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可控/“活性”自由基聚合(CLRP)可以用于制备分子量分布窄、分子链缺陷少的聚合物,如聚乙烯(PE)、聚氯乙烯(PVC)、聚偏氯乙烯(PVDC)和聚偏氟乙烯(PVDF),且易控制上述单体与其他单体共聚得到嵌段聚合物。本文调研了近年来可控/“活性”自由基聚合(如碘转移聚合(ITP)、氮氧稳定自由基聚合(NMP)、可逆加成断裂链转移(RAFT)聚合和金属催化的活性自由基聚合(OMRP)等)制备聚乙烯和聚卤代烯烃等方面的工作,并指出了未来的发展方向。 相似文献
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有随机投资回报的随机保费模型的渐近破产概率(英文) 总被引:1,自引:0,他引:1
本文研究了随机投资回报环境下扰动的随机保费模型的破产问题.利用鞅方法和随机分析的理论讨论了盈余过程的一些基本性质,得到了一个可以用来求解破产时刻的Laplace变换的积分微分方程,结果推广了已有的随机投资问报风险模型的结论. 相似文献
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In this paper, it is assumed that an insurer with a jump-diffusion risk process would invest its surplus in a bond market, and the interest structure of the bond market is assumed to follow the Vasicek interest model. This paper focuses on the studying of the ruin problems in the above compounded process. In this compounded risk model, ruin may be caused by a claim or oscillation. We decompose the ruin probability for the compounded risk process into two probabilities: the probability that ruin caused by a claim and the probability that ruin caused by oscillation. Integro-differential equations for these ruin probabilities are derived. When the claim sizes are exponentially distributed, the above-mentioned integro-differential equations can be reduced into a three-order partial differential equation. 相似文献
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塑料球栅阵列封装PBGA的可靠性分析中,考虑封装过程中SnAgCu焊料与铜焊盘界面间产生的金属间化合物(Intermetallic compound,IMC)的影响,并引入内聚力模型(Cohesive zone model,CZM),利用ANSYS对热循环作用下焊点/IMC界面的脱层开裂情况进行研究.结果表明:热循环作用下,在封装器件中焊点承受较大的应力应变,且远离中心的外侧焊点具有比内侧焊点更大的应力应变.IMC的存在极大的降低了焊点的可靠性.界面分层最先发生在最外侧的IMC/焊点界面的两端,随着热循环次数的增加,分层逐渐沿着界面两端向里扩展.在热循环的前几个阶段,各个界面的最大损伤值增大较快,随着热循环的继续加载,界面最大损伤值逐渐趋于稳定.整个过程中四号焊点界面的损伤值始终最大. 相似文献
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具有超大通道结构的介孔氧化硅柱层状钛酸的合成和催化应用初探 总被引:6,自引:0,他引:6
A mesoporous (d=2.3mm) silica-pillared layered tetratitanate with a super gallery (d001=1.84mm)was prepared by first preswelling layered tetratitanate with n-dodecyl amine, then reacting with 20wt% NH2(CH2)3Si(OC2H5)3 aqueous solution, and finally calcinating the resultant solid product in air at 550℃. All the reaction was carried out hydrothermally in an autoclave at 130℃. The obtained material has a relatively high BET surface area of 204m2·g-1 and a thermal stability beyond 600℃. The catalytic application of the material was also investigated by using the dehydration of isopropanol and the reform of n-hexane as two probing reactions. 相似文献
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采用甲基丙烯酸锌加速还原氯化钯(PdCl2) 溶液中的钯离子(Pd 2+)为钯(Pd) 纳米微球, 进而用得到的钯纳米微球直接制备钯/氧化钯(Pd/PdO) 纳米复合微球. 通过扫描电子显微镜(SEM)、 透射电子显微镜(TEM)、 粉末X射线衍射分析(XRD)及X射线光电子能谱分析(XPS) 等方法对 Pd/PdO 纳米复合微球进行表征, 结果表明, 制备的纳米复合微球为表面粗糙、 大小均一的纳米微球. 采用紫外-可见吸收光谱(UV-Vis) 等方法考察了 Pd/PdO 纳米复合微球在对硝基苯酚(4-NTP) 还原反应中的催化性能, 发现其具有良好的催化活性和循环稳定性. 相似文献