双硬配体修饰的{BW12O40}超分子化合物的水热合成及其超级电容性能

以苯并咪唑（biz）、乙二胺（en）为配体,K₅[BW₁₂O₄₀]为前驱体水热法合成了一种双硬配体修饰的超分子化合物（H₂biz）(Hbiz)[Co（en）₃][BW₁₂O₄₀]（1）.单晶结构分析表明,该化合物是由1个[BW₁₂O₄₀]^5-阴离子、1个[Co（en）₃]²⁺片段、单、双质子化的biz构成,并通过氢键或超分子作用形成1D到3D结构.以该化合物为活性物质制成玻碳电极,在电流密度为1 A·g^-1时,其比电容是473.15 F·g^-1.同时,该化合物具有较高的稳定性,5 000次循环后保持率达94.7%.标题化合物的电荷存储机制是扩散电荷和表面电荷相互作用.表明合成化合物是一种有实用价值的物质.     

高分子减阻剂研究进展

综述了近年来高分子减阻剂研究进展，对高分子减阻剂的两种主要合成方法进行了比较，详细阐述主催化剂、助催化剂、聚合物的相对分子质量及相对分子质量分布、聚合物的空间构型、聚合物后处理等对高分子减阻剂减阻性能的影响，对分子缔合型减阻剂也进行了概括。结合本课题组的研究，提出我国应加快减阻剂生产与应用的研究，减少对进口减阻剂的依赖。     

制备色谱法分离纯化高良姜黄酮中高良姜素和山柰素

建立了制备型高效液相色谱(Prep-HPLC)分离高良姜黄酮中高良姜素和山柰素的方法。高良姜黄酮经HPD-600树脂吸附洗脱纯化后,采用Prep-HPLC分离高良姜黄酮中高良姜素和山柰素。制备色谱条件:流动相为甲醇-0.6%(v/v)乙酸水溶液(58:42, v/v),柱温为常温,流速为7.0 mL/min,检测波长为360 nm,进样量为700 μ L,上样质量浓度为10.0 g/L。分离的单体由质谱和核磁共振氢谱、碳谱鉴定确证为高良姜素和山柰素,HPLC外标法定量,纯度分别为99.5%和99.7%。该方法分离效果好、高效、低毒,可用于高良姜中高良姜素和山柰素的分离制备。     

对"一个不寻常的错误引发的思考"的思考

文[1]观点有错误.该文指出: 　　解 "已知函数f(x)=|x-a|+1/x(x＞ )且f(x)≥1/2恒成立,求a的取值范围"这个问题中的变形:……     

HIRFL新B1聚束器频率微调系统的设计及稳定性分析

 频率自动调谐系统是聚束器的重要组成部分之一。频率调谐系统成功的研制和投入使用达到了使谐振腔体的固有谐振频率在22～54 MHz的范围内自动稳定在输入信号频率上的目的，频率自动微调系统达到了±5×10^-6的频率稳定度，解决了由于腔体失谐所造成的高频电压滑落的问题，由此在腔体的加速缝隙间得到稳定的高频电压，保证了聚束器系统的高质量可靠运行。     

不确定关联时滞大系统的自适应分散镇定控制

针对时变的满足一定匹配条件的不确定关联时滞大系统,利用自适应界化技术,给出了设计分散镇定控制器的自适应的方法.其特点是在假设中系统不确定项是有界的,但界是未知的,且在关联项存在时变时滞的情况下证明了闭环自适应系统的渐近稳定性.最后举例说明了该方法的有效性.     

Syntheses, Crystal Structures and Electrochemical Properties of Three New One-dimensional Compounds Based on the BiW9O33 Unit

Three new one-dimensional compounds [{NaO2(H2O)2}2{(M(H2O)2)2(WO2)2- (BiW9O33)2}]·16H3O+·XH2O (M = MnII (1), CoII (2), NiII (3)) have been synthesized in an aqueous solution, and structurally characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction. These tungstobismuthates reveal that one common feature is the trivacant β-B-BiW9O33 Keggin fragment as the structural building unit. Two β-B-BiW9O33 units are connected by two WO2 groups with further stabilization by the addition of two M(H2O)22+ groups leading to the M2Bi2W20 anions, which are linked in a 1-D chain by bisodium cluster. Electrochemical analyses show that compounds 1-3 display unique redox properties and good electrocatalytic activity to reduce nitrite.     

HIRFL 高频相位与幅度稳定系统

介绍了兰州重离子研究装置(HIRFL) 主回旋加速器(SSC) 高频系统高频电压的相位稳定与幅度稳定系统,重点介绍了设备的组成和稳定环路设计以及正交变换与稳定环路滤波器的设计方法。通过在SSC 腔体上进行的长期的现场测试,得到了调制抑制度与长期稳定度的测试方法,并对结果进行了分析。其中,设备的长期相位稳定度达到0:014°,长期幅度稳定度达到1.29x10-4,远高于改造前的指标。The phase and amplitude stabilization system of high-frequency voltage on the main cyclotron SSC of Heavy Ion Research Facility in Lanzhou (HIRFL) is introduced. The system composition, negative feedback loop design and other important aspects about the development of the system are particularly presented in this paper. Designing method of digital PLL orthogonal transformation and loop filter of phase and amplitude stabilization are introduced in detail. Control systems of SSC have been tested through a long-term stability experiments, the test method of the parasitic modulation suppression and stabilization in long term is proposed. According to the analyzing data, it shows that phase control accuracy in long term is within 0:014° and the amplitude deviation in long term is lower than 1.29x10-4. Compared with the traditional system, its capability and target is much better.     

RF system design and measurement of HIRF-CSRe

An RF system for the CSRe （cooling storage experimental ring） is designed and manufactured domestically. The present paper mainly describes the RF system design in five main sections： ferrite ring, RF cavity, RF generator, low level system and cavity cooling. The cavity is based on a type of coaxial resonator which is shorted at the end with one gap and loaded with domestic ferrite rings. The RF generator is designed in the push-pull mode and the low level control system is based on a DSP＋FGPA＋DDS＋USB interface and has three feedback loops. Finally we give the results of the measurement on our system.     

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建立了包含两种正离子的碰撞等离子体鞘层的流体模型,通过四阶龙格-库塔法模拟了碰撞对含有两种正离子的等离子体鞘层中的离子密度和速度分布产生的影响。结果表明,对于两种正离子的等离子体来说,鞘层中无论哪种离子与中性粒子碰撞频率的增加,该种离子的密度和速度分布都将呈现波动变化,密度是先增加后降低,速度是先降低后增加;而另一种离子的密度和速度呈单调变化。鞘边正离子的含量越少,受自身与中性粒子的碰撞频率增加,鞘层中该种离子密度先增加后降低的变化位置就越远离等离子体的鞘层边界。同时发现该种离子密度分布受自身碰撞频率增加,降低的幅度变化非常小。另外发现电子碰撞器壁产生的二次电子发射系数对质量较轻的离子影响要大一些。