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1.
The compression behaviour of Ni77P23 amorphous alloy is investigated at room temperature in a diamond-anvil cell instrument using in-situ high pressure energy dispersive x-ray diffraction with a synchrotron radiation source. The equation of state is determined by fitting the experimental data according to the Birch-Murnaghan equation. It is found that the structure of Ni77P23 amorphous alloy is stable under pressures up to 30.5 GPa. Within the pressure range from zero to the experimental one, the pressure-induced structural relaxation is reversible. 相似文献
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含硼杂原子Na-B-ZSM-5分子筛对甲醇脱氢制甲醛反应的催化性能 总被引:1,自引:0,他引:1
以白炭黑为硅源、硼酸为硼源、NaOH为碱源、四丙基溴化铵(TPABr)和1,6-己二胺(HMDA)混合模板剂,采用水热合成法制备含硼杂原子Na-B-ZSM-5分子筛,用XRD、SEM、FT-IR、UV-vis、11B MAS NMR、NH3-TPD等方法对其进行表征。在连续流动常压固定床反应器上评价Na-B-ZSM-5分子筛对甲醇脱氢制甲醛反应的催化性能,考察n(Si)/n(B)、n(Na2O)/n(SiO2)、晶化温度和晶化时间等制备参数以及反应温度和质量空速等工艺参数对催化性能的影响。结果表明,硼进入了分子筛的骨架结构中,存在与B酸中心有关的骨架四配位硼和与L酸中心有关的骨架三配位硼,Na-B-ZSM-5分子筛含有较多的弱酸位和少量的中强酸位。催化剂的最佳制备参数为n(Si)/n(B)比值为7.5、n(Na2O)/n(SiO2)比值为0.14、晶化温度170℃、晶化时间48 h。Na-B-ZSM-5(7.5)分子筛在反应温度550℃、质量空速1.85 h-1的反应条件下对甲醇的转化率为62.97%,甲醛的选择性为68.86%。 相似文献
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By employing the first-principles pseudopotential plane-wave method, the physical properties of zincblende ZnO are investigated in comparison with those of the common wurtzite structure. Zincblende ZnO is predicted to be a direct gap semiconductor. Compared to the wurtzite structure, the zincblende ZnO is characterized by smaller bandgap and pressure coefficient, larger electron effective mass, increasing static dielectric constants and more covalent bonding. Furthermore, the optical properties including dielectric function and energy loss function of zincblende ZnO were obtained and analysed with some features. These aspects reveal promising applications of zincblende ZnO in optoelectronic devices. 相似文献
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用类金刚石碳掩膜制备LaAlO3台阶衬底 总被引:2,自引:1,他引:1
我们用脉冲激光淀积(PLD)方法在LaAlO3(LAO)衬底上生长了类金刚石碳(DLC)膜,并以此作为掩模,制备了台阶衬底.SEM分析表明,制备的台阶衬底具有陡直的台阶角度(大于700).我们用这样的台阶衬底制成了YBCO台阶结并测量了结的基本特性,结果表明,结有较好的高频特性. 相似文献
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<正>A 128×128 elements cylindrical liquid crystal(LC) lens array with electrically controllable focal length is proposed.The cylindrical LC lens array uses transparent indium tin oxide(ITO) films as electrode,avoiding to affect the optical path operating in the voltage-off status.As the top electrode of the cylindrical LC lens array contacts with LC,the operation voltage root-mean-square(RMS) amplitude can be as low as 1.4 V and the response time is about 20-30 ms.The special optical focusing feature of the cylindrical LC lens array is got.And the focal length of this array is about 60-450μm. 相似文献
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The structural,elastic, and electronic properties of ZrxNbl-xC alloys from first principle calculations* 下载免费PDF全文
The structural, elastic, electronic, and thermodynamic properties of ZrxNbl xC alloys are investigated using the first principles method based on the density functional theory. The results show that the structural properties of Zr~.Nb1 xC alloys vary continuously with the increase of Zr composition. The alloy possesses both the highest shear modulus (215 GPa) and a higher bulk modulus (294 GPa), with a Zr composition of 0.21. Meanwhile, the Zr0.2! Nb0.79C alloy shows metallic conductivity based on the analysis of the density of states. In addition, the thermodynamic stability of the designed alloys is estimated using the calculated enthalpy of mixing. 相似文献