氧弹燃烧处理试样-离子色谱法测定聚苯硫醚中总氯含量

采用氧弹燃烧法对样品进行燃烧,然后用超纯水作为吸收液吸收释出的氯或氯化物,并提出了离子色谱法分离测定聚苯硫醚中总氯含量的方法。以Metrosep A Supp 5-250型分析柱为离子交换柱,以3.2 mmol.L-1碳酸-钠1.0 mmol.L-1碳酸氢钠溶液为淋洗液等度洗脱。方法用于矿物油标准样品(AOD 1.11)和聚乙烯标准样品(ERM-EC 681K)标准样品的分析,测定值与标准值相一致。     

Li4Ti5O12/(Cu+C)复合材料的制备及电化学性能

以Li₄Ti₅O₁₂,Cu(CH₃COO)₂·H₂O和C₆H₁₂O₆为前驱体,化学沉积与热分解结合合成锂离子电池负极材料Li₄Ti₅O₁₂/(Cu+C)。采用X-射线衍射(XRD)、扫描电子显微镜(SEM)、恒流充放电、循环伏安和电化学阻抗方法表征样品的结构、形貌和电化学性能。结果表明,Li₄Ti₅O₁₂表面包覆的Cu与C提高了Li₄Ti₅O₁₂电极材料的导电率,其循环性能和倍率性能得到有效地改善。在0.5C、1C和3C倍率下,经过50次充放电循环,放电比容量分别为168.2、160、140.6 mAh·g^-1,其容量保持率分别为88.7%、84.4%、71.2%。电化学阻抗测试表明,表面包覆的Cu与C使其电荷转移阻抗大幅度减少。     

基于聚N-甲基苯胺/Ni2+修饰玻碳电极的无酶葡萄糖传感器研究

在0.50 mol·L-1 HClO4溶液中,采用循环伏安法在玻碳(GC)电极上修饰聚N-甲基苯胺(PNMA)薄膜,然后将电极浸泡在1.0 mol·L-1 Ni(NO3)2溶液中,使Ni2+渗入PNMA薄膜中得到PNMA/Ni2+/GC电极,研究了该修饰电极的伏安特性及对葡萄糖的电催化氧化行为.实验结果表明,在0.10...     

壳聚糖-O-聚(寡聚乙二醇甲基丙烯酸酯)的原子转移自由基聚合与表征

基于原子转移自由基聚合(ATRP)和十二烷基硫酸钠(SDS)-壳聚糖(CS)复合物(SCC)的位置选择性改性策略,合成了结构可控的壳聚糖-O-聚(寡聚乙二醇甲基丙烯酸甲酯)(CS-POEGMA)刷状衍生物.通过在SCC的羟基上引入溴代异丁酸后脱除SDS得到大分子引发剂O-溴化壳聚糖(CS-Br).用红外光谱(FT-IR...     

激发态丰质子核的双质子发射

将有效液滴模型和推广的液滴模型推广至激发态丰质子核的双质子发射半衰期研究,发现这两个模型都能较好地再现双质子发射半衰期的实验数据.基于这两个模型预言了一些核的激发态的双质子发射的半衰期,为将来的实验提供参考,并将上述半衰期与统一裂变模型给出的半衰期进行了比较和分析.此外,以⁹⁴Ag的21~+激发态的双质子发射为例,讨论了衰变能和衰变过程中带走的轨道角动量对其半衰期的影响,发现半衰期对它们的依赖很敏感,半衰期对衰变能的强烈依赖表明了精确测量核质量和激发能的重要性和必要性.     

Quantum steganography with a large payload based on dense coding and entanglement swapping of Greenberger-Horne-Zeilinger states

A quantum steganography protocol with a large payload is proposed based on the dense coding and the entanglement swapping of the Greenberger-Horne-Zeilinger (GHZ) states. Its super quantum channel is formed by building up a hidden channel within the original quantum secure direct communication (QSDC) scheme. Based on the original QSDC, secret messages are transmitted by integrating the dense coding and the entanglement swapping of the GHZ states. The capacity of the super quantum channel achieves six bits per round covert communication, much higher than the previous quantum steganography protocols. Its imperceptibility is good, since the information and the secret messages can be regarded to be random or pseudo-random. Moreover, its security is proved to be reliable.     

Processes of DNA condensation induced by multivalent cations： Approximate annealing experiments and molecular dynamics simulations

The condensation of DNA induced by spermine is studied by atomic force microscopy （AFM） and molecular dynamics （MD） simulation in this paper. In our experiments, an equivalent amount of multivalent cations is added to the DNA solutions in different numbers of steps, and we find that the process of DNA condensation strongly depends on the speed of adding cations. That is, the slower the spermine cations are added, the slower the DNA aggregates. The MD and steered molecular dynamics （SMD） simulation results agree well with the experimental results, and the simulation data also show that the more steps of adding multivalent cations there are, the more compact the condensed DNA structure will be. This investigation can help us to control DNA condensation and understand the complicated structures of DNA--cation complexes.     

偶偶No同位素转动性质研究(英文)

通过总Routhian 面计算方法研究了Z = 102 号元素已实验合成的偶偶248-264No同位素的转动性质。计算的基态形变β2,β4 与前人的计算相符。252,245No 两核基态带的转动惯量特征能得到基本再现。偶偶248-264No同位素转动惯量系统上弯的现象可归因于带交叉。研究还表明,推转时质子与中子顺排有强烈竞争,在较轻的No同位素中j_15/2 中子拆对顺排较为优先,而在较重的No 核中i_13/2 质子顺排更加优先。The rotational properties of the synthesized even-even 248-264No isotopes have been investigated by means of total Routhian surface calculations. The calculated ground-state properties (e.g. β2; β4) are in agreement with previous calculations. The behaviors of moment of inertia of 252,254No are well reproduced by our calculations. The systematic upbending in moment of inertia is attributed to band crossing. It is found that the j_15/2 neutron rotation-alignment is preferred for the lighter No isotopes, but the i_13/2 proton alignment is favored in the heavier ones.     

扇形孔气膜冷却应用的综合特性

扇形孔气膜冷却是为避免圆孔气膜冷却吹离而产生的,然而这两种孔在实际叶栅运用中的特性往往受到叶栅流动以及各种参数的影响而显得极为复杂。本文首先探讨平板扇形孔在不同密度比、吹风比下的特性,得到扇形孔的流动和传热特性以及各参数对其的影响。然后结合扇形孔在叶栅上的应用,研究了压力面和吸力面不同的流动特性对于扇形孔应用的影响,以及在叶栅冷却中冷气参数对扇形孔的综合影响。