O(1D)和CD4反应的准经典轨线

在新的全域势能面上, 用准经典轨线方法细致地研究了O(¹D)+CD₄多通道化学反应的动力学．这个势能面是用交换不变多项式方法基于MRC+Q/aug-cc-pVTZ从头算点拟合得到的．通过计算得到了产物OD+CD₃、D+CD₂OD/CD₃O和D₂+DCOD/D₂CO的分支比、平动能分布以及角度分布,结果显示理论与实验吻合得较好, 从而说明了这个反应的同位素取代效应很小． 研究表明,O(¹D)+CD₄反应是经过陷入的抽取机理发生的： 最初主要通过D原子的抽取,并不是之前人们认为的直接C-D键的插入形成CD3OD中间物后再进而解离成各个产物通道．     

Wave-packet continuum discretization for quantum scattering

A general approach to a solution of few- and many-body scattering problems based on a continuum-discretization procedure is described in detail. The complete discretization of continuous spectrum is realized using stationary wave packets which are the normalized states constructed from exact non-normalized continuum states. Projecting the wave functions and all scattering operators like t$t$-matrix, resolvent, etc. on such a wave-packet basis results in a formulation of quantum scattering problem entirely in terms of discrete elements and linear equations with regular matrices. It is demonstrated that there is a close relation between the above stationary wave packets and pseudostates which are employed often to approximate the scattering states with a finite L₂$L_2$ basis. Such a fully discrete treatment of complicated few- and many-body scattering problems leads to significant simplification of their practical solution. Also we get finite-dimensional approximations for complicated operators like effective interactions between composite particles constructed via the Feshbach-type projection formalism. As illustrations to this general approach we consider several important particular problems including multichannel scattering and scattering in the three-nucleon system within the Faddeev framework.     

Molybdenum Carbide‐Embedded Multichannel Hollow Carbon Nanofibers as Bifunctional Catalysts for Water Splitting

With the environmental pollution and non‐renewable fossil fuels, it is imperative to develop eco‐friendly, renewable, and highly efficient electrocatalysts for sustainable energy. Herein, a simple electrospinning process used to synthesis Mo₂C‐embedded multichannel hollow carbon nanofibers (Mo₂C‐MCNFs) and followed by the pyrolysis process. As prepared lotus root‐like nanoarchitecture could offer rich porosity and facilitate the electrolyte infiltration, the Mo₂C‐MCNFs delivered favourable catalytic activity for HER and OER. The resultant catalysts exhibit low overpotentials of 114 mV and 320 mV at a current density of 10 mA cm^?2 for HER and OER, respectively. Furthermore, using the Mo₂C‐MCNFs catalysts as a bifunctional electrode toward overall water splitting, which only needs a small cell voltage of 1.68 V to afford a current density of 10 mA cm^?2 in the home‐made alkaline electrolyzer. This interesting work presents a simple and effective strategy to further fabricating tunable nanostructures for energy‐related applications.     

Fluorescent azophenol-quinazoline dyad as multichannel reversible pH indicator in aqueous media: an innovative concept on diazo based dyads

A novel azophenol-quinazoline dyad 1 has been designed, synthesized and demonstrated as an efficient reversible multichannel pH indicator through distinct signalling in aqueous media. Owing to the competence between highly fluorescent quinazoline moiety and a well known fluorescence quencher diazo group, dyad 1 is moderately fluorescent in nature. Under acidic conditions 1 displays diverse fluorogenic changes (blue emission at pH 4.25; green at pH 1.80) while under basic condition (pH 11.80) chromogenic changes were observed.     

The physical meaning of scattering matrix singularities in coupled-channel formalisms⋆

The physical meaning of bare and dressed scattering matrix singularities has been investigated. Special attention has been attributed to the role of the well-known invariance of the scattering matrix with respect to the field transformation of the effective Lagrangian. Examples of evaluating bare and dressed quantities in various models are given.     

Multichannel sampling theorem for bandpass signals in the linear canonical transform domain

The linear canonical transform (LCT) describes the effect of first-order quadratic phase optical system on a wave field. The classical multichannel sampling theorem for common bandlimited signals has been extended differently to bandlimited signals associated with LCT. However, a practical issue associated with the reconstruction of the original bandpass signal from multichannel samples in LCT domain still remains unresolved. The purpose of this paper is to introduce a practical multichannel sampling theorem for bandpass signals in LCT domain. The sampling expansion which is constructed by the ordinary convolution in the time domain can reduce the effect of spectral leakage and is easy to implement. The classical multichannel sampling theorem and the well-known sampling theorems for the LCT are shown to be special cases of it. Some potential applications of the multichannel sampling are also presented to show the advantage of the theory.     

A LUT-based scheme for LNA linearization in direct RF sampling receivers

Direct RF sampling receiver – a fully digital receiver architecture – undoubtedly becomes a favored choice for HF/VHF as this approach inherently bypasses the legacy nonlinearities caused by analog components. In DRF-RF and wideband multichannel in general, LNA is still an indispensable component to ensure the receiver’s sensitivity. However, with the presence of multiple channels, the total RF power often surpasses the linear threshold that LNA and the amplified signal become severely distorted. This paper proposed a method for mitigating the LNA distortion using the look-up table (LUT) approach. Specifically, our receiver is designed with two modes of operation. In training mode, a built-in signal circuit generates a training signal for extracting the LNA characteristic and eventually reconstructs the inverse LNA nonlinear model in the form of a LUT memory. During the receiving mode, a linearization circuit reverses the distortion impact by matching the RF power level with the inverse nonlinear model pre-stored in the LUT. The effectiveness of the proposed distortion compensation method first is evaluated by a MATLAB simulation with a multi-channel DRF-RF model. The simulation results show that the proposed approach significantly improved the SNDR for the channel of interest. Furthermore, the model has been practically verified, where the actual distorted signals are sampled from a commercial LNA (ZFL-500LN+) by a customized FPGA board. Results from measurements show an improvement of $\sim$7 dB for SNDR and 27% for EVM in a strong distortion scenario of QPSK modulation signal.     

用于KT-5C托卡马克等离子体电子密度测量的多道HCN激光干涉仪

等离子体的电子密度是聚变等离子体研究中的重要参数。一般采用探测电磁波通过等离子体后产生的相移来求等离子体的电子密度,等离子体引起的相移△(?)与探测弦线上的线积分电子密度n_e有如下的关系:     

Wavelets for multichannel signals

In this paper, we introduce and investigate multichannel wavelets, which are wavelets for vector fields, based on the concept of full rank subdivision operators. We prove that, like in the scalar and multiwavelet case, the existence of a scaling function with orthogonal integer translates guarantees the existence of a wavelet function, also with orthonormal integer translates. In this context, however, scaling functions as well as wavelets turn out to be matrix-valued functions.     

Fused silica capillary tube isotachophoresis using a multichannel photodiode array detector

Isotachophoresis carried out in a 0.25 mm i.d. fused-silica capillary tube yielded high resolution, compared with that in a fluorinated ethylene-propylene polymer tube. The use of an ultraviolet-visible multichannel spectrophotometer with photodiode array as detector together with a cross flow cell (volume 0.01 μl) was investigated. The system was successfully applied to the analysis of cationic dyes such as neutral red, bismarck brown, and basic fuchsine.