吸附树脂分离纯化枇杷花总黄酮的研究

比较了D-101、D-160、AB-8、NKA-9和聚酰胺等5种吸附树脂对枇杷花总黄酮的吸附及解吸附性能。在静态吸附和动态吸附实验基础上,筛选出效果较好的AB-8树脂进行动态吸附参数的研究。考察了样品液pH值、样品液浓度、洗脱液浓度、上样速度、洗脱速度等对AB-8树脂吸附和解吸效果的影响,确定了AB-8树脂动态吸附枇杷花总黄酮的最佳条件。获得的最佳纯化条件如下,样品液pH值为5.5,样品液浓度为12mg/mL,洗脱液为30%的乙醇水溶液,上样速度为2BV/h,洗脱速度为1BV/h。纯化后样品总黄酮含量达86.7%,比纯化前总黄酮含量高5~6倍。实验结果表明,AB-8树脂可用于分离纯化枇杷花总黄酮。     

核壳结构AgInS2@ZnS量子点的合成及荧光性能

合成了一种新型核壳结构的AgInS₂@ZnS量子点并研究了其荧光性能. AgInS₂@ZnS的合成包括以变性牛血清白蛋白(dBSA)为稳定剂水相法构建AgInS₂核以及形成ZnS壳两部分. 考察了配方和工艺条件对该量子点荧光性能的影响, 并采用X射线粉末衍射(XRD)等手段对制备的纳米粒子进行了表征. 结果表明, AgInS₂@ZnS是一种核壳结构的纳米物质, 其粒径介于5~7 nm之间, 荧光量子产率达35.3%.     

约束含参分岔问题的分类

约束边界与分岔参数有关的约束分岔问题,称为约束含参分岔问题．通过引入适当的变换,将约束含参分岔问题转化为新变量的非约束分岔问题,推导出了约束含参分岔问题转迁集的一般形式,结果表明只有约束分岔集受约束含参的影响,其它转迁集与不含参约束分岔的转迁集相同．以含参约束树枝分岔为例分析了此类问题的分岔分类,讨论了约束含参对分岔分类的影响．     

Searching for sub-MeV boosted dark matter from xenon electron direct detection

Direct detection experiments tend to lose sensitivity in searches for sub-MeV light dark matter candidates due to the threshold of recoil energy.However,such light dark matter particles could be accelerated by energetic cosmic rays,such that they could be detected with existing detectors.We derive constraints on the scattering of a boosted light dark matter particle and electron from the XENON100/1T experiment.We illustrate that the energy dependence of the cross section plays a crucial role in improving both the detection sensitivity and also the complementarity of direct detection and other experiments.     

Classification of parametrically constrained bifurcations

If the constraint boundary relates to a bifurcation parameter, a bifurcation is said to be parametrically constrained. Relying upon some substitution, a parametrically constrained bifurcation is transformed to an unconstrained bifurcation about new variables. A general form of transition sets of the parametrically constrained bifurcation is derived. The result indicates that only the constrained bifurcation set is influenced by parametric constraints, while other transition sets are the same as those of the corresponding nonparametrically constrained bifurcation. Taking parametrically constrained pitchfork bifurcation problems as examples, effects of parametric constraints on bifurcation classification are discussed.     

压杆稳定性问题浅议

对于压杆稳定问题,很容易误认为,只有当轴向压力等于临界载荷及其若干整数倍时,杆件才有曲线平衡解,才会失稳;当轴向压力介于临界载荷整数倍之间时,杆件不存在曲线平衡解,不会失稳,这与实际情况不符.利用曲率的精确公式,探讨了造成这一问题的原因,说明了拉杆不会失稳的原因,描述了随着压力增大压杆挠曲线的变化情况.     

基于模板剥离法制备高性能钙钛矿单晶薄膜光电探测器

近年来,杂化钙钛矿半导体材料由于其带隙可调、吸收系数高、载流子迁移率高、成本低廉等诸多优点,在光电器件领域备受青睐,如太阳能电池、电致发光器件、光电探测器等。其中,钙钛矿单晶薄膜因其无晶界、杂质和缺陷含量低等特点,展现出更为优异的光学、电学特性,成为制备高性能光电器件的理想材料体系。然而,钙钛矿单晶薄膜常采用空间限域法直接生长在空穴传输层上,不可避免地将导致界面缺陷和载流子层间输运等问题,严重制约了钙钛矿单晶薄膜光电探测器的性能。为此,本文通过引入模板剥离法工艺技术,在钙钛矿单晶薄膜两侧分别蒸镀功能层材料,制备了结构为Cu/BCP/C₆₀/MAPbBr₃/MoO₃/Ag的钙钛矿单晶薄膜光电探测器。基于模板剥离法,两侧蒸镀的功能层与钙钛矿单晶薄膜接触紧密,将有效改善载流子的注入和传输;同时,优化的器件结构以及考虑能带匹配等因素可实现高灵敏、响应快速的钙钛矿单晶薄膜光电探测器。改进后器件的开关比高达3.1×10³,响应度可达7.15 A/W,探测率为5.39×10¹² Jones,...     

水溶性功能化Ag2S量子点的合成及其对超痕量Hg2+的双模式分析应用

以巯基丙酸为稳定剂,在乙二醇存在下合成了水溶性功能化Ag2S量子点。研究了该量子点的特性及其与常见金属离子的相互作用,发现仅Hg2+能够猝灭该量子点体系的荧光并使溶液变色,基于该现象建立了裸眼-荧光双模式选择性识别水体中痕量Hg2+的新方法。实验数据显示,在裸眼模式下,常见金属离子中只有Hg2+使Ag2S量子点的颜色由黄色变为无色;在荧光模式下,常见金属离子中只有Hg2+对量子点荧光猝灭最大,并且随着Hg2+浓度的增大Ag2S量子点的荧光猝灭越来越显著。研究表明,Hg2+与Ag2S量子点的作用机制可能为电荷转移致使量子点聚集而发生荧光猝灭。在优化条件下,8.0×10-9～5.6×10-8 mol/L浓度的Hg2+与Ag2S量子点荧光的猝灭呈良好的线性关系(R=0.9903),检出限(S/N=3)为4.2×10-9 mol/L,裸眼可识别9.0×10-5 mol/L的Hg2+。该方法成功地应用于水样中超痕量Hg2+的检测。     

Confronting the DAMPE excess with the scotogenic type-Ⅱ seesaw model

The DArk Matter Particle Explorer(DAMPE) has observed a tentative peak at E ~ 1.4 Te V in the cosmic-ray electron spectrum.In this paper,we interpret this excess in the scotogenic type-Ⅱ seesaw model.This model extends the canonical type-Ⅱ seesaw model with dark matter(DM) candidates and a loop-induced vacuum expectation value of the triplet scalars,v?,resulting in small neutrino masses naturally even for Te V scale triplet scalars.Assuming a nearby DM subhalo,the DAMPE excess can be explained by DM annihilating into a pair of triplet scalars which subsequently decay to charged lepton final states.Spectrum fitting of the DAMPE excess indicates it potentially favors the inverted neutrino mass hierarchy.We also discuss how to evade associated neutrino flux in our model.     

利用计算全息技术重构激光超声的激发面源

把计算全息技术引入激光超声无损检测系统,此系统借助直接搜索算法生成计算全息图,利用空间光调制器液晶器件代替传统全息干板再现全息图像,并将此生成、再现方法具体用于空间调制的脉冲激光源的产生,以辅助固体表面的窄带超声波的激发。由于算法的稳健性和重建方法灵活性,大大简化了激光超声实验系统,缩短了实验周期,在激光超声无损检测领域有广泛的应用空间。