全文获取类型
收费全文 | 36000篇 |
免费 | 3120篇 |
国内免费 | 2532篇 |
专业分类
化学 | 24398篇 |
晶体学 | 438篇 |
力学 | 1535篇 |
综合类 | 235篇 |
数学 | 4112篇 |
物理学 | 10934篇 |
出版年
2023年 | 296篇 |
2022年 | 353篇 |
2021年 | 825篇 |
2020年 | 853篇 |
2019年 | 923篇 |
2018年 | 825篇 |
2017年 | 803篇 |
2016年 | 1291篇 |
2015年 | 1246篇 |
2014年 | 1678篇 |
2013年 | 2438篇 |
2012年 | 2809篇 |
2011年 | 3171篇 |
2010年 | 2215篇 |
2009年 | 2114篇 |
2008年 | 2720篇 |
2007年 | 2414篇 |
2006年 | 2418篇 |
2005年 | 2069篇 |
2004年 | 1749篇 |
2003年 | 1404篇 |
2002年 | 1338篇 |
2001年 | 964篇 |
2000年 | 783篇 |
1999年 | 523篇 |
1998年 | 339篇 |
1997年 | 294篇 |
1996年 | 348篇 |
1995年 | 261篇 |
1994年 | 265篇 |
1993年 | 256篇 |
1992年 | 203篇 |
1991年 | 166篇 |
1990年 | 149篇 |
1989年 | 137篇 |
1988年 | 97篇 |
1987年 | 90篇 |
1986年 | 64篇 |
1985年 | 91篇 |
1984年 | 56篇 |
1983年 | 45篇 |
1982年 | 66篇 |
1981年 | 63篇 |
1980年 | 39篇 |
1979年 | 50篇 |
1978年 | 57篇 |
1977年 | 38篇 |
1976年 | 44篇 |
1975年 | 39篇 |
1974年 | 41篇 |
排序方式: 共有10000条查询结果,搜索用时 21 毫秒
1.
Luan Nguyen Ngoc Kim Do Sang Yen Nguyen Dong 《Journal of Optimization Theory and Applications》2022,193(1):574-597
Journal of Optimization Theory and Applications - We consider the conic linear program given by a closed convex cone in an Euclidean space and a matrix, where vector on the right-hand side of the... 相似文献
2.
Science China Chemistry - 相似文献
3.
Mohammad A. Khalilzadeh Soo Young Kim Ho Won Jang Rafael Luque Rajender S. Varma Richard A. Venditti Mohammadreza Shokouhimehr 《Materials Today Chemistry》2022
The requirement of green and sustainable materials to prepare heterogeneous catalysts has intensified for practical reasons over the past few decades. Carbohydrates are possibly the most plentiful and renewable organic materials in nature with inimitable physiochemical properties, plausible low-cost and large-scale production, and sustainability features could be exploited in the generation of nanostructured heterogeneous catalysts. This review article outlines the organic transformations catalyzed by diverse carbohydrate-based nanostructured catalysts in greener and environmentally friendly processes. Selected examples are highlighted for a variety of organic reactions exploiting the proposed catalysts’ reactivity and reusability, and interactions with the intrinsic nature of the applied carbohydrate supports; advantages and speculated challenges of the introduced catalysts are deliberated as well. 相似文献
4.
Annals of Global Analysis and Geometry - We study harmonic maps from a 3-manifold with boundary to $$\mathbb {S}^1$$ and prove a special case of Gromov dihedral rigidity of three-dimensional cubes... 相似文献
5.
CdS/Si nanofilm heterojunctions based on amorphous silicon films:Fabrication,structures,and electrical properties 下载免费PDF全文
Shortening the distance between the depletion region and the electrodes to reduce the trapped probability of carriers is a useful approach for improving the performance of heterojunction.The CdS/Si nanofilm heterojunctions are fabricated by using the radio frequency magnetron sputtering method to deposit the amorphous silicon nanofilms and Cd S nanofilms on the ITO glass in turn.The relation of current density to applied voltage(I-V)shows the obvious rectification effect.From the analysis of the double logarithm I-V curve it follows that below~2.73 V the electron behaviors obey the Ohmic mechanism and above~2.73 V the electron behaviors conform to the space charge limited current(SCLC)mechanism.In the SCLC region part of the traps between the Fermi level and conduction band are occupied,and with the increase of voltage most of the traps are occupied.It is believed that Cd S/Si nanofilm heterojunction is a potential candidate in the field of nano electronic and optoelectronic devices by optimizing its fabricating procedure. 相似文献
6.
7.
Journal of Fluorescence - We synthesized an original reversible colorimetric chemosensor PDJ... 相似文献
8.
Liu Jinjie Yang Xinmin Zeng Shengda Zhao Yong 《Journal of Optimization Theory and Applications》2022,193(1):877-909
Journal of Optimization Theory and Applications - In this paper, we introduce and investigate a new kind of coupled systems, called coupled variational inequalities, which consist of two elliptic... 相似文献
9.
10.
Peter T. Smith Younghoon Kim Dr. Bahiru Punja Benke Prof. Kimoon Kim Prof. Christopher J. Chang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(12):4932-4937
We report a supramolecular strategy for promoting the selective reduction of O2 for direct electrosynthesis of H2O2. We utilized cobalt tetraphenylporphyrin (Co-TPP), an oxygen reduction reaction (ORR) catalyst with highly variable product selectivity, as a building block to assemble the permanently porous supramolecular cage Co-PB-1(6) bearing six Co-TPP subunits connected through twenty-four imine bonds. Reduction of these imine linkers to amines yields the more flexible cage Co-rPB-1(6). Both Co-PB-1(6) and Co-rPB-1(6) cages produce 90–100 % H2O2 from electrochemical ORR catalysis in neutral pH water, whereas the Co-TPP monomer gives a 50 % mixture of H2O2 and H2O. Bimolecular pathways have been implicated in facilitating H2O formation, therefore, we attribute this high H2O2 selectivity to site isolation of the discrete molecular units in each supramolecule. The ability to control reaction selectivity in supramolecular structures beyond traditional host–guest interactions offers new opportunities for designing such architectures for a broader range of catalytic applications. 相似文献