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Carbohydrate-based nanostructured catalysts: applications in organic transformations
Authors:Mohammad A Khalilzadeh  Soo Young Kim  Ho Won Jang  Rafael Luque  Rajender S Varma  Richard A Venditti  Mohammadreza Shokouhimehr
Institution:1. Department of Forest Biomaterials, College of Natural Resources, North Carolina State University, Raleigh, NC, 27695-8005, United States;2. Department of Materials Science and Engineering, Institute of Green Manufacturing Technology, Korea University, 145, Anam-ro Seongbuk-gu, Seoul 02841, Republic of Korea;3. Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 08826, Republic of Korea;4. Departamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, Cordoba 14014, Spain;5. Peoples Friendship University of Russia (RUDN University), 6 Miklukho Maklaya St., 117198, Moscow, Russia;6. Regional Centre of Advanced Technologies and Materials, Czech Advanced Technology and Research Institute, Palacky University in Olomouc, ?lechtitel? 27, 783 71 Olomouc, Czech Republic
Abstract:The requirement of green and sustainable materials to prepare heterogeneous catalysts has intensified for practical reasons over the past few decades. Carbohydrates are possibly the most plentiful and renewable organic materials in nature with inimitable physiochemical properties, plausible low-cost and large-scale production, and sustainability features could be exploited in the generation of nanostructured heterogeneous catalysts. This review article outlines the organic transformations catalyzed by diverse carbohydrate-based nanostructured catalysts in greener and environmentally friendly processes. Selected examples are highlighted for a variety of organic reactions exploiting the proposed catalysts’ reactivity and reusability, and interactions with the intrinsic nature of the applied carbohydrate supports; advantages and speculated challenges of the introduced catalysts are deliberated as well.
Keywords:Carbohydrate  Catalysis  Cellulose  Chitosan  Coupling reaction  Nanocatalyst  Nanomaterials  Oxidation  Reduction
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