瞳孔直径估算模型

在对已有瞳孔直径估算模型研究分析的基础上,测量了不同光环境下受试者瞳孔直径的变化,利用实测数据对现有模型进行了对比分析。利用角膜通量密度建立了亮度、视角与瞳孔直径的关系,并以Stanley-Davies模型为基础对原有计算关系式进行了修正与优化,提高了模型的计算精度。通过实验拓展了Stanley-Davies计算方法的适用视场范围,将最大适用视场拓展到40°。     

Na、Lu掺杂Mg2Si的电子结构及光学性质的第一性原理计算

采用基于密度泛函理论的第一性原理赝势平面波方法,研究了未掺杂Mg2Si以及Na、Lu掺杂Mg2Si的电子结构和光学性质.计算结果表明:Na掺杂Mg2Si后,费米能级进入价带,呈p型导电;Lu掺杂Mg2Si后,费米能级进入导带,呈n型导电.未掺杂Mg2Si对于能量低于0.5eV的光子几乎不吸收,但Na、Lu掺杂的Mg2Si对于能量低于0.5eV的光子还存在较大的吸收,即Na、Lu掺杂改善了Mg2Si对红外光子的吸收.掺杂后,可见光区的吸收系数与反射率明显减小,这说明掺杂的Mg2Si在可见光区的透过率增大.计算结果为Mg2Si 基光电器件的设计与应用提供了理论依据.     

Tracking problem under a time-varying topology

This paper studies the multi-agent tracking problem of a third-order maneuvering target under uncertain communication environments. Each tracking agent is assumed to be a third-order system and can only use its own and neighbors＇ position, velocity, and acceleration information to design its control input. In this work, the uncertain communication environments are modelled by a finite number of constant Laplacian matrices together with their corresponding scheduling functions. Sufficient conditions for the existence of a tracking strategy have been expressed in terms of the solvability of linear matrix inequalities. Finally, a numerical example is employed to demonstrate the effectiveness of the proposed tracking strategy.     

1,2-环丙烷乙酰化糖水解机理的理论研究

采用密度泛函B3LYP方法研究了1,2-环丙烷乙酰化糖在氘代氯仿溶液中的水解反应的详细机理。计算结果表明,当H2O分子从不同方向进攻1,2-环丙烷乙酰化糖分子时,会形成不同的反应途径,当H2O从糖分子的六元环平面下方进攻时,反应为一步反应,环丙烷的开环步骤为反应决速步,生成α构型产物。当H2O从糖分子的六元环平面上方进攻时,反应为两步反应,形成产物的氢迁移步骤为决速步,生成β构型产物。H2O从糖分子平面下方进攻的反应途径在热力学及动力学上都更有优势,1,2-环丙烷乙酰化糖的水解反应更有利于生成α构型产物,计算结果与实验结果一致。     

Evolution from Diffuse Ferroelectric to Relaxor Ferroelectric in Pb1-xBax（Fe1/2Nb1/2）O3 Solid Solutions

Dielectric and ferroelectric characteristics for Pb1-xBax（Fe1/2Nh/2）O3 （x = 0,0.05,0.1,0.15, and 0.2） ceramics are determined together with their structures. X-ray diffraction （XRD） analysis confirms the solid solutions with the cubic structure. The dielectric nature changes from diffuse ferroelectric to relaxor ferroelectric with increasing x, while the phase transition temperature Tc （or Tm） decreases monotonously. The diffuse ferroelectric phase transition is observed in the solid solutions with 0≤x ≤0.05. For Pbl-xBax（Fe1/2Nb1/2）O3 with 0.1≤ x≤0.2, relaxor ferroelectric behavior is determined, and the Vogel-Fulcher equation is used to describe the relaxor behavior. The 1/ε versus T plots reveal the diffusion dielectric characteristics in both diffuse and relaxor ferroelectrics.     

Synthesis of a Nine-atom Germanium Cluster K_(0.5)[K(18-crown-6)]_(1.5)Ge_9·1.5en with Unprecedented “up” and “down” Chain Arrangement of Unit [-(Ge_9-K-Ge_9)~(3-)-]

A new complex K0.5[K(18-crown-6)]1.5Ge9·1.5en(1) which contains unprecedented "up" and "down" chain arrangement of unit [-(Ge-9-K-Ge9)3-] has been prepared by the reaction of K4Ge9 with HgS in ethylenediamine(en) in the presence of 18-crown-6(1,4,7,10,13,16-hexaoxacyclooctadecane), and characterized by X-ray structure analysis. The color of the title crystals(black), which is darker than that of the reported three compounds with chains of germanium clusters, may result from the naked K+ and their interactions with the chain. And the structure differences between 1 and the reported three compounds with chains of germanium have also been discussed.     

同步辐射核共振振动能谱学(上):原理篇

核共振振动能谱学(简称核振能谱)是一种以同步辐射为实验基础的新型的振动能谱学方法。与红外、拉曼等传统的振动光谱学方法相比,核振能谱在理论上和实验上具有一系列突出的特点和优越性,从而在各学科,特别是在铁基化学和铁基生物化学的研究中有着广泛的应用。文章分为上下两篇,上篇介绍核振能谱的基本概念、基本理论、实验方法和实验条件等基础内容,并以简单的四氯化铁离子([FeCl4]-)为例,演示由原始核振能谱到振动态密度函数(PVDOS)的分析流程。在选材上,文章侧重先进性、代表性和实用性;在叙述上,考虑到非同步辐射专业研究者的阅读需要,文章突出实验科学和应用科学的内容,力求简单明了、通俗易懂。下篇将系统介绍该能谱学方法在化学与生物化学中的应用实例。     

On an entropy of ℤ + k -actions

In this paper,a definition of entropy for Z＋k（k≥2）-actions due to Friedland is studied.Unlike the traditional definition,it may take a nonzero value for actions whose generators have finite（even zero） entropy as single transformations.Some basic properties are investigated and its value for the Z＋k-actions on circles generated by expanding endomorphisms is given.Moreover,an upper bound of this entropy for the Z＋k-actions on tori generated by expanding endomorphisms is obtained via the preimage entropies,which are entropy-like invariants depending on the ＂inverse orbits＂ structure of the system.     

国科大等在二维原子晶体研究中获进展

<正>二维原子晶体作为一种新型材料备受关注。近期,《自然-物理》(Nature Physics)杂志发表了中国科学院大学物理学院研究团队在这一新兴领域的重要发现。二维原子晶体中的典型代表——石墨烯(Graphene)以其优异的载流子迁移率、力学性能等在凝聚态物理及材料科学领域引起了广泛的研究兴趣并取得了巨大的进展;而六方氮化硼(hBN)作为石墨烯的等电子体,具有一定的能隙、原子级平整的表面并且表面没有悬挂键,非常适合于作为承载石墨烯的基底,构成石墨