固体氧化物燃料电池LSCF-SDC 纳米复合阴极制备及性能研究

利用硝酸盐溶液一次浸渗工艺在La0.6Sr0.4Co0.2Fe0.8O3-δ(LSCF)表面涂覆Sm0.2Ce0.8O2(SDC)纳米颗粒,制备了LSCF-SDC纳米结构复合阴极。微观结构分析显示SDC纳米颗粒在LSCF表面均匀分布并且颗粒大小均一。界面阻抗图谱表明SDC浸渗极大的降低了LSCF阴极的界面极化阻抗,在750和650℃仅为0.074,0.44Ω.cm2。LSCF-SDC复合阴极的表观活化能为1.42 eV,略小于纯LSCF阴极。与混合法制备的LSCF-GDC复合电极相比,采用浸渗工艺制备的LSCF-SDC纳米结构复合阴极也显示出良好的电化学催化活性。     

Electron tunneling in single layer graphene with an energy gap

When a single layer graphene is epitaxially grown on silicon carbide,it will exhibit a finite energy gap like a conventional semiconductor,and its energy dispersion is no longer linear in momentum in the low energy regime.In this paper,we have investigated the tunneling characteristics through a two-dimensional barrier in a single layer graphene with an energy gap.It is found that when the electron is at a zero angle of incidence,the transmission probability as a function of incidence energy has a gap.Away from the gap the transmission coefficient oscillates with incidence energy which is analogous to that of a conventional semiconductor.The conductance under zero temperature has a gap.The properties of electron transmission may be useful for developing graphene-based nano-electronics.     

高速太赫兹探测器

太赫兹(terahertz,THz)技术在高速空间通信、外差探测、生物医学、无损检测和国家安全等领域具有广阔的应用前景.能响应1 GHz调制速率以上THz光的高速THz探测器是快速成像、THz高速空间通信、超快光谱学应用技术和THz外差探测等领域的核心器件.传统的THz热探测器难以实现高速工作,而基于半导体的THz探测器在理论上可实现高速工作.光导天线具有超快的响应速度,可实现常温和宽谱探测;肖特基势垒二极管混频器、超导-绝缘体-超导混频器和超导热电子混频器具有转换效率高、噪声低等优点,可用于高速THz空间外差和直接探测;基于高迁移率二维电子气的天线耦合场效应晶体管灵敏度高、阻抗低,可实现常温高速THz探测;THz量子阱探测器是一种基于子带间跃迁原理的单极器件,非常适合高频和高速探测应用,亚波长金属微腔耦合机理可显著提高器件的工作温度及光子吸收效率.本文对上述几种高速THz探测器进行了综述并分析了各种探测器的优缺点.     

X射线光场成像技术研究

X射线三维成像技术是目前国内外X射线成像研究领域的一个研究热点.但针对一些特殊成像目标,传统X射线计算层析(CT)成像模式易出现投影信息缺失等问题,影响CT重建的图像质量,使得CT成像的应用受到一定的限制.本文主要研究了基于光场成像理论的X射线三维立体成像技术.首先从同步辐射光源模型出发,对X射线光场成像进行建模;然后,基于光场成像数字重聚焦理论,对成像目标场在深度方向上进行切片重建.结果表明:该方法可以实现对成像目标任一视角下任一深度的内部切片重建,但是由于光学聚焦过程中的离焦现象,会引入较为严重的背景噪声.当对其原始数据进行滤波后,再进行X射线光场重聚焦,可以有效消除重建伪影,提高图像的重建质量.本研究既有算法理论意义,又可应用于工业、医疗等较复杂目标的快速检测,具有较大的应用价值.     

Analysis of thermal stability and pyrolysis kinetic of dibutyl phosphate-based ionic liquid through thermogravimetry,gas chromatography/mass spectrometry,and Fourier transform infrared spectrometry

Journal of Thermal Analysis and Calorimetry - The impingement of CuO-water nanofluid flows upon a cylinder subject to a uniform magnetic field with constant surface temperature and embedded in...     

Simulation of Photocurrents of Terahertz Quantum-Well Photodetectors

We theoretically simulate the influence of the scattering processes of the electrons in the continuum states on the shapes of the photoeurrent spectra of THz quantum well photodetectors. The width of the photocurrent peak should be wider according to the uncertainty relation when these scattering processes lead to shorter relaxation time. We take a simple approximation model to include this influence and calculate the photocurrent spectra, which axe in agreement with experimental results qualitatively.     

丙烯和氧等离子体直接气相合成环氧丙烷

在室温和大气压下,在针板式反应器中,通过脉冲电晕放电等离子体对分子氧和丙烯直接合成环氧丙烷的活化作用,考察了放电电极间距、电晕放电脉冲电压以及电晕放电重复频率参数对丙烯转化率、环氧丙烷产率和其选择性的影响,反应物及各产物通过在线色谱法进行分析.实验结果表明,在室温和大气压下,用脉冲电晕等离子体法可转化丙烯和氧气直接生成环氧丙烷,适当调节上述各参数可提高环氧丙烷的收率.当反应气总流速为200mL/min,极间距为4mm,脉冲放电电压为18kV,放电频率为120Hz时,环氧丙烷的收率、丙烯的转化率及环氧丙烷的选择性分别为5.15%,19.15%和26.89%.     

Numerical Analysis of Multilayer Waveguides Using Effective Refractive Index Method

With the help of the effective refractive index method we have numerically analyzed a multilayer planar waveguide structure and calculated the propagation constants, confinement factors, and transverse electric (TE) modes. A five-layer waveguide model has been provided to analyze the electro-magne tic wave propagation process. The analysis method has been applied to the 980 nm laser with active layer of GaInAs/GaInAsP strained quantum wells, GaInAsP confinement layers and GaInP cap layers. By changing the thickness of confinement layers, we obtained confinement factor as high as 95% with higher TE modes TE1 and TE2. The results are in good agreement with the experiment by A. Al-Muhanna et al. and give the new idea to enhance output power of semiconductor lasers. The analysis method can also be extended to any other slab multilayer waveguide structures, and the results are useful to the fabrication of optic-electronic devices.     

Simulation of the Propagation Property of Metal Wires Terahertz Waveguides

The propagation property of metal wires terahertz waveguides is studied and simulated under the framework of the Sommerfeld model. The group velocity dispersion, attenuation amplitude, transverse magnetic mode and propagating energy have been obtained by numerically solving the complex eigenvalue equation for the propagation constant. It is found that the group velocity dispersion and attenuation amplitude decrease with the increasing radii of metal wires. The energy power within the dielectric layer increase with the increase of radiation frequency.     

太赫兹半导体探测器研究进展

太赫兹（THz）探测器是THz技术应用的关键器件之一．基于半导体的全固态THz量子阱探测器（THzQWIP）具有探测响应速度快、制作工艺成熟、体积小和易集成等优点．文章简要介绍了THz探测器的分类和特点，重点介绍了THzQWIP的工作原理和研究进展．