the five physisorption configurations we considered,the most likely adsorption position is Na vacancy.The O₂ adsorption enhances the magnetism of the system.The contribution of spin polarization is mainly from the O 2p orbitals.The characteristics of exchange coupling are also calculated,which show that the ferromagnetic coupling is favorable.Compared with the previous calculation results,our calculations could explain the room-temperature ferromagnetism of Na_0.5Bi_0.5TiO₃ nanocrytalline powders more reasonably,because of taking into account adsorbed oxygen and cation vacancies.Moreover,our results also show that adsorption of O₂ molecule as well as introduction of cation vacancies may be a promising approach to improve multiferroic materials.     

过渡金属掺杂在Na0.5Bi0.5TiO3体系中诱导产生磁性的第一性原理研究

The origins of magnetism in transition-metal doped Na_0.5Bi_0.5TiO₃ system are investigated by ab initio calculations. The calculated results indicate that a transition-metal atom substitution for a Ti atom produces magnetic moments, which are due to the spin-polarization of transition-metal 3d electrons. The characteristics of exchange coupling are also calculated, which shows that in Cr-/Mn-/Fe-/Co-doped Na_0.5Bi_0.5TiO₃ system, the antiferromagnetic coupling is favorable. The results can successfully explain the experimental phenomenon that, in Mn-/Fe-doped Na_0.5Bi_0.5TiO₃ system, the ferromagnetism disappears at low temperature and the paramagnetic component becomes stronger with the increase of doping concentration of Mn/Fe/Co ions. Unexpectedly, we find the Na_0.5Bi_0.5Ti_0.67V_0.33iO₃ system with ferromagnetic coupling is favorable and produces a magnetic moment of 2.00 μB, which indicates that low temperature ferromagnetism materials could be made by introducing V atoms in Na_0.5Bi_0.5TiO₃. This may be a new way to produce low temperature multiferroic materials.     

2007年重庆市璧山县和云阳县抽样地区环境碘含量调查分析

为了解重庆市抽样地区自然环境中的碘含量,为碘盐的合理摄入和防治碘相关疾病提供依据,采用多级整群随机抽样法,选择重庆市渝东地区云阳县和渝西地区璧山县为调查点,在两县经济状况中等的乡镇各抽取3所乡镇小学的8～10岁儿童各30名作为调查对象,以直接滴定法(GB/T13025.7-1999)检测了其家庭食用盐碘含量;采用随机抽样方法抽取两县居民饮用水样和土壤样,以GB5750-85中砷铈催化分光光度法测定了水碘含量,反向放大比色法测定了土壤碘含量。结果表明,检测两县居民食盐样本556份,璧山县与云阳县食盐碘均数分别为30.41和35.78mg/kg;抽取两县居民饮用水样87份,两县水碘中位数分别为6.50和2.78μg/L;水碘含量10μg/L的水样分别占73.33%和100%;抽取两县浅表层土壤样品88份,两县土壤碘中位数分别为8.20和7.56mg/kg。提示两抽样县均属于碘缺乏地区,需要通过食盐加碘防治碘缺乏病。可根据各地区具体情况,考虑适当调整食盐含碘量。