Probing the EOS and nn cross section by analyzing the collective flow at high and intermediate energy in the RVUU approach

We have studied the collective flow at high and intermediate energy in a relativistic Vlasov-Uehling-Uhlenbeck (RVUU) approach based on Walecka's QHD-I model, with the aim to probe the nuclear-matter equation of state (EOS) and the in-medium nucleon-nucleon cross section σ. At high energy (1.2 GeV/u), the out-of-plane azimuthal correlation function C(Ψ) is only sensitive to the effective mass m^* and insensitive to the nuclear compressibility K and the effective nucleon-nucleon cross section σ within a reasonable range. We have found that the preferred value of m^* is about 0.85 m. With this value of m^*, from the in-plane mean transverse momentum P_x(Y) which is sensitive to both m^* and σ we have drawn an effective nn cross section σ, namely σ 0.8σ_f where σ_f is the free nucleon-nucleon cross section in Cugnon's parametrization. Taking advantage of the fact that the energy of vanishing flow (EVF) at intermediate energy (around 100 MeV/u) is only sensitive to the nucleon-nucleon cross section σ, we have drawn some information on the nucleon-nucleon cross section σ, namely σ = (1.4±0.2)σ_f.     

声速测量实验中压电接收端的声压随位置变化的规律

本文介绍了我们所研究的共振干涉接收端声压振幅方程以及用微机解此方程的数学计算方法。     

甘肃甘南蕨麻中矿物元素含量的测定

用浓硝酸-高氯酸混合酸对蕨麻样品进行消化,采用空气-乙炔火焰原子吸收光谱法测定了样品中矿物元素含量。结果表明,蕨麻中Fe、Mg含量较高,还含有Zn、Cu、Mn、Co等人体必需微量元素,有较高营养价值,测定结果的相对标准偏差在1．738％-17．372％之间。     

Styrene butadiene rubber/carbon black composites modified by imidazole derivatives

In this study, the imidazole derivatives such as 2-undecylimidazole (UI) and 2-mercapto-1-methylimidazole (MMI) are utilized to work as novel additives for modifying styrene butadiene rubber (SBR)/carbon black (CB) composites. The imidazole groups on UI and MMI can be hydrogen-bonded with oxygen-containing groups on the surface of CB, and the undecyl or thiol groups can be reacted with the SBR chains via physical entanglement or thiol-ene chemistry. The results demonstrate that the static and dynamic mechanical performances of SBR/UI and SBR/MMI composites are significantly improved over those of the SBR composite. Compared with blank SBR composite, the tensile strength, modulus at 300% elongation, and tear strength of SBR/MMI-1.0 are greatly improved by 30, 42, and 18%, respectively. The rolling resistance of SBR/MMI-1.0 is reduced by 10.4%, and the wet grip property is increased by 4.0%. The superiority of appropriate MMI content (1.0 phr in our work) in the enhancement for the overall performance of SBR composites is attributed to the promotion of a good dispersion of CB throughout the SBR matrix and the enhanced interfacial interactions between CB and the SBR matrix. This work may enlarge the potential applications of modified CB to fabricate high-performance rubber composites.     

Theoretical studies on molecular and structures of mono- and binuclear chromium carbazole derivatives for optoelectronics

Studies on the molecular geometries, electronic properties and second-order nonlinearities of a series of mono- and binuclear chromium carbazole complexes: (N-vinylcarbazole)Cr(CO)(3) (M1), (N-vinylcarbazole)Cr(CO)(2)PPh(3) (M2), (CO)(3)Cr(N-vinylcarbazole)Cr(CO)(3) (B1), and (CO)(3)Cr(N-vinylcarbazole)Cr(CO)(2)PPh(3) (B2) were carried out, using the density functional theory (DFT) at the B3LYP//LanL2DZ/6-31G(d) level. The experimental singlet metal-to-ligand charge transfer ((1)MLCT) spectra of these complexes can also be well simulated and discussed by the time-dependent DFT (TDDFT) at the B3LYP//LanL2DZ/6-311+G(d) level associated with the polarizable continuum model (PCM). The computational results show that an unusual characteristic of chromium carbazole structures is explained in terms of interaction between frontier molecular orbitals of the metal and its ligands. The highest occupied molecular orbitals (HOMOs) of these complexes are composed of a set of distorted degenerated Cr 3d orbitals, whereas the lowest unoccupied molecular orbitals (LUMOs) are predominantly the N-vinylcarbazole ligand π* orbitals. The HOMO-LUMO energy gaps decrease in the order NVC > M1 > B1 > M2 > B2. The considerable coupling between the carbazole and (CO)(3) in M1 creates an asymmetric environment about the chromium atom, leading to modest second-order responses. The PPh(3) ligand is acting as a donor which increases the donating strength of the d(π) orbitals in chromium carbazole species, resulting in the large electronic asymmetry in M2. As for the binuclear chromium carbazole chromophores, a wide-range (1)MLCT band and large oscillator strength are found, allowing for the electronic interactions between two metal centers which can be modified by altering the ligand bound to the metals to induce peculiar asymmetry. Essentially, Cr(CO)(3) acceptor and Cr(CO)(2)PPh(3) donor units in B2 make significant contribution to the charge-transfer process or NLO responses via conventional push-pull chromophoric architecture.     

Synthesis of 2(5H)‐Furanone Derivatives with Bis‐1,2,3‐triazole Structure

A series of new chiral 2(5H)‐furanone derivatives containing bis‐1,2,3‐triazole moiety were designed and synthesized from (5S)‐5‐alkoxy‐3,4‐dihalo‐2(5H)‐furanones 1 , dicarboxyl amino acids 2 , propargyl bromide, and organic azides 5 under mild conditions via the sequential three steps, including asymmetric Michael addition‐elimination, substitution and no‐ligand click reaction. Twelve new intermediates, including N‐[5‐alkoxy‐2(5H)‐furanonyl] dicarboxyl amino acids 3 and their corresponding propargyl esters 4 , and twelve target molecules 6 were characterized by FTIR, ¹H NMR, ¹³C NMR, MS and elemental analysis. The influences of different synthetic conditions and substrates in each step were investigated. The research provides a new method and idea for the synthesis of 2(5H)‐furanone compounds with polyheterocyclic structure due to the diversities of four basic unit molecules.     

环形薄板二维驻波的研究

在理论上和实验上对环形薄板二维驻波波节图形(克拉尼图形) 进行了研究. 通过在极坐标下对垂直板面方向小振动方程进行分离变量, 求解出环形薄板小振动方程在外边界悬空时分别在两种内边界条件, 即内边界悬空和内边界简支下的解析解的简正模式, 并计算了在第一种边条件下几种共振模式的径向波速近似值, 以及两种边条件下的圆形驻波波节线的半径和薄板的弹性模量. 发现通过调节环形薄板上点振动源的频率, 可精确控制薄板上出现的克拉尼图形. 实验上观察到了仅有圆形波节线, 仅有辐射状波节线, 以及两种波节线同时存在3 种简正模式的情形, 且波节线的数量可严格控制. 理论结果跟实验符合得很好.      

磷酸特地唑胺的合成新方法

以(5R)-3-(4-溴-3-氟苯基)-5-羟甲基噁唑烷-2-酮为起始原料,在[PdCl₂(dppf)]·CH₂Cl₂催化下与联硼酸频那醇酯反应得到硼化物,继而与5-溴-2-(2-甲基-2H-四唑-5-基)吡啶进行Suzuki反应得到特地唑胺,收率82.9%。 分别考察了催化体系对硼化反应和Suzuki反应的影响,确定了较佳的反应条件。 特地唑胺与二苄基N,N-二异丙基亚磷酰胺反应得到二苄基保护的磷酸特地唑胺,随后经Pd/C脱苄得到磷酸特地唑胺,总收率66.2%。     

激光烧蚀金属靶时气体电离分析

我们使用Ｎｄ：ＹＡＧ激光器烧蚀金属Ａｌ靶获得等离子体,利用光谱时－空分辨技术,关于环境气体分解及其对等离子体辐射特征的影响进行了研究。使用的气体是Ａｒ,Ａｉｒ,Ｎ２。结果发现,在等离子体形成初期,等离子体时－空分辨谱中有大量的环境气体离子谱线。基于Ａｌ等离子体不同激光能量下的时间－空间分辨谱。对激光烧蚀金属靶时气体电离现象进行了分析,对气体分解造成的影响进行了简单的讨论。