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排序方式: 共有23条查询结果,搜索用时 164 毫秒
1.
用气液色谱法研究过一系列作为Lewis碱(B)的有机配体和作为Lewis酸(A)的配合物之间的加合作用.研究较多的碱已有脂肪醇、醚、酮、醛、脂及胶等.对生物体系中广为存在的杂环配体碱的工作还很少.本文着重研究噻吩,呋喃和吡咯这类小分子杂环配体和Ni[CF_3COCHC(C_4H_4S)=NCH_2]_2(以下简称A)配合物的加合反应. Ni[CF_3COCHC(C_4H_4S)=NCH_2]_2的合成参考文献.固定液角鲨烷系英国进口,  相似文献   
2.
酒石酸亚铁分光光度法测定茶多酚   总被引:35,自引:0,他引:35  
采用没食子酸丙酯为基准物质酒石酸亚铁作为显色剂,光度法测定茶多酚制品中茶多酚的含量。最大吸收波长540nm摩尔吸光系数2.65×10^3回收率为98%-101%,相对标准偏差为0.90%。方法简便,结果令人满意。  相似文献   
3.
用于丁烯氧化脱氢的铁系复合氧化物催化剂具有复杂的相组成,可能存在着。Fe。O。、1贝。0。、Fe。0。、铁酸盐尖晶石相及尖晶石相之间形成的固溶体,这些相的鉴定对于弄清活性位/相的结构具有本质意义.由于缺乏有效的相结构表征手段,导致对于活性位/相的结构和上述各相所起的作用的观,入歧异.Misono山曾测出7-Fe。O。具有较高的活性,故认为它是该系催化剂的活性相,但XRD难以把7-Fe。O。与其它尖晶石相区分开,因而无法确认它在催化剂中是否存在及起何作用.Gillot门提出了可用红外光谱鉴定了一FeZO。:1-Fe。O。在600~…  相似文献   
4.
By using the methods of Picard-Fuchs equation and Riccati equation, we study the upper bound of the number of zeros for Abelian integrals in a kind of quadratic reversible centers of genus one under polynomial perturbations of degree $n$. We obtain that the upper bound is $7[(n-3)/2]+5$ when $n\ge 5$, $8$ when $n=4$, $5$ when $n=3$, $4$ when $n=2$, and $0$ when $n=1$ or $n=0$, which linearly depends on $n$.  相似文献   
5.
As(III) specifically interacts with an arsenic-binding aptamer to form an As(III)-aptamer complex, so that the following cationic polymer can aggregate gold nanoparticles (AuNPs) and cause a remarkable change in color, which enables the colorimetric detection of As(III) with high selectivity and a detection limit of 5.3 ppb.  相似文献   
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7.
Yao  Yuangen 《Nonlinear dynamics》2022,107(4):3887-3901
Nonlinear Dynamics - It has been shown recently that a chaos-driven bistable system with two square waves as input can consistently work as a reliable logic gate, in an optimal window of chaos...  相似文献   
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9.
RIBLL1终端实验装置   总被引:1,自引:0,他引:1  
描述了一套HIRFL的放射性核次级束流引起反应测量的实验装置,它由RIB鉴别、测量系统、次级靶控制系统和次级反应产物鉴别、测量系统组成.高增益分组延迟线读出、重心定位PPAC,横向场IC,椭球面镜聚焦、PMT读出、闪烁薄膜时间拾取器,双叠层纵向场阳极分条读出IC,PMT矩阵读出x—y位置灵敏Phoswich闪烁探测器,康普顿抑制HpGeγ探测器等单元是这套装置的基本部件.目前,该装置已安装在兰州重离子加速器RIBLL1终端.性能测试和实验研究正在进行.  相似文献   
10.
Luo  Danqiu  Chen  Huayun  Zhou  Pei  Tao  Han  Wu  Yuangen 《Analytical and bioanalytical chemistry》2019,411(29):7857-7868

A novel colorimetric sensing platform based on the peroxidase activity of hemin regulated by oligonucleotide and pesticide was reported for the ultrasensitive and selective detection of isocarbophos. Oligonucleotides can accumulate on the surface of hemin in acid condition and temporarily inhibit its catalytic activity, which results in the loss of one electron of TMB molecule and produce the blue products. With the addition of isocarbophos, the pesticide molecules can interact with oligonucleotides to form some complexes, which relieve the inhibition of ssDNA to hemin and further enhance its catalytic activity. Thus, the TMB molecules are further oxidized to lose another electron and produce the yellow product in a few minutes, which has the characteristic absorption peak at 450 nm. The color change of the sensing system is related to the amount of isocarbophos, so this method can quickly discriminate whether the target pesticide exceeds the maximal residue limit just by naked eyes. To improve the performance of sensing platform, some important parameters like buffer condition and ssDNA have been investigated, and the peroxidase activity of hemin was further studied to verify the catalytic mechanism. The proposed sensing platform has a detection limit as low as 0.6 μg/L and displays good selectivity against other competitive pesticides. Moreover, the developed sensing platform also exhibits favorable accuracy and stability, indicating that it has potential applications in the detection of pesticide residues in agricultural products.

A novel colorimetric sensing platform based on oligonucleotides and pesticide regulation; the peroxidase catalytic activity of hemin was firstly reported for the ultrasensitive and selective detection of isocarbophos pesticide.

  相似文献   
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