全文获取类型
收费全文 | 2543篇 |
免费 | 366篇 |
国内免费 | 298篇 |
专业分类
化学 | 1934篇 |
晶体学 | 40篇 |
力学 | 134篇 |
综合类 | 21篇 |
数学 | 241篇 |
物理学 | 837篇 |
出版年
2024年 | 4篇 |
2023年 | 60篇 |
2022年 | 39篇 |
2021年 | 98篇 |
2020年 | 116篇 |
2019年 | 114篇 |
2018年 | 71篇 |
2017年 | 78篇 |
2016年 | 109篇 |
2015年 | 137篇 |
2014年 | 137篇 |
2013年 | 174篇 |
2012年 | 245篇 |
2011年 | 256篇 |
2010年 | 158篇 |
2009年 | 136篇 |
2008年 | 164篇 |
2007年 | 147篇 |
2006年 | 125篇 |
2005年 | 116篇 |
2004年 | 85篇 |
2003年 | 65篇 |
2002年 | 78篇 |
2001年 | 44篇 |
2000年 | 46篇 |
1999年 | 44篇 |
1998年 | 51篇 |
1997年 | 53篇 |
1996年 | 53篇 |
1995年 | 32篇 |
1994年 | 32篇 |
1993年 | 30篇 |
1992年 | 18篇 |
1991年 | 21篇 |
1990年 | 18篇 |
1989年 | 15篇 |
1988年 | 3篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1980年 | 2篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1969年 | 1篇 |
1966年 | 1篇 |
1957年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有3207条查询结果,搜索用时 296 毫秒
1.
2.
A nanomaterials-based novel molecular beacon has attracted growing attentions in fluorescent assays as many nanomaterials possess excellent quenching efficiency. In this work, a gold-based nanobeacon probe was established to detect organophosphorus pesticides for the first time. The constructed gold-based nanobeacon acted as a signal indicator and could display the decreasing of the intensity in the presence of targets, which competitively bound to single strand DNA. To achieve a high sensitive probe, some parameters including solution pH, temperature and reaction time were investigated and optimized. The gold-based nanobeacon probe assay was proved to be rapid and sensitive to achieve a detection limit of 0.035 μM for isocarbophos, 0.134 μM for profenofos, 0.384 μM for phorate and 2.35 μM for omethoate, respectively. The prepared nanobeacon effectively reduced the background and improved the detection sensitivity and selectivity. The probe is stable, easy to operate and does not need sophisticated instruments. These features makes the probe feasible for screening trace organophosphorus pesticides in real samples. 相似文献
3.
4.
Yaping Chen Dr. Kun Rui Prof. Jixin Zhu Prof. Shi Xue Dou Dr. Wenping Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(3):703-713
Developing clean and sustainable energies as alternatives to fossil fuels is in strong demand within modern society. The oxygen evolution reaction (OER) is the efficiency-limiting process in plenty of key renewable energy systems, such as electrochemical water splitting and rechargeable metal–air batteries. In this regard, ongoing efforts have been devoted to seeking high-performance electrocatalysts for enhanced energy conversion efficiency. Apart from traditional precious-metal-based catalysts, nickel-based compounds are the most promising earth-abundant OER catalysts, attracting ever-increasing interest due to high activity and stability. In this review, the recent progress on nickel-based oxide and (oxy)hydroxide composites for water oxidation catalysis in terms of materials design/synthesis and electrochemical performance is summarized. Some underlying mechanisms to profoundly understand the catalytic active sites are also highlighted. In addition, the future research trends and perspectives on the development of Ni-based OER electrocatalysts are discussed. 相似文献
5.
6.
7.
两段级联掺铒光纤放大器的优化研究 总被引:7,自引:4,他引:3
基于Giles模型,研究了980 nm和1480 nm泵浦的两段级联掺铒光纤放大器(EDFA)的设计,得出了掺铒光纤(EDF)的最佳长度和光隔离器的最佳位置随泵浦功率和信号功率的变化关系.比较980 nm和1480 nm泵浦的两段级联EDFA,可以发现,前者的最佳EDF长度短,而光隔离器最佳位置距EDFA输入端远. 相似文献
8.
Zhihui Zhao Hui Dai Xiangmei Wu Haitao Chang Xiaoming Gao Mengjun Liu Pengfei Tu 《Chemistry of Natural Compounds》2007,43(4):374-376
A pectic polysaccharide was isolated from the fruits of Ziziphus jujuba Mill. cv. jinsixiaozao Hort. and its structure was characterized by acid hydrolysis, methylation, and NMR spectroscopies.
The purified fraction Ju-B-7 had a molecular mass of over 2000 kDa. Chemical and spectroscopic analyses indicated that Ju-B-7
is composed mainly of α-1,4-linked D-galactopyranosyluronic acid and 1,2-linked L-rhamnose with a molar ratio of 8.1:1. It can significantly stimulate
spleen cell proliferation in vitro (P<0.01, 10 μmg/mL).
Published in Khimiya Prirodnykh Soedinenii, No. 4, pp. 311–312, July–August, 2007. 相似文献
9.
10.
1引言许多科学和工程计算问题都可以归结为无界区域上的偏微分方程边值问题.而求解椭圆方程边值问题的常用技术是有限元方法,可是对于无界区域,在用有限元方法求解时,往往遇到困难.最简单的办法显然是直接略去区域的无界部分求解,但这样做或者导致过低的计算精度,或者要付出很高的计算代价.边界归化,即将求解偏微分方程边值问题转化为边界积分方程,是求解某些无界区域问题的强有力的手段.自70年代以来,有限元和 相似文献