Rhodium(III)‐Catalyzed ortho Alkenylation of N‐Phenoxyacetamides with N‐Tosylhydrazones or Diazoesters through CH Activation

A coupling reaction of N‐phenoxyacetamides with N‐tosylhydrazones or diazoesters through Rh^III‐catalyzed C? H activation is reported. In this reaction, ortho‐alkenyl phenols were obtained in good yields and with excellent regio‐ and stereoselectivity. Rh–carbene migratory insertion is proposed as the key step in the reaction mechanism.     

Rhodium(III)‐Catalyzed Transannulation of Cyclopropenes with N‐Phenoxyacetamides through CH Activation

An efficient rhodium(III)‐catalyzed synthesis of 2H‐chromene from N‐phenoxyacetamides and cyclopropenes has been developed. The reaction represents the first example of using cyclopropenes as a three‐carbon unit in rhodium(III)‐catalyzed C(sp²)? H activations.     

Temperature Dependent In-Plane Anisotropic Magnetoresistance in HfTe_5 Thin Layers

We report the observation of in-plane anisotropic magnetoresistance and planar Hall effect in non-magnetic HfTe₅ thin layers.The observed anisotropic magnetoresistance as well as its sign is strongly dependent on the critical resistivity anomaly temperature T_p.Below T_p,the anisotropic magnetoresistance is negative with large negative magnetoresistance.When the in-plane magnetic field is perpendicular to the current,the negative longitudinal magnetoresistance reaches its maximum.The negative longitudinal magnetoresistance effect in HfTe₅ thin layers is dramatically different from that induced by the chiral anomaly as observed in Weyl and Dirac semimetals.One potential underlying origin may be attributed to the reduced spin scattering,which arises from the in-plane magnetic field driven coupling between the top and bottom surface states.Our findings provide valuable insights for the anisotropic magnetoresistance effect in topological electronic systems and the device potential of HfTe5 in spintronics and quantum sensing.     

Identification and cloning of molecular markers for UV-B tolerant gene in wild sugarcane (Saccharum spontaneum L.)

Previously we have selected wild sugarcane (Saccharum spontaneum L.) sterile lines that are tolerant or susceptible to UV-B radiation based on response index (RI) in a field screening test. The RI was established according to plant height, tiller number, leaf index, total biomass and brix under enhanced ultraviolet-B (UV-B, 280-310 nm) radiation. In this experiment, molecular markers linked to the UV-B tolerant and susceptible genes were identified and cloned. RAPD (Randomly amplified polymorphic DNAs) assay using 100 arbitrary primers followed by clustering analysis separated the tolerant and susceptible lines into two groups at the genetic distance of 0.380. The UV-B tolerant and susceptible gene pools were constructed and compared using the Bulked Segregate Analysis (BSA) approach. Of the 100 arbitrary RAPD primers, primer OPR16 produced polymorphic DNA banding patterns from both gene pools. The OPR16-1200 bp DNA fragment was only amplified from the tolerant lines and the OPR16-800 bp from the susceptible ones. These two PCR fragments were cloned onto T-vector. DNA sequence alignment analysis determined that 42% homology existed between the reverse and forward sequences of the OPR16-1200 bp clone, and 36% homology between the forward sequences of the OPR16-800 bp and OPR16-1200 bp clones. The two DNA clones were determined to be linked to the UV-B tolerant and susceptible genes, and they can be used to develop molecular markers for the associated traits.     

基于PVDF薄膜传感器的猪肝动态压缩力学性能测试

瞬态冲击载荷作用下肝脏的力学响应是损伤生物力学的重要研究内容。本文提出了一种可用于软组织动态压缩力学特性测试的改进SHPB(分离式霍普金森压杆,Split Hopkinson Pressure Bar)方法。该方法采用PVDF(聚偏氟乙烯,Polyvinylidene Fluor)压电薄膜传感器测量实验过程中试件两端面的受力,以此来计算试件的应力,从而无需测量透射杆上的微弱透射信号。猪肝试样前后端面的PVDF压电信号对比表明,加载过程中试样达到了动态应力平衡状态。试样动态压缩中的惯性效应主要在加载的初始阶段对透射应力信号造成较大影响,在大变形阶段惯性效应引起的轴向应力较小。利用此方法对猪肝组织进行三种高应变率(1800s^-1,2500s^-1,3500s^-1)的动态压缩实验,并采用基于真实应变的惯性效应公式对实验数据进行修正计算。结果表明:猪肝组织在准静态与高应变率时的应力应变曲线都呈现出凹向上的非线性特征,即曲线初始阶段应力增长较缓慢,当应变达到15%后应力值则迅速增大;猪肝组织也具有明显的应变率效应,即随着应变率的增加,应力应变曲线的整体应力值也随之增大。最后,采用黏超弹性本构模型描述了猪肝组织的动态应力应变曲线。     

The effect of floating-potential conductors on the electric field near overhead transmission lines

The use of helicopters as platforms equipped with infrared and UV detection, digital cameras and other inspection equipment is an effective method of increasing the efficiency and effectiveness of transmission line inspection. However, as a 'floating-potential conductor' near to a high-voltage transmission line, a helicopter causes distortion of the local electric field, with regions of high electric field near the helicopter's surface where the curvature is high. In this paper, these fields are investigated both by calculation and experimentally, using a simple metal sphere, and then a model of a helicopter, placed near to a short length of energized transmission line conductor.     

Synthesis and characterization of pyridyl anion exchange resin for 99Tc removal

Journal of Radioanalytical and Nuclear Chemistry - A new pyridyl anion exchange resin (PS-N) was synthesized by chloroacetylation and quaternization on the polystyrene-divinylbenzene microspheres...     

铁（Ⅲ）与2—[（邻羟苄叉）胺基]酚和吡啶混配配合物的合成、性质和结构

合成了铁（Ⅲ）与2－[(邻羟苄叉）胺基]酚和吡啶混配配合物，通过四园衍射测定了配合物的结构，晶体属单斜晶系，空间群为C2／c，晶胞参数：α=10.109(4)°/A，b=23.403(7)°/A,c=18.417(3)°/A,β=102.20(2)°;V=4258.8°/A^3,Z=4,Dc=1.41g/cm^3,μ=7.4cm^-1(Mo Kα），F(000)=1872.用DTA和TG技术研究了配合物的热分解过程。     

发现于泰顺的5种浙江新记录植物

报道了近来发现于温州市泰顺县的5种浙江分布新记录植物,分别是细花虾脊兰(Calanthe mannii Hook.f.)(兰科Orchidaceae)、钮子瓜(Zehneria bodinieri(H.Lév.)W.J.de WildeDuyfjes)(葫芦科Cucurbitaceae)、大齿报春苣苔(Primulina juliae(Hance)Mich.M9llerA.Weber)(苦苣苔科Gesneriaceae)、大果俞藤(Yua austro-orientalis(Metcalf)C.L.Li)(葡萄科Vitaceae)和圆叶母草(Lindernia rotundifolia(L.)Alston)(玄参科Scrophulariaceae).凭证标本保存于浙江农林大学植物标本馆(ZJFC).