Target voltage behaviour of a vanadium-oxide thin film during reactive magnetron sputtering

This paper simulates reactive magnetron-sputtering in constant current mode in a Vanadium-O 2 /Ar system equipped with a DC power supply by adopting both kinetics model and Berg’s model.The target voltage during the reactive sputtering has been investigated as a function of reactive gas flow.Both experiments and simulations demonstrate a hysteresis curve with respect to the oxygen supply.The time-dependent variation of the target mode is studied by measuring the target voltage for various reactive oxygen gas flows and pre-sputtering times.The presputtering time increases with the increased initial target voltage.Furthermore,a corresponding time-dependent model simulating target voltage changes is also proposed.Based on these simulations,we find some relationships between the discharge voltage behaviour and the properties of the formed oxide.In this way,a better understanding of the target voltage changes during reactive sputtering can be achieved.We conclude that the presented theoretical models for parameter-dependent case and time-dependent case are in qualitative agreement with the experimental results and can be used to comprehend the target voltage behaviour in the deposition of vanadium oxide thin films.     

刚性直杆倾倒过程的动态分析

考察了刚性直杆由静止开始倾倒到接触地面前这一短暂时间内的力学行为.建立了刚性直杆定轴转动和平面运动的动力学方程.应用Mathematica软件揭示了系统在倾倒过程中的角位移、角速度、角加速度、质心加速度以及摩擦力等随时间变化的规律.     

激光多普勒差动检波装置的信号研究

研究了差动多普勒技术和锁相放大器的频率跟踪技术, 设计了一种精度高、动态范围大的激光多普勒差动检波系统.此系统结构紧凑, 安装调节方便, 可以充分利用激光光能.而且, 它把两束高斯光束的束腰聚焦在被测物体上, 获得了最小光斑和平面波的叠加, 提高了分辨力、信噪比和信号强度.采用频率自动跟踪技术来解决信号丢失问题, 抑制了各种噪声和干扰.模拟实验证明, 振幅测量精度为1％, 频率为0.6％; 分辨力为50 nm, 技术指标是令人满意的.     

强耦合激子-声子系统中的三阶非线性光学系数的理论计算

应用Dyson-Maleev变换,对强耦合激子—声子系统中非线性光学性质进行了理论研究.结果表明,当信号光场频率与激子频率的失谐量等于光学声子的频率时,系统的非线性光学吸收和克尔（Kerr）系数显著增大,从而证明了激子-声子的强相互作用对介质的非线性光学性质的影响相当大,并且当考虑激子偏离玻色子模型时,这种影响将进一步增大.     

百赫兹气动式斯特林制冷机耦合特性研究

基于耦合特性理论和数值模拟计算对斯特林制冷机的运行参数和几何参数进行设计及优化,研制了一台总重量800g的气动式斯特林制冷机。并将声-力两部分结合起来,定量地构建了耦合相位关系图,揭示了百赫兹压缩机与膨胀机的耦合匹配机理。实验结果表明:整机运行频率100Hz,在32W输入电功下,80K可提供1W制冷量。     

基于视频分析验证两种常见模型的机械能守恒

利用Tracker软件的自动追踪功能,分别对弹簧振子系统和定滑轮系统进行分析,得到两个系统中物体运动规律图象及其数据。在考虑弹簧与滑轮质量的情况下,验证系统机械能守恒。     

集流器偏心对多翼离心风机性能及噪声的影响研究

风机进口处的流动状态对其性能具有直接影响。本文对某多翼离心风机提出一种进口集流器偏心安装的方法,来控制其进口流动,使其性能获得提升、噪声降低。通过数值寻优与实验寻优的相互验证,对不同工况下集流器偏心安装前后的风机性能、噪声及内部流场展开分析,并最后得出了集流器的合理偏心位置。结果表明:当偏心角θ=120°且偏距比ε=0.016时,偏心方向对应叶道内的流动分离减弱,叶轮出口气流速度增大,同时叶轮前盘和集流器间隙间的流量泄漏也相应减小。在风机运行工况范围内,该风机的风量最大增加3.5%,全压效率最大提高3%,噪声降幅最大达1.2dB.     

D~0-~0 mixing parameter y in the factorization-assisted topological-amplitude approach

We calculate the D~0-~0 mixing parameter y in the factorization-assisted topological-amplitude(FAT)approach, considering contributions from D~0→PP, PV, and VV modes, where P(V) stands for a pseudoscalar(vector) meson. The D~0→PP and PV decay amplitudes are extracted in the FAT approach, and the D~0→VV decay amplitudes with final states in the longitudinal polarization are estimated via the parameter set for D~0→PV. It is found that the VV contribution to y, being of order of 10-4, is negligible, and that the PP and PV contributions amount only up to y_(PP+PV) =(0.21±0.07)%, a prediction more precise than those previously obtained in the literature,and much lower than the experimental data y_(exp) =(0.61 ±0.08)%. We conclude that D~0 meson decays into other two-body and multi-particle final states are relevant to the evaluation of y, so it is difficult to understand it fully in an exclusive approach.     

双(取代水杨醛)缩卡巴肼正丁基锡配合物的合成、结构及除草活性

在微波甲醇溶剂热中,正丁基三氯化锡(n-BuSnCl₃)与双[4-二乙氨基或(3,5-二叔丁基)取代水杨醛]缩卡巴肼和缩硫代卡巴肼配体反应,合成双(取代水杨醛)缩卡巴肼和缩硫代卡巴肼丁基锡配合物,( n-BuSn) ₂CI₃(OH₂)[(2-OH,R)PhCH=NNH]₂CX[R:4-NEt₂(4-二乙氨基),X:O(A1);R:4-NEt₂,X:S(A2);R:3,5-(t-Bu)₂,X:O(A3);R:3,5-(t-Bu)₂,X:S(A4)],经元素分析、IR、¹H 和 ¹³C NMR表征,X射线衍射获得的配合物A2的晶体结构表明,化合物A2是具有六配位畸形八面体构型的双锡核配合物。 配体及其丁基锡配合物均对马齿苋、刺苋、四九菜心、苋菜和决明子靶标植物具有生长抑制作用,且配合物A1和A2具有较广谱、配合物A3和A4具有选择性生长抑制作用,可作为杂草生长抑制候选物研究。     

酸性溶液中SO2选择性还原分解钨过氧配合物——钨中微量钼的除去

用SO₂还原4:2钨过氧配合物[H₄W₄O₁₂(O₂)₂]已被作为在室温和低酸度条件下生产钨酸的一种新方法--络合均相沉淀法^[1,2].有意义的是,这一方法还能用SO₂对钨、钼过氧配合物的选择性分解,同时除去钨中的微量钼.本文研究了不同游离酸度和不同反应温度条件下选择性分解时的除钼效果,并初步给予理论上的解释.