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991.
992.
关于两类矩阵最佳逼近问题 总被引:6,自引:0,他引:6
1.引言与引理 设Rm×n表示所有m×n阶实矩阵的集合;SRn×n是所有n阶实对称矩阵的全体;ORn×n是所有n阶实正交矩阵的全体;In是n阶单位矩阵;AT是矩阵A的转置;rankA表示矩阵 A的秩;‖·‖是矩阵的Frobenius范数.此外,对于 ,A*B表示 A与 B的 Hadamard积,其定义为 ,现考虑如下问题: 问题 Ⅰ给定 ,使得 ,求 问题Ⅱ给定 ,求 ,使得 本文运用矩阵对… 相似文献
993.
对聚苯树脂炭化产物作为锂离子电池碳电极材料的研究Ⅱ.炭化产物制备的电极材料组装的锂离子电池电化学性能 总被引:1,自引:0,他引:1
电化学性质;对聚苯树脂炭化产物作为锂离子电池碳电极材料的研究Ⅱ.炭化产物制备的电极材料组装的锂离子电池电化学性能 相似文献
994.
La0.15Sr0.85Ga0.3Fe0.7O3-δ(LSGFO) and La0.15Sr0.85Co0.3Fe0.7O3-δ(LSCFO) mixed oxygen-ion and electron conducting oxides were synthesized by using a combined EDTA and citrate complexing method, and the corresponding dense membranes were fabricated. The properties of the oxide powders and membranes were characterized with combined SEM, XRD, H2-TPR, O2-TPD techniques, mechanical strength and oxygen permeation measurement. The results showed that LSGFO had much higher thermochemical stability than LSCFO due to the higher valence stability of Ga3+. After the temperature-programmed reduction by 5% H2 in Ar from 20℃to 1020℃, the basic perovskite structure of LSGFO was successfully preserved. LSGFO also favors the oxygen vacancy formation better than LSCFO. Oxygen permeation measurement demonstrated that LSGFO had higher oxygen permeation flux than LSCFO, but they had similar activation energy for oxygen transportation, with a value of 110 and 117 kJ ?mol~(-1), respectively. The difference in oxygen permeation f 相似文献
995.
996.
Molybdenum nitrides have attracted significant attention recently due to their uniquephysical and chemical properties. Many studies have shown that Mo,N is an activecatalyst for CO hydrogenation. The fundamental understanding concerning the reactionmechanisms over Mo=N. however, is not well established. The powerful surface sciencetechniques may provide an insight into the surface structure and properties of such animportant catalytic material. In previous paper', we described the results o… 相似文献
997.
In order to further study on minor diterpenoid constituents of lsodon rubescens, wereinvestigated this species, which was collected in Taibai mountain, Shaanxi Province.TWo new diterpenoids, taibairubescensins A (l) and B (2), were isolated. In this paper,we present the structure elucidation of these two new diterpenoids.Taibairubescensin A (l ), C,.H,#O, (FABMS m/z 435[M 11 ), an amorphous powder,showed UV and iR absorption bands for the existence of hydroxyl, acetoxyl and a fivemembe… 相似文献
998.
6-Diketones are useful chelating agents with many metal ions. Chiral 6-diketones.especially chiral 3-acylcamphors as an outstanding representation, have even moreextensive applications as stationary phases in chromatograpy and as ligands of chemicalshifting reagents in NMR spectroscopy'for determining the enantiomeric excess of 'chrialcompoundsl=. Furthermore, they can be 'used as ligands in asymmetric catalysis'-'.Much work has been done for the synthesis of 3-acylcamphors due to their broad… 相似文献
999.
Pei Pei SUN* Ya Ping XIAO Bao Chuan SHI Department of Chemistry Nanjing Normal University Nanjing 《中国化学快报》2000,11(12)
Organic reactions promoted by active metals have aroused much interest in recent years. Active bismuth has been used in Barbier-type reaction of allylic halides with aldehydes1 and aldimines2 as well as Reformatzky type reaction3. Other publications referred to the cross coupling between aldehydes and α-diketones4, the substitution to benzotriazole drivatives5 and the reductive coupling reaction of nitro compounds6. These reactions generally promoted by elemental bismuth generated in situ fr… 相似文献
1000.
There are abundant supplies of mixture gases containing CH, and C,H, from natural gas,FCC (Fluidized Catalytic Cracking) dry gas, refinery gas, elc. Commonly, the amount ofC,H, is relatively lower than that of CH,. With regard to the utilization of methane,partial oxidation of methane to syngas over nickel based catalysts has received intensiveallention l'2. For mixture gases containing CH# and C,H,, their conversion to syngas isalso of significance (but has not gained adequate attentio… 相似文献