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{[Eu(2,5-PDA)(OAc)(H2O)]·1.5H2O}n稀土配合物的晶体结构及荧光性质 总被引:4,自引:0,他引:4
在水热条件下合成了一个新的2,5-吡啶二羧酸的稀土配合物{[Eu(2,5-PDA)(Oac)(H2O)]·1.5H2O}n.通过元素分析和X射线单晶衍射确定了该化合物的组成和晶体结构, 并对荧光性质进行了表征.该晶体属单斜晶系, P21/n空间群, 晶胞参数a=0.935 01(15) nm, b=0.834 77(13) nm, c=1.677 9(3) nm, β=106.18°;V=1.257 8(3) nm3, Z=4, 最后的一致性因子[I>2σ(I)]: R1=0.024 3, Wr2=0.060 5.标题化合物中醋酸根的羧基以螯合-桥联三齿的方式将2个不对称单元中的铕离子连接起来形成二核单元, 2,5-PDA配体分别从与醋酸根和铕离子的平面成88°和56°夹角的方向将二核单元连接起来, 从而形成了由配位键构筑的三维结构, 未配位水分子通过氢键存在于晶体中. 相似文献
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We present a new method for image encryption on the basis of simplifed fractional Hartley transform (SFRHT). SFRHT is a real transform as Hartley transform (HT) and furthermore, superior to HT in virtue of the advantage that it can also append fractional orders as additional keys for the purpose of improving the system security to some extent. With this method, one can encrypt an image with an intensity-only medium such as a photographic film or a CCD camera by spatially incoherent or coherent illumination. The optical realization is then proposed and computer simulations are also performed to verify the feasibility of this method. 相似文献
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