Correction to: Theoretical modeling and experimental evaluation of a magnetostrictive actuator with radial-nested stacked configuration

Nonlinear Dynamics -     

A stable pillared metal–organic framework constructed by H4TCPP ligand as luminescent sensor for selective detection of TNP and Fe3+ ions

A novel luminescent metal–organic framework ( Zn‐TCPP/BPY ) with pillared structure based on 2,3,5,6‐tetrakis(4‐carboxyphenyl)pyrazine (H₄TCPP) and 4,4′‐bipyridine (BPY) has been designed and synthesized through a solvothermal reaction. The [Zn₂(COO)₄] paddlewheel units are linked by TCPP^4? ligands to form two‐dimensional layers and further connected by BPY ligands as pillars to construct the twofold interpenetrating three‐dimensional framework. Interestingly, Zn‐TCPP/BPY possesses outstanding stability in organic solvents and water as well as maintains its structural rigidity in aqueous solutions of different pH values (3–12). After activation, Zn‐TCPP/BPY possesses permanent porosity with Brunauer–Emmett–Teller surface area of 630 m² g^–1. Remarkably, Zn‐TCPP/BPY displays excellent fluorescent property in virtue of the aggregation‐induced emission effect of the H₄TCPP ligand, which can be highly active and quenched by small amounts of 2,4,6‐trinitrophenol (TNP) and Fe³⁺ ions. Furthermore, the detection effect of Zn‐TCPP/BPY remains basically the same even after five cycles. The excellent stability, high sensitivity, and recyclability of Zn‐TCPP/BPY make it an outstanding chemical sensor for detecting TNP and Fe³⁺ ions.     

Highly porous CuO/MnO2 catalyst prepared by gas release-assisted technology and its enhancement of formaldehyde removal efficiency

Research on Chemical Intermediates - A porous CuO/MnO2 catalyst was synthesized by a gas release-assisted method. Due to the participation of gases (H2O, NH3, CO2) released from ammonia and...     

岩爆与围岩分类

岩爆是高地应力条件下完整脆性硬质围岩失稳的一种表现型式,岩爆烈度如何影响围岩类别尚不清楚,探索岩爆与围岩分类的关系,对准确判别高地应力条件下的围岩类别有着重要意义。本文以某深埋隧洞围岩分类为依据,对我国水利水电地下洞室围岩分类中岩爆烈度与围岩类别的关系、岩爆判别指标的选取等问题进行了探讨。     

滑坡防治工程安全性评价研究

滑坡灾害防治是一门综合性工程,防治工程的安全性取决于滑坡勘察、设计以及施工质量,本文就滑坡治理过程中各阶段易出现的问题予以实例说明,探讨滑坡防治工程中应注意的几个问题,对这些经验教训进行总结,同时强调监测在防治工程中的作用,其对于滑坡防治工程具有一定借鉴意义。     

Characterization and biochemical investigation of the potential inositol monophosphate phosphatase involved in bacterial mycothiol biosynthesis

Abstract

Mycothiol (MSH) is the predominant form of small molecule thiols produced by actinomycetes and plays a pivotal role in the bacterial detoxication process. The only enzyme involved in MSH biosynthesis that has not been characterized yet is a phosphatase MshA2, which was proposed to catalyze the hydrolysis of 3-phospho-1-D-myo-inosityl-2-acetamido-2-deoxy-α-D-glucopyranoside (GlcNAc-Ins-3-P) to GlcNAc-Ins. In this study, a new inositol monophosphate phosphatase from Corynebacterium glutamicum, designated as Cg0911, was discovered, expressed and characterized. Detailed biochemical studies on Cg0911 revealed that GlcNAc-Ins-3-P was its preferred substrate for efficient conversion into GlcNAc-Ins.     

Binding and cytotoxicity of 131I-labeled gastrin-releasing peptide receptor antagonists modified by cell penetrating peptides

Gastrin releasing peptide receptors (GRPRs) are one of the most interesting targets over expressed in various tumors. Due to the superior potential of the GRPR antagonist analogs, they have been studied in the tumor radio imaging and therapy field. However, typical antagonists suffered the shortcomings of no internalization and poor binding affinity which hampered their applications in radiotherapy. Therefore, we attempted to introduce Oligoarginines (cell penetrating peptides) to RM26, aiming to increase the binding affinity or even trigger the internalization of the peptides on cells. The results showed Arg₆ as the most potent CPP, significantly enhanced the binding avidity of RM26 to the GRPR.

     

Complexation of 1,3-Diamino-2-hydroxypropane- N,N , N ', N '-tetraacetic Acid (DHPTA) with Heavy Lanthanides (Tb 3+ , Ho 3+ , Lu 3+ ) in Aqueous Solution

Thermodynamic equilibria of complexes of 1,3-diamino-2-hydroxypropane-N,N,N',N'-tetraacetic acid (DHPTA) with heavy lanthanides (Tb3+, Ho3+ and Lu3+) in aqueous solution have been investigated with potentiometry, spectrophotometry, luminescence spectroscopy and nuclear magnetic resonance spectroscopy (NMR). The results identified three 1:1 Ln/DHPTA (Ln: Tb3+, Ho3+ and Lu3+) complexes with different degrees of deprotonation, LnL−, Ln(H−1L)2−, and Ln(OH)(H−1L)3−, where H−1 represents the deprotonation of the hydroxyl group between two methyliminodiacetate groups in the DHPTA structure. The alkoxide form of the DHPTA hydroxyl group directly binds to the lanthanide atom, forming highly strong chelation. The complex of Ln(H−1L)2− could be present as a dimeric or polymeric complex in solution.     

平顶高斯超短脉冲激光的时间部分相干性对相干合成的影响

 利用准单色光干涉理论,计算了2×2平顶高斯超短脉冲激光在远场的干涉图样,分析了激光的时间部分相干性及其存在束间相位差时对相干合成的影响。计算结果表明,当单路激光输出光束线宽小于100 nm时,理想波前的远场光斑图样和峰值光强基本保持不变,当光束线宽大于100 nm时,干涉减弱衍射效应逐渐增强;光束间存在相位差时,时间部分相干性将破坏远场图样随束间相位差的周期性变化,相位差越大干涉越弱;当超过相干长度时,则为非相干合成,但1/6倍相干长度范围内,仍可视为较理想的相干合成,此时焦斑的斯特列尔比大于0.9,对超短脉冲的相干合成影响可忽略。     

公路边坡岩体分级中坡高修正系数的改进

坡高与边坡稳定性有密切关系。CSMR分级体系在SMR的基础之上针对水电边坡工程引入了坡高修正系数 ,但在公路边坡分级实践中发现 ,该坡高修正系数仍有待于改进。对各类边坡可能失稳形式的力学分析 ,证明坡高修正系数 ξ可近似表示为ξ =a+b/H 的形式。通过对 1 0 0余个边坡样本统计分析 ,得出两种不同岩层、坡面产状组合形式下坡高修正系数的数学表达式。经检验 ,改进后的CSMR体系能够满足公路边坡稳定性初步评价的要求。