Synthesis and characterization of gallium-based perovskitetype dense membrane with oxygen semipermeability |
| |
Authors: | CONG You SHAO Zongping YANG Weishen XIONG Guoxing LIN Liwu |
| |
Institution: | 1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 2. Chinese Academy of Sciences, |
| |
Abstract: | La0.15Sr0.85Ga0.3Fe0.7O3-δ (LSGFO) and La0.15Sr0.85Co0.3Fe0.7O3-δ (LSCFO) mixed oxygenion and electron conducting oxides were synthesized by using a combined EDTA and citrate complexing method,
and the corresponding dense membranes were fabricated. The properties of the oxide powders and membranes were characterized
with combined SEM, XRD, H2-TPR, O2-TPD techniques, mechanical strength and oxygen permeation measurement. The results showed that LSGFO had much higher thermochemical
stability than LSCFO due to the higher valence stability of Ga3+. After the temperature-programmed reduction by 5% H2 in Ar from 20°C to 1020°C, the basic perovskite structure of LSGFO was successfully preserved. LSGFO also favors the oxygen
vacancy formation better than LSCFO. Oxygen permeation measurement demonstrated that LSGFO had higher oxygen permeation flux
than LSCFO, but they had similar activation energy for oxygen transportation, with a value of 110 and 117 kJ · mol-1, respectively. The difference in oxygen permeation fluxes was correlated with the difference in oxygen vacancy concentrations
for the two materials. |
| |
Keywords: | perovskite Ga2O3 oxygen separation membrane La0 15Sr0 85 Ga0 3Fe0 7O3-δ La0 15Sr0 85Co0 3Fe0 7O3-δ |
本文献已被 CNKI 万方数据 SpringerLink 等数据库收录! |
|