藤黄酸重排反应产物研究

藤黄酸能显著抑制多种人类肿瘤细胞的增殖,在酸性环境中易发生重排反应,其重排产物对肿瘤细胞也具有很强的抑制作用.通过波谱技术确定了两个藤黄酸的重排反应产物的结构并归属了其波谱数据.细胞毒活性测试显示,两个重排产物对A549,HCT116和MDA-MB-231显示很强的抑制作用.     

三维N-S方程计算隐式有限体积法

利用NND有限差分格式，发展了一种新的完全隐式的有限体积数值方法，以求解与时间相关的N－S方程．对通过单元体界面的无粘流和粘性流通量均作隐式处理．对绕流钝锥体和不同攻角的气动辅助实验飞行器的高超声速粘性流和化学反应流获得了定常数值解．对流加热率和流场电子密度的计算值与实验数据进行了比较，符合较好，证实了本方法的精确性．     

Preparation of yolk-shell sulfur/carbon nanocomposite via an organic solvent route for lithium–sulfur batteries

A yolk-shell sulfur/carbon (S/C) composite for the cathode of lithium–sulfur batteries was successfully prepared by an accessible method with tetrahydrofuran as solvent. The as-prepared composites are characterized by thermal gravimetric, X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption and desorption. In this composite, sulfur particle is encapsulated in the carbon shell even entering into the micropores of carbon Bp2000. The electrochemical performance of the S/C composites is evaluated. The results indicate that the S/C composite with 50 wt% sulfur content shows good reversibility, excellent rate capability, and slow degradation. It delivers an initial capacity of 784.4 mAh g^?1 (based on sulfur weight) and preserves at 598.3 mAh g^?1 after 195 cycles at 1C. It achieves a high-capacity retention of 76.27 % from the 5th to 200th cycle, and as high as 91.19 % during the latter 150 cycles. The improvement is mainly attributed to the favorable structure of the S/C composite, in which the carbon cannot only facilitate transport of electrons and Li⁺ ions but also trap polysulfides and retard the shuttle effect during charge/discharge process.     

Effects of nonlinearity of restoring springs on propulsion performance of wave glider

Nonlinear Dynamics - Wave glider is an unmanned surface vehicle that can directly convert wave energy into forward propulsion and fulfill long-term marine monitoring. A previous study suggested...     

MKdV方程的多辛Fourier拟谱方法

基于谱微分矩阵方法,给出MKdV方程的多辛Fourier拟谱格式及其相应多辛离散守恒律,证明了它等价于通常的Fourier拟谱格式．数值结果表明,格式对于长时间计算具有稳定性与高精度．     

Polyethylene glycol‐bound Ru catalyst for asymmetric transfer hydrogenation of aromatic ketones in water

A new polyethylene glycol‐supported chiral monosulfonamide was synthesized from (R,R)‐1,2‐diaminocyclohexane and shown to act as a ligand for ruthenium(II)‐catalyzed asymmetric transfer hydrogenation of aromatic ketones in neat water using sodium formate as the hydrogen source. Good enantioselectivities were obtained and the catalyst could be easily separated from the reaction mixture and reused several times. Copyright © 2011 John Wiley & Sons, Ltd.     

Synthesis of water‐soluble monotosylated ethylenediamines and their application in ruthenium and iridium‐catalyzed transfer hydrogenation of aldehydes

Synthesis of novel water‐soluble monotosylated ethylenediamines and their application in ruthenium and iridium‐catalyzed transfer hydrogenation of aldehydes are described. Various aldehydes, including electron‐deficient and electron‐rich variants, were reduced with high conversions and chemoselectivity using sodium formate as a hydrogen source in neat water. Copyright © 2011 John Wiley & Sons, Ltd.     

基于模糊集合论的实物期权定价方法

实物期权的定价在风险投资决策过程中具有重要意义.传统的实物期权定价方法忽略标的资产价值和投资成本的模糊性,从而可能导致错误的投资决策.本文主要研究了具有模糊标的的资产价值和投资成本情形时的实物期权定价模型.文中将这些模糊因素分别视为模糊数和模糊变量,然后运用模糊集合论,结合B-S期权定价理论,对实物期权进行定价,得到了基于模糊集合论的实物期权定价模型.     

不具有性质(wa)的拓扑空间

设（X，T）是拓扑空间，如果对于任意的开覆盖u和任意的稠密子集D存在X的离散子集F∪→D使得St(F,u)=∪{U∈u:U∩F≠φ}=X，则称（X，T）具有性质（wa)，每一正规空间都具有性质（wa)。M.V.Matveev举例说明了T1空间可以不具有性质(wa)，本文证明了存在很多Hausdorff空间不具有性质（wa)，且进一步举例说明了Tychonoff空间可以不具有性质（wa)，这些结果回答了Matveev的问题。