Eu,Dy共掺杂SrAl2O4长余辉材料制备新工艺

活化Al-Sr合金粉末水解制备SrAl₂O₄长余辉材料的前驱体,并采用高温固相反应法制备出Eu,Dy共掺杂的SrAl₂O₄长余辉材料,对其微观结构和发光特性进行了研究。实验结果表明:前驱体中Al、Sr元素在微观状态下分布均匀,所制成的长余辉发光材料的发射主峰位于520nm附近,为典型的Eu²⁺离子4f5d-4f的特征发射,初始亮度达到18cd/m²,余辉时间长达46h。     

Cs3Cu2I5晶体薄膜吸收谱的研究

本文测定了Ｃｓ３Ｃｕ２ Ｉ５ 晶体薄膜在室温及液氮温度下的吸收谱,并依此计算出该材料的激子参数,即激子束缚能ΔＥ（１）ｅｘ ＝ （０．５３±０．０７）ｅＶ,激子半径ａｅｘ ＝ ０．３２６ ｎｍ ,禁带宽度Ｅｇ ＝ （５．００±０．０７）ｅＶ。在谱分析的基础上,论证了Ｃｓ３Ｃｕ２Ｉ５ 的电子和激子激发定域在该晶体的ＣｕＩ亚晶格之中,同时,揭示了在低温下Ｃｓｘ Ｃｕ１－ ｘ Ｉ系列化合物的第一激子峰位置随其摩尔组分变化的规律。     

胶粘剂对石英音叉剪切力控距的影响

粘接音叉和光纤探针的胶粘剂对由石英音叉和光纤探针构成剪切力控距体系的品质因数有明显的影响。通过对比不同胶粘剂的物理特性 ,选择了适合于粘接音叉和光纤探针的胶粘剂。研究发现 ,室温快速固化环氧树脂胶粘剂HY 91 4 ,GHJ光学用环氧型胶粘剂 (Opticalepoxy)和 50 2胶能满足实验要求。理论分析指出 ,对于同样的音叉和光纤探针来说 ,胶粘剂的密度和用量是影响音叉 探针体系品质因数的主要因素     

宏观长Ag2S纳米线簇的制备及其温度电导特性和光电导特性

以固态离子学方法制备的宏观长银(Ag)纳米线簇为基础,采用气-固反应法制备出宏观长硫化银(Ag₂S)纳米线簇.利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、能量色散谱(EDS)和X射线光电子能谱(XPS)等手段对样品形貌和成分进行表征.将厘米长的Ag₂S纳米线簇两端涂敷金胶作为电极,并与外电路连接.在不同温度或采用不同波长的光束辐照下,测试了样品的输运性质.无光照时,在144—380 K的温度范围内,样品的电导随温度上升而非线性增大.室温下,Ag关键词： 硫化银纳米线 温度电导 光电导     

行星齿轮传动的模糊优化设计

根据齿轮传动可靠性与优化设计的相关性,建立起双级行星齿轮传动在合理可靠性条件下的优化设计数模。在寻求多目标优化全局最优解过程中,为减少全局寻优的盲目性,解决统一权法加权处理的困难,应用了模糊集合概念和贴近度算法,从而克服了原设计方案可靠性方面的缺陷,使设计参数更加先进、合理、准确。     

FABRICATION AND APPLICATION OF NEAR-FIELD OPTICAL FIBRE PROBE

In this paper, the fabrication of a large cone angle near-field optical fibre probe, using the two-step chemical etching method and bent probe, is introduced, and the controlling parameters of the coated Cr－Al film at the probe tip are presented. The scanning electron microscopy images display that the tip diameter of the uncoated large cone angle fibre probe obtained is less than 50nm, the cone angle over 90°, and the diameter of light aperture at the coated probe tip is less than 100nm. The measured results of the optical transmission efficiency for various probe tips show that the uncoated straight optical fibre probe, film-coated straight probe and film-coated bent probe are 3×10^-1, 2×10^-3, and 1×10^-4 times that of the flat fibre probe, respectively. In addition, the force images and near-field optical images of a standard sample are acquired using a large cone angle and film-coated bent probe.     

Ferroelectric Ba0.75Sr0.25TiO3 tunable charge transfer in perovskite devices

Interfacial charge recombination is a main issue causing the efficiency loss of the perovskite solar cells (PSCs). Here, ferroelectric Ba_0.75Sr_0.25TiO₃ (BST) is introduced as a polarization tunable layer to promote the interfacial charge transfer of the PSCs. The coexistence of ferroelectric polarization and charge carriers in BST is confirmed by density functional theory (DFT) calculations. Experimental characterization demonstrates the polarization reversal and the existence of domain in BST film. The BST film conductivity is tested as 2.98×10^-4 S/cm, which is comparable to the TiO₂ being used as the electron transporting layer (ETL) in PSCs. The calculations results prove that BST can be introduced into the PSCs and the interfacial charge transfer can be tuned by ferroelectric polarization. Thus, we fabricated the BST-based PSCs with a champion power conversion efficiency (PCE) of 19.05% after poling.     

基于金/硅纳米线阵列肖特基结的自驱动式的可见-近红外光探测器性能研究

本文成功构筑了金/硅纳米线(Au/SiNWs)阵列自驱动式可见-近红外光探测器.探测器在暗态时表现出良好的二极管整流特性,在±1 V偏压下,整流比达584.在可见-近红外光照下,光探测器具有明显的光生伏特效应.光探测性能研究表明:当无外加偏压时,探测器对波长为405 nm、532 nm和1064 nm的光源具有较高的响应率,并且响应快速、信号稳定,重现性良好;当给器件施加一个很小的正偏压时,通过暗态和照光的切换,探测器可使外电路中的电流快速地正负交替变化,从而实现一种快速、有效的二进制光响应.自驱动式Au/SiNWs阵列光探测器显示了高灵敏、快速、宽光谱响应特性,具有巨大的应用前景.     

Al(OH)3和Sr(OH)2复合粉末的制备及性能研究

本文采用活化Al-Sr合金粉末水解反应制备Al(OH)3和Sr(OH)2复合粉末,利用XRD,SEM,EDS,BET及激光粒度仪对复合粉末进行结构和性能研究.研究结果表明,Al(OH)3和Sr(OH)2的复合粉末中Sr/Al比例与配比相比有所偏移,但在复合粉末中两者均匀混合,具有化学组成的微观均匀性.复合粉末微观形貌为1～3μm片状小颗粒叠加的团聚颗粒,BET比表面积较大,达到45.2m2/g,水解产物粒度分布均匀,D50为27.58μm,D25/D75为0.76.     

Absorption Spectra and Ionic Conductivity of RbxCs1-xAg4I5 Superionic Conductors Thin Films

A series of RbxCs1-xAg4I5(x=0-1) thin films were grown by vacuum evaporation on NaCI crystal substrates at 350K. The absorption spectra of these films were measured at 80K in the wavelength range from 240nm to 400nm. It is shown that superionic conductor thin films of quaternary compound Rb0.5Cs0.5Ag4I5 and ternary compound RbAg415 can be obtained at x=0.5-0.6 and x=0.7-1, respectively. At x=0.65, the combined compound film of the mixture of 30mol% RbAg4I5 and 70mol% Rb0.5Cs0.5Ag4I5 is presented. Then, based on the spectral positions of the A1 and A2 peaks, we determined that the Rb0.5Cs0.5Ag4I5 exciton coupling energy Rex is 0.21eV, the forbidden zone width Eg is 3.82eV and the exciton radius aex is 0.70hm. Furthermore, the ionic conductivities of superionic conductor thin films of RbAg4I5 and Rb0.5Cs0.5Ag4I5 and their mixture film are investigated, respectively, in the temperature range 303 K-393K.