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人体血液红细胞31P NMR谱的研究 总被引:1,自引:0,他引:1
介绍了人体血液红细胞31P NMR谱的测量方法,介绍了样品的处理方法和测试参数的选择.发现正常人和病人血液的红细胞在21P NMR谱上存在着明显的差异,这些差异可望在临床医学上用于对某些血液病进行诊断和疗效跟踪的检测. 相似文献
84.
Subnanometer-sized copper nanoclusters were prepared by a one-pot procedure based on wet chemical reduction. The structural characteristics of the 2-mercapto-5-n-propylpyrimidine-protected nanoclusters, Cu(n) (n ≤ 8), were determined by mass spectrometry. The Cu nanoclusters displayed apparent luminescence, with dual emissions at 425 and 593 nm, with quantum yields of 3.5 and 0.9%, respectively, and high electrocatalytic activity in the electoreduction of oxygen. 相似文献
85.
ABSTRACT Aqueous glutathione-capped cadmium/tellurium quantum dots with a diameter of about 3 nm were synthesized. The fluorescence was quenched in the presence of protoporphyrin IX disodium salt, with the excitation wavelength at 320 nm. Under the optimal conditions, the quenched fluorescence intensity was linear in the range of 0.096–16 µg · mL?1 with a concentration of protoporphyrin IX disodium salt, and the detection limit (3σ) was 2.8 × 10?2 µg · mL?1. The proposed method has been applied to the determination of protoporphyrin in serum samples with satisfactory results. The interaction mechanism was investigated. 相似文献
86.
A novel glutathione-capped cadmium telluride quantum dots-based fluorescence “off–on” sensor was designed and applied for highly sensitive and selective monitoring of histidine in aqueous solution. To provide a platform for histidine detection, manganese ion was first employed as an effective quencher to decrease the fluorescence of glutathione-capped cadmium telluride quantum dots because of the binding of manganese ion to glutathione on the surface of quantum dots and the electron transfer from the photoexcited glutathione-capped cadmium telluride quantum dots to manganese ion. Due to its high binding affinity with manganese ion, histidine can make the manganese ion to be dissociated from the surface of glutathione-capped cadmium telluride quantum dots to form more stable complex with histidine in solution, and set free the luminescent glutathione-capped cadmium telluride quantum dots, thereby recovering the fluorescence of glutathione-capped cadmium telluride quantum dots. Experimental results showed that the recovered fluorescence intensity was directly proportional to the concentration of histidine in the range of 0.006 to 465.0 µg mL?1 with a correlation coefficient (R) of 0.9977, and the detection limit (3σ/K) was 1.82 ng mL?1. Relevant experiments also revealed that the fluorescence sensor gives excellent selectivity for histidine over other common amino acids. To further investigate perfect analysis performance, this sensor was utilized to determine histidine in synthetic samples with satisfactory results. 相似文献
87.
Fu Hongyuan Shi Yizhong You Jian Hao Tingting Wang Tao 《Research on Chemical Intermediates》2019,45(6):3557-3570
Research on Chemical Intermediates - To exploit novel ferrocene-based small molecules with long conjugated structures as visible and electrochemical multichannel chemosensors, four conjugated... 相似文献
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We derive the threshold pump intensity for a singly resonant intracavity optical parametric oscillator (IOPO)based on a temporal coupled field model.Particular attention is Paid to the dependence of the intracavity singly resonant OPO(SRO)threshold intensity on the signal wave output coupling.Meanwhile,a Nd:YAG laser pumped KTiOPO4(KTP)IOPO for eye-safe laser output is studied experimentally.The experiment is performed with four signal wave output reflectivities of 60%,70%,80%,and 90%,respectively.The measured values are in good agreement with the theoretical results.With an output coupler reflectivity of 80%,a peak power of 70 kW at 1572 nm has been obtained at a repetition rate of 3.5 kHz.The pulse width is 4.9 ns.Such investigation is helpful to identifying suitable operational regime of low pump intensity. 相似文献
90.
We report here a facile colorimetric sensor based on the N-acetyl-l-cysteine (NALC)-stabilized Ag nanoparticles (NALC–Ag NPs) for detection of Fe3+ ions in aqueous solution. The Ag NPs with an average diameter of 6.55 ± 1.0 nm are successfully synthesized through a simple method using sodium borohydride as reducing agent and N-acetyl-l-cysteine as protecting ligand. The synthesized silver nanoparticles show a strong surface plasmon resonance (SPR) around 400 nm and the SPR intensity decreases with the increasing of Fe3+ concentration in aqueous solution. Based on the linear relationship between SPR intensity and concentration of Fe3+ ions, the as-synthesized water-soluble silver nanoparticles can be used for the sensitive and selective detection of Fe3+ ions in water with a linear range from 80 nM to 80 μM and a detection limit of 80 nM. On the basis of the experimental results, a new detection mechanism of oxidation–reduction reaction between Ag NPs and Fe3+ ions is proposed, which is different from previously reported mechanisms. Moreover, the NALC–Ag NPs could be applied to the detection of Fe3+ ions in real environmental water samples. 相似文献