全文获取类型
收费全文 | 14047篇 |
免费 | 4017篇 |
国内免费 | 1542篇 |
专业分类
化学 | 5018篇 |
晶体学 | 119篇 |
力学 | 212篇 |
综合类 | 135篇 |
数学 | 1711篇 |
物理学 | 12411篇 |
出版年
2024年 | 36篇 |
2023年 | 231篇 |
2022年 | 445篇 |
2021年 | 599篇 |
2020年 | 598篇 |
2019年 | 527篇 |
2018年 | 495篇 |
2017年 | 558篇 |
2016年 | 720篇 |
2015年 | 635篇 |
2014年 | 954篇 |
2013年 | 1196篇 |
2012年 | 947篇 |
2011年 | 1094篇 |
2010年 | 857篇 |
2009年 | 909篇 |
2008年 | 1093篇 |
2007年 | 1024篇 |
2006年 | 955篇 |
2005年 | 858篇 |
2004年 | 734篇 |
2003年 | 656篇 |
2002年 | 597篇 |
2001年 | 452篇 |
2000年 | 467篇 |
1999年 | 333篇 |
1998年 | 330篇 |
1997年 | 232篇 |
1996年 | 171篇 |
1995年 | 163篇 |
1994年 | 104篇 |
1993年 | 89篇 |
1992年 | 85篇 |
1991年 | 65篇 |
1990年 | 68篇 |
1989年 | 69篇 |
1988年 | 35篇 |
1987年 | 30篇 |
1986年 | 32篇 |
1985年 | 28篇 |
1984年 | 32篇 |
1983年 | 14篇 |
1982年 | 14篇 |
1981年 | 20篇 |
1980年 | 9篇 |
1979年 | 8篇 |
1978年 | 12篇 |
1977年 | 5篇 |
1976年 | 6篇 |
1972年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 265 毫秒
1.
高端芯片制造所需要的极紫外光刻技术位于我国当前面临35项"卡脖子"关键核心技术之首.高转换效率的极紫外光源是极紫外光刻系统的重要组成部分.本文通过采用双激光脉冲打靶技术实现较强的6.7 nm极紫外光输出.首先,理论计算Gd18+—Gd27+离子最外层4d壳层的4p-4d和4d-4f能级之间跃迁、以及Gd14+—Gd17+离子最外层4f壳层的4d-4f能级之间跃迁对波长为6.7 nm附近极紫外光的贡献.其后开展实验研究,结果表明,随着双脉冲之间延时的逐渐增加,波长为6.7 nm附近的极紫外光辐射强度呈现先减弱、后增加、之后再减弱的变化趋势,在双脉冲延时为100 ns处产生的极紫外光辐射最强.并且,在延时为100 ns处产生的光谱效率最高,相比于单脉冲激光产生的光谱效率提升了33%.此外,发现双激光脉冲打靶技术可以有效地减弱等离子体的自吸收效应,获得的6.7 nm附近极紫外光谱宽度均小于单激光脉冲打靶的情形,且在脉冲延时为30 ns时刻所产生的光谱宽度最窄,约为单独主脉冲产生极紫外光谱宽度的1/3.同时... 相似文献
2.
3.
Shi-Jie Pan 《中国物理 B》2022,31(6):60304-060304
Neighborhood preserving embedding (NPE) is an important linear dimensionality reduction technique that aims at preserving the local manifold structure. NPE contains three steps, i.e., finding the nearest neighbors of each data point, constructing the weight matrix, and obtaining the transformation matrix. Liang et al. proposed a variational quantum algorithm (VQA) for NPE [Phys. Rev. A 101 032323 (2020)]. The algorithm consists of three quantum sub-algorithms, corresponding to the three steps of NPE, and was expected to have an exponential speedup on the dimensionality n. However, the algorithm has two disadvantages: (i) It is not known how to efficiently obtain the input of the third sub-algorithm from the output of the second one. (ii) Its complexity cannot be rigorously analyzed because the third sub-algorithm in it is a VQA. In this paper, we propose a complete quantum algorithm for NPE, in which we redesign the three sub-algorithms and give a rigorous complexity analysis. It is shown that our algorithm can achieve a polynomial speedup on the number of data points m and an exponential speedup on the dimensionality n under certain conditions over the classical NPE algorithm, and achieve a significant speedup compared to Liang et al.'s algorithm even without considering the complexity of the VQA. 相似文献
4.
从量子力学诞生日起,它的经典对应(或类比)一直是物理学家关心的话题.本文以介观电路量子化的框架中,带有互感的两个介观电容-电感(LC)电路为例,首次讨论了量子纠缠的经典类比(或对应)问题.先用有序算符内的积分理论证明其互感是产生量子纠缠的源头;再推导出求解特征频率的公式,就发现它与一个经典系统的小振动频率的表达式有相似之处,该经典系统组成如下:两个墙壁各连一个相同的弹簧,两个弹簧之间接着一个滑动小车可以在光滑的桌面上运动,小车挂有一根单摆.用分析力学求此系统的小振动频率,发现与上述介观电路的特征频率形式类似,单摆的摆动会造成小车来回振动,摆、小车和弹簧的互相牵制效应反映了小车和摆的"纠缠". 相似文献
5.
Johannes C. B. Dietschreit Annika Wagner T. Anh Le Philipp Klein Prof. Dr. Hermann Schindelin Prof. Dr. Till Opatz Prof. Dr. Bernd Engels Prof. Dr. Ute A. Hellmich Prof. Dr. Christian Ochsenfeld 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(31):12769-12773
The absence of fluorine from most biomolecules renders it an excellent probe for NMR spectroscopy to monitor inhibitor–protein interactions. However, predicting the binding mode of a fluorinated ligand from a chemical shift (or vice versa) has been challenging due to the high electron density of the fluorine atom. Nonetheless, reliable 19F chemical-shift predictions to deduce ligand-binding modes hold great potential for in silico drug design. Herein, we present a systematic QM/MM study to predict the 19F NMR chemical shifts of a covalently bound fluorinated inhibitor to the essential oxidoreductase tryparedoxin (Tpx) from African trypanosomes, the causative agent of African sleeping sickness. We include many protein–inhibitor conformations as well as monomeric and dimeric inhibitor–protein complexes, thus rendering it the largest computational study on chemical shifts of 19F nuclei in a biological context to date. Our predicted shifts agree well with those obtained experimentally and pave the way for future work in this area. 相似文献
6.
Approximately every 100 years, as witnessed in the last two centuries, we are facing an influenza pandemic, necessitating the need to combat a novel virus strain. As a result of the new coronavirus (severe acute respiratory syndrome coronavirus type 2 [SARS-CoV-2] outbreak in January 2020, many clinical studies are being carried out with the aim of combating or eradicating the disease altogether. However, so far, developing coronavirus disease 2019 (COVID-19) detection kits or vaccines has remained elusive. In this regard, the development of antiviral nanomaterials by surface engineering with enhanced specificity might prove valuable to combat this novel virus. Quantum dots (QDs) are multifaceted agents with the ability to fight against/inhibit the activity of COVID-19 virus. This article exclusively discusses the potential role of QDs as biosensors and antiviral agents for attenuation of viral infection. 相似文献
7.
8.
Naomichi Hatano 《Molecular physics》2019,117(15-16):2121-2127
The Lindblad equation for a two-level system under an electric field is analyzed by mapping to a linear equation with a non-Hermitian matrix. Exceptional points of the matrix are found to be extensive; the second-order ones are located on lines in a two-dimensional parameter space, while the third-order one is at a point. 相似文献
9.
Luis Gutiérrez-Arzaluz David Ignacio Ramírez-Palma Lillian G. Ramírez-Palma Prof. Dr. José Enrique Barquera-Lozada Prof. Dr. Jorge Peon Prof. Dr. Fernando Cortés-Guzmán 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(3):775-784
Copper(I) complexes (CICs) are of great interest due to their applications as redox mediators and molecular switches. CICs present drastic geometrical change in their excited states, which interferes with their luminescence properties. The photophysical process has been extensively studied by several time-resolved methods to gain an understanding of the dynamics and mechanism of the torsion, which has been explained in terms of a Jahn–Teller effect. Here, we propose an alternative explanation for the photoinduced structural change of CICs, based on electron density redistribution. After photoexcitation of a CIC (S0→S1), a metal-to-ligand charge transfer stabilizes the ligand and destabilizes the metal. A subsequent electron transfer, through an intersystem crossing process, followed by an internal conversion (S1→T2→T1), intensifies the energetic differences between the metal and ligand within the complex. The energy profile of each state is the result of the balance between metal and ligand energy changes. The loss of electrons originates an increase in the attractive potential energy within the copper basin, which is not compensated by the associated reduction of the repulsive atomic potential. To counterbalance the atomic destabilization, the valence shell of the copper center is polarized (defined by ∇2ρ(r) and ∇2Vne(r)) during the deactivation path. This polarization increases the magnitude of the intra-atomic nuclear–electron interactions within the copper atom and provokes the flattening of the structure to obtain the geometry with the maximum interaction between the charge depletions of the metal and the charge concentrations of the ligand. 相似文献
10.
Dr. Xiaoyan Sun Prof. Dr. Shaodong Zhou Dr. Lei Yue Dr. Maria Schlangen Prof. Dr. Helmut Schwarz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(14):3550-3559
Thermal gas-phase reactions of the ruthenium-oxide clusters [RuOx]+ (x=1–3) with methane and dihydrogen have been explored by using FT-ICR mass spectrometry complemented by high-level quantum chemical calculations. For methane activation, as compared to the previously studied [RuO]+/CH4 couple, the higher oxidized Ru systems give rise to completely different product distributions. [RuO2]+ brings about the generations of [Ru,O,C,H2]+/H2O, [Ru,O,C]+/H2/H2O, and [Ru,O,H2]+/CH2O, whereas [RuO3]+ exhibits a higher selectivity and efficiency in producing formaldehyde and syngas (CO+H2). Regarding the reactions with H2, as compared to CH4, both [RuO]+ and [RuO2]+ react similarly inefficiently with oxygen-atom transfer being the main reaction channel; in contrast, [RuO3]+ is inert toward dihydrogen. Theoretical analysis reveals that the reduction of the metal center drives the overall oxidation of methane, whereas the back-bonding orbital interactions between the cluster ions and dihydrogen control the H−H bond activation. Furthermore, the reactivity patterns of [RuOx]+ (x=1–3) with CH4 and H2 have been compared with the previously reported results of Group 8 analogues [OsOx]+/CH4/H2 (x=1–3) and the [FeO]+/H2 system. The electronic origins for their distinctly different reaction behaviors have been addressed. 相似文献