首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   10360篇
  免费   2035篇
  国内免费   1719篇
化学   7661篇
晶体学   200篇
力学   727篇
综合类   109篇
数学   997篇
物理学   4420篇
  2024年   9篇
  2023年   172篇
  2022年   289篇
  2021年   385篇
  2020年   483篇
  2019年   426篇
  2018年   423篇
  2017年   396篇
  2016年   551篇
  2015年   578篇
  2014年   726篇
  2013年   868篇
  2012年   964篇
  2011年   1060篇
  2010年   801篇
  2009年   707篇
  2008年   804篇
  2007年   771篇
  2006年   678篇
  2005年   523篇
  2004年   415篇
  2003年   342篇
  2002年   296篇
  2001年   274篇
  2000年   190篇
  1999年   161篇
  1998年   117篇
  1997年   126篇
  1996年   112篇
  1995年   76篇
  1994年   56篇
  1993年   68篇
  1992年   48篇
  1991年   45篇
  1990年   39篇
  1989年   23篇
  1988年   21篇
  1987年   17篇
  1986年   24篇
  1985年   14篇
  1984年   7篇
  1983年   9篇
  1982年   7篇
  1981年   2篇
  1979年   2篇
  1973年   1篇
  1971年   1篇
  1970年   2篇
  1957年   4篇
  1936年   1篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Zhong  Weizhou  Zhang  Zexiong  Chen  Xiaowei  Wei  Qiang  Chen  Gang  Huang  Xicheng 《Acta Mechanica Sinica》2021,37(7):1136-1151
Acta Mechanica Sinica - Multi-scale finite element method is adopted to simulate wood compression behavior under axial and transverse loading. Representative volume elements (RVE) of wood...  相似文献   
2.
International Journal of Theoretical Physics - We consider the stationary state of a spin-orbit coupled (SOC) binary Bose-Einstein condensates with dipole-dipole interaction (DDI). Our results are...  相似文献   
3.
针对圆柱形膨胀腔消声器三维建模及声学性能分析问题, 提出一种基于切比雪夫变分原理的耦合声场建模方法, 建立三维圆柱形膨胀腔消声器理论模型并搭建试验台架, 传递损失试验结果验证了理论模型的准确性. 将膨胀腔消声器内部声场分解为多个子声场, 基于子声场间压力与质点振速连续性条件, 推导声场耦合变分公式, 构建子声场拉格朗日泛函. 将子声场声压函数展开为切比雪夫-傅里叶级数形式, 通过瑞利-里兹法求解膨胀腔消声器频率、声压响应及传递损失. 计算并对比分析扩张比、扩张腔长度、进出口管偏置对膨胀腔消声器消声性能的影响. 结果表明: 扩张比增大会有效提高消声器在低频段的消声性能, 进出口管的偏置对消声器消声性能影响很小.  相似文献   
4.
5.
Deep eutectic solvents (DESs) were applied as eco-friendly solvents in this study for the extraction of alkaloids from lotus leaf, including O-nornuciferine, N-nornuciferine, nuciferine and roemerine. A series of hydrophilic and hydrophobic DESs with different hydrogen bond donors and a acceptors were synthesized and screened for a suitable DESs for extraction of alkaloids from lotus leaf. The study results showed that the hydrophilic DES with choline chloride and propanediol had the highest extraction yield. The main factors affecting the extraction efficiency—choline chloride–propanediol ratio, water content in deep eutectic solvents, solid–liquid ratio and extraction time—were investigated via a single-factor experiment. The optimized extraction conditions were 30% of water in choline chloride–propanediol (1:4) for heated extraction for 30 min and solid–liquid ratio 1:100 g/ml. Under optimum conditions, the extraction yields of O-nornuciferine, N-nornuciferine, nuciferine and roemerine were 0.069, 0.152, 0.334 and 0.041 g/100 g respectively, which were higher than those of methanol in acidified aqueous solution. This study suggests considerable potential for DESs as promising materials for the green and efficient extraction solvents for bioactive alkaloids from natural sources.  相似文献   
6.
The design of wound dressings with excellent self-healing ability, adequate adhesion, good biocompatibility, and potential antibacterial ability is of great significance for the healing of infected wounds arising from human activities. Herein, a series of multi-functional hydrogel dressings, poly(ionized isocyanoethyl methacrylate-glutamine)/poly(hexamethylene guanidine) (iGx/PHMGy) hydrogels, were obtained through homopolymerization of fully ionized isocyanoethyl methacrylate-glutamine (iIEM-Gln) in the presence of poly(hexamethylene guanidine) (PHMG), in which strong hydrogen bonds were formed among urea groups in the P (iIEM-Gln) chain to form a stable hydrogel network. The prepared iGx/PHMGy hydrogels exhibited adequate self-healing ability and tissue adhesion, which could be firmly adhered to the wound surface and remained intact during application. In addition, the presence of PHMG imparted good antibacterial activity to the hydrogels for the effective promotion of the wound healing in S. aureus infected skin wound on mice. Overall, this multi-functional hydrogel provides a facile and effective strategy for the design of infected wound dressings, and may show great potential in clinical applications.  相似文献   
7.
伍强 《化学教育》2022,43(19):83-87
针对一线教师在设计硅酸盐材料一课时面对的困难,开发了与陶瓷、玻璃、水泥相对应的石家河红陶杯、洛阳浮法玻璃、白鹤滩大坝等3个教学素材。包含2个原创实验、7个资料、14个原创提问。开发的素材可用于硅酸盐材料高一新授课或以硅酸盐材料为情境的高三复习课中,也可为原创题的命制者提供参考。素材的选择遵循了立德树人的理念,培养了学生的爱国情怀,同时也提升了高级思维能力。  相似文献   
8.
Zhang  Bing  Yang  Jie-qin  Liu  Ying  Hu  Bin  Yang  Yang  Zhao  Li  Lu  Qiang 《Cellulose (London, England)》2022,29(12):6565-6578
Cellulose - Heating is essential in various biomass pre-treatments and thermal conversion processes. It is of practical significance to study the characteristics of cellulose-lignin and...  相似文献   
9.
Amlexanox, an anti-inflammatory and anti-allergic agent, has been widely used clinically for the treatment of canker sores, asthma, and allergic rhinitis. Recently, amlexanox has received considerable attention in curing nonalcoholic fatty liver diseases and hepatitis virus infection. Herein, we first established a sensitive high-performance liquid chromatography-tandem mass spectrum (LC–MS/MS) method for the determination of amlexanox in rat plasma. Propranolol was used as the internal standard (IS). Using a simple protein precipitation method, the amlexanox and IS were separated with Capcell Pak C18 column (2.0 × 50 mm, 5 μm) and eluted with water and acetonitrile each containing 0.1% formic acid using gradient elution condition at a flow rate of 0.4 mL·min−1. Amlexanox and IS were detected by a triple quadrupole mass in multiple reactive monitoring (MRM) under the transitions of m/z 299.2 → 281.2 and m/z 259.9 → 116.1 with positive electrospray ionization, respectively. The calibration curves of amlexanox were established with the range of 50 to 2000 ng·mL−1 (r2 > 0.99). The validation method consisted of selectivity, accuracy, precision, carryover effect, matrix effect, recovery, dilution effect, and stability. The fully validated method was successfully applied to the pharmacokinetic study of amlexanox in Wistar rats.  相似文献   
10.
Meng  Y.  Cai  B.  Lan  Q.  Niu  F.  Zhang  X.  Yang  Y. 《Crystallography Reports》2022,67(2):224-228
Crystallography Reports - A di-nuclear uranyl complex with the formula of [(UO2)2(L)4(H2O)2]?4H2O (1) (HL = quinoline-6-carboxylic acid) was synthesized hydrothermally and characterized by...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号