Transition from tunneling regime to local point contact realized on Ba_(0.6)K_(0.4)Fe_2As_2 surface

Using scanning tunneling spectroscopy, we studied the transition from tunneling regime to local point contact on the iron-based superconductor Ba_(0.6)K_(0.4)Fe_2As_2. By gradually reducing the junction resistance, a series of spectra were obtained with the characteristics evolving from single-particle tunneling into Andreev reflection. The spectra can be well fitted to the modified Blonder–Tinkham–Klapwijk(BTK) model and exhibit significant changes of both spectral broadening and orbital selection due to the formation of point contact. The spatial resolution of the point contact was estimated to be several nanometers, providing a unique way to study the inhomogeneity of unconventional superconductors on such a scale.     

Re_3W的点接触安德烈夫反射谱研究

本文通过对不同晶体结构Re_3W样品的点接触测量和对比研究,证实具有中心对称结构和非中心对称结构的Re_3W都是弱耦合Bardeen-Cooper-Schrieffer超导体,同时发现在两个相表面都可以形成很理想的点接触结,即电子通过界面时受到的非弹性散射很弱.将Re_3W样品置于大气环境近六个月后重新进行测量,仍然能够得到类似的结果,表明Re_3W具有很好的稳定性. Re_3W的这种优良特性,不仅可通过点接触实验得到的参数推算出Re_3W两个相的费米速度,而且提供了一种简单的方法,可以在点接触实验中利用Re_3W来印证针尖材料的费米速度和测量其自旋极化率等.作为尝试,本文用Re_3W/Ni点接触结测量了铁磁性金属Ni的自旋极化率,得到了与前人报道一致的结果.     

CrAlN涂层海水环境腐蚀磨损行为研究

采用多弧离子镀在316不锈钢上沉积Cr Al N涂层,用X射线衍射仪(XRD)和扫描电子显微镜(SEM)表征涂层的成分和结构,纳米压痕和划痕仪分别测试涂层的硬度和结合力.通过球-盘往复式摩擦磨损试验机在海水环境下测试涂层腐蚀磨损性能,并用电化学工作站实时监测其摩擦过程中的电化学特性.结果表明:Cr Al N在有摩擦的条件下,涂层极化曲线的阳极区域存在较为明显的钝化区,抑制了涂层进一步腐蚀.在阳极电位下,涂层的摩擦系数随着加载电位的增加显著降低.随着加载电位的升高,涂层的磨损量也相应地增大.在阳极电位0.5 V下的磨损量是阴极电位–1 V下的2.99倍.在0 V时,磨损促进腐蚀的损失量,约占总损失量的13.71%.在–1 V,–0.5 V,–0.25 V,OCP,0 V下的磨损机理主要为磨粒磨损和塑性变形,而在0.25 V,0.5 V下的磨损机理主要为疲劳点蚀.     

超导电性制冷唯象理论

本文以超导热力学唯象为基础，讨论了有退磁效应和远退磁效应的两种Ｉ类超导体样品在外场从０增加到临界场ＨＣ（Ｔ）过程中所产生的制冷效应，我们发现：对于有退磁效应的样品，其制冷效应发生在中间态区；而从Ｍｅｉｓｓｎｅｒ态到中间态和从中间态到正常态的相变过程是二级相为，所以无制冷效应，这可能是超导体制冷实验研究的核心问题。     

Specific heat of the non-centrosymmetric superconductor Re3W

The alloys of non-centrosymmetric superconductor, Re 3 W, which were reported to have an α-Mn structure [P. Greenfield and P. A. Beck, J. Metals, N. Y. 8, 265 (1959)] with T c = 9 K, are prepared by arc melting. The values of ac susceptibility and the low-temperature specific heat of these alloys are measured. It is found that there are two superconducting phases coexisting in the samples with T c1 ≈ 9 K and T c2 ≈ 7 K, which are both non-centrosymmetric in structure as reported previously. By analysing the specific heat data measured in various magnetic fields down to a temperature of 1.8 K, we find that the absence of the inversion symmetry does not lead to an obvious deviation from an s-wave pairing symmetry in Re 3 W.     

磁通钉扎液体的动力学特性

依据Ｍａｌｏｚｅｍｏｆｆ和Ｇｒｉｅｓｓｅｎ等建议的表征高温超导体有效钉扎势的唯象表式Ｕ（Ｔ,Ｂ,Ｊ）＝Ｕｏ（Ｔ,Ｂ）／μ（Ｔ,Ｂ）［Ｊｃ（Ｔ,Ｂ）／Ｊ）＾μ（Ｔ,Ｂ）－１］和热激活涡旋运动模型,并通过ＹＢａ２Ｃｕ３Ｏ７－δ薄膜直流传输特性的测量结果,利用“函数唯一性”数据处理方法,研究了钉扎液体的玻璃态指数μ（Ｔ,Ｂ）随温度与外磁场的负值函数形式。以及钉扎势垒Ｕｏ（Ｔ,Ｂ）和Ｊｃ（Ｔ,Ｂ）随外场与     

超导体中涡旋运动损耗与Anderson相滑移理论

本文用G L唯象理论结合Anderson相滑移理论讨论了第Ⅱ类高温超导体中的涡旋以V运动在超流电流上产生电压的损耗原因 ,并将结果与M .Tinkham的Josephson相滑移理论进行了比较 .     

白三烯A4水解酶功能调节剂（E）-2-（1-羟基-4-环己酮）乙基咖啡酸酯的全合成研究

以1，4-环己二酮单乙二醇缩酮和咖啡酸为起始原料，经两条不同的路线完成了（E）-2-（1-羟基-4-环己酮）乙基咖啡酸酯的全合成，并确定了其最佳合成路线，总收率达56％．     

Nonlinear uniaxial pressure dependence of the resistivity in Sr_(1-x)Ba_xFe_(1.97)Ni_(0.03)As_2

Nematic order and its fluctuations have been widely found in iron-based superconductors. Above the nematic order transition temperature, the resistivity shows a linear relationship with the uniaxial pressure or strain along the nematic direction and the normalized slope is thought to be associated with nematic susceptibility. Here we systematically studied the uniaxial pressure dependence of the resistivity in Sr_(1-x)Ba_xFe_(1.97)Ni_(0.03)As_2, where nonlinear behaviors are observed near the nematic transition temperature. We show that it can be well explained by the Landau theory for the second-order phase transitions considering that the external field is not zero. The effect of the coupling between the isotropic and nematic channels is shown to be negligible. Moreover, our results suggest that the nature of the magnetic and nematic transitions in Sr_(1-x)Ba_xFe_2As_2 is determined by the strength of the magnetic-elastic coupling.     

Distinction between critical current effects and intrinsic anomalies in the point-contact Andreev reflection spectra of unconventional superconductors

In this work,we discuss the origin of several anomalies present in the point-contact Andreev reflection spectra of(Li_(1-x)Fe_x)OHFeSe,LiTi_2O_4,and La_(2-x)Ce_xCuO_4.While these features are similar to those stemming from intrinsic superconducting properties,such as Andreev reflection,electron-boson coupling,multigap superconductivity,d-wave and p-wave pairing symmetry,they cannot be accounted for by the modified Blonder–Tinkham–Klapwijk(BTK) model,but require to consider critical current effects arising from the junction geometry.Our results point to the importance of tracking the evolution of the dips and peaks in the differential conductance as a function of the bias voltage,in order to correctly deduce the properties of the superconducting state.