全文获取类型
收费全文 | 19367篇 |
免费 | 3726篇 |
国内免费 | 3331篇 |
专业分类
化学 | 15418篇 |
晶体学 | 352篇 |
力学 | 950篇 |
综合类 | 238篇 |
数学 | 2023篇 |
物理学 | 7443篇 |
出版年
2024年 | 52篇 |
2023年 | 385篇 |
2022年 | 514篇 |
2021年 | 746篇 |
2020年 | 938篇 |
2019年 | 957篇 |
2018年 | 801篇 |
2017年 | 762篇 |
2016年 | 1028篇 |
2015年 | 1116篇 |
2014年 | 1337篇 |
2013年 | 1694篇 |
2012年 | 1914篇 |
2011年 | 1923篇 |
2010年 | 1449篇 |
2009年 | 1351篇 |
2008年 | 1498篇 |
2007年 | 1230篇 |
2006年 | 1114篇 |
2005年 | 897篇 |
2004年 | 779篇 |
2003年 | 624篇 |
2002年 | 617篇 |
2001年 | 446篇 |
2000年 | 381篇 |
1999年 | 370篇 |
1998年 | 245篇 |
1997年 | 192篇 |
1996年 | 183篇 |
1995年 | 132篇 |
1994年 | 132篇 |
1993年 | 99篇 |
1992年 | 87篇 |
1991年 | 93篇 |
1990年 | 60篇 |
1989年 | 54篇 |
1988年 | 35篇 |
1987年 | 25篇 |
1986年 | 45篇 |
1985年 | 38篇 |
1984年 | 13篇 |
1983年 | 12篇 |
1982年 | 11篇 |
1981年 | 6篇 |
1979年 | 5篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1968年 | 3篇 |
1957年 | 5篇 |
1936年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 343 毫秒
1.
Yujie Gao Zhiye Qiu Lei Liu Mengmeng Li Bingjie Xu Dan Yu Dongming Qi Jindan Wu 《Journal of polymer science. Part A, Polymer chemistry》2022,60(15):2191-2212
Refractory wounds have always been an important issue to healthcare systems, whose healing process is always delayed by multiple factors, including bacterial infections, chronic inflammation, and excessive exudates, etc. Employing multifunctional wound dressings is recognized as an effective strategy to deal with refractory wounds, which has yielded promising outcomes in recent years. Among these advanced wound dressings, fibrous dressings have gained growing attention due to their unique merits. Such wound dressings have demonstrated great potential in delivering theranostic agents, such as antibacterial agents, anti-inflammatory drugs, growth factors, and diagnostic probes, etc., for the purposes of accelerating wound healing. This paper reviews the development of multifunctional fibrous dressings and their applications in treating refractory wounds. The construction approaches of novel fibrous dressing with capabilities of antibacterial, anti-inflammation, exudate management and diagnosis were also introduced. Furthermore, the existing problems and challenges are also discussed briefly. 相似文献
2.
Tian Xiu-Zhi Yang Rui Ma Jia-Jia Ni Yong-Hao Deng Hai-Bo Dai Lei Tan Jiao-Jun Zhang Mei-Yun Jiang Xue 《高分子科学》2022,40(7):789-798
Chinese Journal of Polymer Science - Antistatic and strength properties are of vital importance for polyurethane rubber used in moving parts of many industrial instruments. Herein, polyurethane was... 相似文献
4.
Liu Jun-Wei Shen Shu-Qian Li Ming Li Lei 《International Journal of Theoretical Physics》2021,60(5):1712-1719
International Journal of Theoretical Physics - Quantum coherence, coming from quantum superposition, occupies a significant position in the field of physics. We put forward a lower bound of the... 相似文献
5.
6.
将有机物2,5-二溴对苯二甲酸(H2L1)和2,2′-联吡啶(L2)作为双配体,使用溶剂热法和七水合硫酸锌(ZnSO4·7H2O)、六水合硝酸钴(Co(NO3)2·6H2O)分别反应,得到配合物[Zn(L1)(L2)(H2O)]n(1)和配合物[Co(L1)(L2)(H2O)]n(2)。采用单晶X射线衍射、元素分析、红外光谱、紫外光谱、荧光光谱、热重分析等测试方法对这两种物质进行分析研究。单晶测试结果表明配合物1是单斜晶系,以Zn2+配位连接L2-1与L2形成一维链状结构,各条链在分子间氢键和π…π共轭作用下有规律地堆叠形成三维网络结构。配合物2是三斜晶系,Co1离子和Co1i离子由H2L1上的羧酸氧原子O4和O4i连接,形成双齿螯合的配位结构单元,以Co2+配位连接 L2-1和L2形成二维网格结构,各层在O—H…O分子间氢键和范德瓦耳斯力作用下有规律的堆叠形成三维网络结构。配合物1和2均含有芳香杂环、羧基杂环和氮杂环,具有良好的荧光性质和热稳定性,最大发射波长分别为345 nm和333 nm。 相似文献
7.
8.
Lei Chen Hui-Qing Yang Cheng-Yu Jin Zhao-Xu Chen 《International journal of quantum chemistry》2020,120(22):e26366
We studied the ring opening of propylene oxide (PO) by salen-M coordinated OH− group [M = Al(III), Sc(III), Cr(III), Mn(III), Fe(III), Co(II), Co(III), Ni(II), Cu(II), Zn(II), Ru(III) and Rh(III)]. The results show that the ring-opening energy barriers for M(II) complexes are much lower than those with M(III) complexes in the gas phase, and the barriers correlate linearly with the negative charges on the OH− group and the Fukui function condensed on the OH− group. The nucleophilicity ordering in the gas phase can be rationalized by the ratio of formal positive charges/radius of M cations. Solvent effect greatly increases the barriers of M(II) complexes but slightly changes the results of M(III) ones, making the barriers similar. Analysis indicates that the reaction heats are linearly proportional to the reverse reaction barriers. The relationships established here can be used to estimate the ring-opening barriers and to screen epoxide ring-opening catalysts. 相似文献
9.
Annals of the Institute of Statistical Mathematics - To obtain M-estimators of a response variable when the data are missing at random, we can construct three bias-corrected nonparametric... 相似文献
10.
Jie Lu Ju-Kang Wu Yao Jiang Dr. Peng Tan Lin Zhang Yu Lei Prof. Xiao-Qin Liu Prof. Lin-Bing Sun 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6490-6496
Hierarchically porous metal–organic frameworks (HP-MOFs) are promising in various applications. Most reported HP-MOFs are prepared based on the generation of mesopores in microporous frameworks, and the formed mesopores are connected by microporous channels, limiting the accessibility of mesopores for bulky molecules. A hierarchical structure is formed by constructing microporous MOFs in uninterrupted mesoporous tunnels. Using the confined space in as-prepared mesoporous silica, highly dispersed metal precursors for MOFs are coated on the internal surface of mesoporous tunnels. Ligand vapor-induced crystallization is employed to enable quantitative formation of MOFs in situ, in which sublimated ligands diffuse into mesoporous tunnels and react with metal precursors. The obtained hierarchically porous composites exhibit record-high adsorption capacity for the bulky molecule trypsin. The thermal and storage stability of trypsin is improved upon immobilization on the composites. 相似文献