多层状碱式碳酸锌微晶的制备及其脱除Cu2+性能研究

以壳聚糖(CS)为生物模板,采用低温水热法成功制备出了多层状碱式碳酸锌(ZCHO)微晶.采用XRD、SEM和TG等手段对产物的结构、形态和热学性能进行了表征,结果表明,单个ZCHO微晶颗粒均是由许多ZCHO纳米片构成的.添加适量的CS对形成多层状ZCHO微晶起到了至关重要的作用.热重分析结果表明,CS辅助得到的碳酸锌微晶热稳定性较高.等温吸附实验表明,在室温下,多层状ZCHO微晶能有效脱除水体中的Cu2,去除量与浓度关系符合Freundlich模型.最后讨论了多层状ZCHO微晶大容量去除Cu2+的可能机理.     

Comparison experiments of neon and helium buffer gases cooling in trapped ~(199)Hg~+ ions linear trap

The influences of different buffer gas, neon and helium, on199Hg+clock transition are compared in trapped199Hg+linear trap. By the technique of time domain’s Ramsey separated oscillatory fields, the buffer gas pressure frequency shifts of199Hg+clock transition are measured to be(d f /dPNe)(1/ f) = 1.8 × 10-8Torr-1for neon and(d f /dPHe)(1/ f) = 9.1 × 10-8Torr-1for helium. Meanwhile, the line-width of199Hg+clock transition spectrum with the buffer gas neon is narrower than that with helium at the same pressure. These experimental results show that neon is a more suitable buffer gas than helium in199Hg+ions microwave frequency standards because of the199Hg+clock transition is less sensitive to neon variations and the better cooling effect of neon. The optimum operating pressure for neon is found to be about 1.0 × 10-5Torr in our linear ion trap system.     

ZnO∶Al衬底上低温生长GaN薄膜

利用射频磁控溅射在普通玻璃上制备了(0002)择优取向的ZnO:Al薄膜.采用电子回旋共振-等离子体增强金属有机物化学气相沉积(ECR-PEMOCVD)技术,在ZnO:Al薄膜衬底上沉积了厚度为320 nm的GaN薄膜.利用高能电子衍射(RHEED)、X射线衍射(XRD)、原子力显微镜(AFM)和光透射谱等表征方法,研究了沉积温度对GaN薄膜的结晶性、表面形貌和透射率的影响.     

Evaluation of the frequency instability limited by Dick effect in the microwave ~(199)Hg~+ trapped-ion clock

In the microwave ~(199)Hg~+ trapped-ion clock, the frequency instability degradation caused by the Dick effect is unavoidable because of the periodical interrogating field. In this paper, the general expression of the sensitivity function g(t)to the frequency fluctuation of the interrogating field with Nπ-pulse(N is odd) is derived. According to the measured phase noise of the 40.5-GHz microwave synthesizer, the Dick-effect limited Allan deviation of our ~(199)Hg~+ trapped-ion clock is worked out. The results indicate that the limited Allan deviations are about 1.75 × 10~(-13)τ~(1/2) and 3.03 × 10~(-13)τ~(1/2) respectively in the linear ion trap and in the two-segment extended linear ion trap under our present experimental parameters.