排序方式: 共有3条查询结果,搜索用时 0 毫秒
1
1.
Evolution from Diffuse Ferroelectric to Relaxor Ferroelectric in Pb1-xBax(Fe1/2Nb1/2)O3 Solid Solutions 下载免费PDF全文
Dielectric and ferroelectric characteristics for Pb1-xBax(Fe1/2Nh/2)O3 (x = 0,0.05,0.1,0.15, and 0.2) ceramics are determined together with their structures. X-ray diffraction (XRD) analysis confirms the solid solutions with the cubic structure. The dielectric nature changes from diffuse ferroelectric to relaxor ferroelectric with increasing x, while the phase transition temperature Tc (or Tm) decreases monotonously. The diffuse ferroelectric phase transition is observed in the solid solutions with 0≤x ≤0.05. For Pbl-xBax(Fe1/2Nb1/2)O3 with 0.1≤ x≤0.2, relaxor ferroelectric behavior is determined, and the Vogel-Fulcher equation is used to describe the relaxor behavior. The 1/ε versus T plots reveal the diffusion dielectric characteristics in both diffuse and relaxor ferroelectrics. 相似文献
2.
3.
Ferroelectric transitions in filled tungsten bronze ceramics Sr4R2Ti4Nb6O30, Sr5RTi3NbT030 (R=La, Nb, Sm & Eu) and Ba4Nd2Ti4Nb6030 are investigated with differential scanning calorimetry (DSC) and the Curie- Weiss law fitting to the dielectric constant. The magnitude of the Curie Weiss constant C - 105 suggests displacement-type ferroelectric transition in the present compounds. The large AT difference between dielectric maximum temperature Tm and Curie-Weiss temperature To) values indicate the difficult formation of ferroeleetric domains or polar nanoregions in the present compounds and also the characteristics of the first order ferroelectric transition. Three categories are suggested for the ferroelectric transition in the above tungsten bronzes. The ferroelectric transition exhibits large thermal hysteresis. According to the DSC results, gradual recovery of the endothermic peak occurs after aging at temperature below the Curie point, indicating the gradual stability of the ferroelectric phase after cooling from the high-temperature para-electric phase. The relationship between the Curie- Weiss law fitting parameters and the nature of the ferroelectric transition is modified for the filled tungsten bronzes. 相似文献
1