A general method for large-scale fabrication of Cu nanoislands/dragonfly wing SERS flexible substrates

Noble metal nanorough surfaces that support strong surface-enhanced Raman scattering(SERS) is widely applied in the practical detection of organic molecules. A low-cost, large-area, and environment-friendly SERS-active substrate was acquired by sputtering inexpensive copper(Cu) on natural dragonfly wing(DW) with an easily controlled way of magnetron sputtering. By controlling the sputtering time of the fabrication of Cu on the DW, the performance of the SERS substrates was greatly improved. The SERS-active substrates, obtained at the optimal sputtering time(50 min),showed a low detection limit(10~(-6)M) to 4-aminothiophenol(4-ATP), a high average enhancement factor(EF, 1.98 × 10~4),excellent signal uniformity, and good reproducibility. In addition, the results of the 3D finite-difference time-domain(3 DFDTD) simulation illustrated that the SERS-active substrates provided high-density "hot spots", leading to a large SERS enhancement.     

Surface-enhanced fluorescence and application study based on Ag-wheat leaves

Wheat leaves with natural microstructures as substrates were covered by the silver nanoislands by magnetron to prepare a low-cost, environment-friendly and mass production surface-enhanced fluorescence (SEF) substrate (Ag-WL substrate). The best SEF substrate was selected by repeatly certifying the fluorescence intensity of 10^-5 M Rhodamine B (RB) and 10^-5 M Rhodamine 6G (R6G) aqueous solutions. The abundant semi-spherical protrusions and flake-like structures on the surface of the Ag-WL substrate produce high-density hot spots, which provides a new and simple idea for the preparation of biomimetic materials. The results of 3D finite-different time-domain (FDTD) simulation show that the nanoisland gap of semi-spherical protrusions and flake-like structures has produced rich hotspots. By adjusting the time of magnetron sputtering, the enhancement factor (EF) was as high as 839 times, relative standard deviation (RSD) reached as low as 10.7%, and the substrate was very stable and repeatable, which shows that Ag-WL substrate is trustworthy. Moreover, semi-spherical protrusions provide stronger surface-enhanced Raman scattering (SERS) effects compared to flake-like structure. What is more surprising is that the detection limit of the substrate for toxic substance crystal violet (CV) is as low as 10^-10 M.     

光学薄膜的相位变化与特点

从薄膜的导纳入手，分析了多层薄膜的相位特点和波长与相位的变化关系。计算了高反薄膜的相位变化，分析了光学薄膜的相位对光学器件的影响。     

A novel natural surface-enhanced fluorescence system based on reed leaf as substrate for crystal violet trace detection

The preparation of surface-enhanced fluorescence (SEF) substrates is often influenced by experimental strategies and factors such as the morphology and size of the nanostructures. In this study, using the natural reed leaves (RLs) without any special pretreatment as the substrate, metal silver is modified by magnetron sputtering technology to prepare a stable and efficient SEF system. The abundant “hedgehog-like”protrusions on the RL substrate surface can generate high-density “hot spots”, thus enhancement factor (EF) is enhanced up to 3345 times. The stability and reproducibility are verified in many measurements. The contribution of the intervention of silver nanostructure to the radiation attenuation process of fluorescent molecules is analyzed with the aid of Jablonski diagrams. Three-dimensional (3D) finite difference time domain (FDTD) simulates the spatial electric field and “hot spots”distribution of the substrate. The “hedgehog-like”protrusion structure generates multiple “hot spots”, which produce an excellent local surface plasmon resonance (LSPR) effect and provide higher fluorescence signal. Finally, RL/Ag-35 substrate is used to detect crystal violet (CV), and the detection limit is as low as 10^-13 M. This “hedgehog-like”SEF substrate provides a new strategy for the trace detection of CV, which has a good practical application value.     

飞秒激光器的相位薄膜

论述了飞秒激光器的相位补偿特点，讨论了采用位薄膜作为补偿晶体的色散和相位自调制的飞秒激光器，并对相位薄膜进行了理论设计。     

高灵敏光纤SERS基底的性能研究

由于光纤长度可控以及其独特的光学性能使得光纤SERS基底的检测灵活简单，在本研究中，采用油水分离的实验方法在光纤端面上修饰了银纳米颗粒，证明了该方法可以制备光纤SERS基底并有效增强拉曼信号。我们将结晶紫溶液作为分析物对制备的SERS光纤基底进行了表征，并对光纤SERS基底的均匀性、灵敏度和稳定性三个方面进行了研究。在实际应用中，使用光纤基底对罗丹明6G和农药中间体合成中广泛使用的4-氨基苯硫酚进行了检测。这些实验结果证明了自组装法为光纤SERS基底的制备提供了可行思路。     

纳米光镊技术发展与应用的研究

阐述了纳米光镊技术的特点，它将操作和探测精度从微米提高到纳米。归纳和总结了纳米光镊技术最新方面的研究进展，叙述了一些先进组合技术在改进光镊装置构造、操作精度以及校准方面的应用，并在此基础上提出了一些构想和建议。     

对一道典型力学问题的思考

分析了用悬线将一重球悬挂于天花板下,然后拉重球下方的另一悬线,此后两根悬线谁先断裂这一典型力学问题.结果表明,当拉动悬线的速度v小于某一临界速度Vc时,球上方悬线先断裂;当v>Vc时,则情况较为复杂,具体是上方悬线断裂还是下方悬线断裂取决于悬线能承受的极限张力Fm;当v>>Vc时,选取具有合适的Fm值的悬线,可使得球下方的悬线先断裂.     

硅,锗片的激光损伤及加固研究

利用ＹＡＧ脉冲激光在二种脉宽下（１０ｎｓ、２５０μｓ），对Ｓｉ、Ｇｅ片进行了损伤研究，分别给出了表面损伤机制，并利用镀金风石膜、介质膜和激光预辐照进行加固，讨论了加固效果。     

An effective surface-enhanced Raman scattering template based on gold nanoparticle/silicon nanowire arrays

A large-scale Si nanowire array （SiNWA） is fabricated with gold （Au） nanoparticles by simple metal-assisted chemical etching and metal reduction processes. The three-dimensional nanostructured Au/SiNWA is evaluated as an active substrate for surface-enhanced Raman scattering （SERS）. The results show that the detection limit for rhodamine 6G is as low as 10-7 M, and the Raman enhancement factor is as large as 105 with a relative standard deviation of less than 25%. After the calibration of the Raman peak intensifies of rhodamine 6G and thiram, organic molecules could be quantitatively detected. These results indicate that Au/SiNWA is a promising SERS-active substrate for the detection of biomolecules present in low concentrations. Our findings are an important advance in SERS substrates to allow fast and quantitative detection of trace organic contaminants.