二氧化钛悬浆体系中八种染料的太阳光催化氧化降解

研究了二氧化钛悬浆体系中具有不同结构和不同取代基的八种染料化合物在太阳光作用下的降解过程。实验中测定了染料溶液的脱色速度、总有机碳去除率以及降解过程中部分无机离子的生成情况。结果显示,在此条件下,八种染料化合物均得到不同程度的降解。着重比较了染料分子在光催化降解过程中,不同取代基以及取代基的不同位置对染料分子降解及无机离子生成情况的影响,从而进一步揭示了染料分子的光催化降解机理。     

蒙旦树脂烃化学组成及结构特征

本文对中国三种蒙旦树脂烃潦浒树脂烃（ＬＨＴ）,寻甸树脂烃（ＸＤＴ）,舒兰树脂烃（ＳＬＴ）进行了ＧＣＭＳ分析,获取了树脂烃中单元化合物的组成和结构。结果表明,在这三种树脂烃中,主要是五环三萜烃类五环三萜烷,五环三萜烯,单环、二环、三环、四环芳构化五环三萜烷以及三环二萜烃类降松脂烷,降松香烷,降海松烷,松香烷,山达松脂烷,单环、二环芳构化三环萜烷。比较三种树脂的总离子色谱图,发现在寻甸蒙旦树脂烃和舒兰树脂烃中,五环二萜的各种化合物是该组分主要化学组成,尤其在舒兰蒙旦树脂烃中,具有四环芳构化的萜烷其含量占绝对优势。潦浒蒙旦树脂烃中,三环二萜的各种物质是其重要的化学组成。与此同时,阐述了中国蒙旦蜡精制漂白脱色不完全的原因。     

微波强化光催化氧化技术研究现状及展望

综述了微波强化光催化氧化的处理效果和机理,并对催化剂投量、光源、溶解氧、温度等相关因素对处理效果的影响进行了详细阐述.最后对微波强化光催化的应用前景进行了展望.     

One‐Step Solvothermal Synthesis of Single‐Crystalline TiOF2 Nanotubes with High Lithium‐Ion Battery Performance

Single‐crystalline TiOF₂ nanotubes were prepared by a one‐step solvothermal method. The nanotubes are rectangular in shape with a length of 2–3 μm, width of 200–300 nm, and wall thickness of 40–60 nm. The formation of TiOF₂ nanotubes is directly driven by the interaction between TiF₄ and oleic acid in octadecane to form the 1D nanorods, and this is followed by a mass diffusion process to form the hollow structures. The synthesis approach can be extended to grow TiOF₂ nanoparticles and nanorods. Compared with TiO₂, which is the more commonly considered anode material in lithium‐ion batteries, TiOF₂ has the advantages of a lower Li‐intercalation voltage (e.g., to help increase the total voltage of the battery cell) and higher specific capacities. The TiOF₂ nanotubes showed good Li‐storage properties with high specific capacities, stable cyclabilities, and good rate capabilities.     

Fast Alkene Functionalization In Vivo by Photoclick Chemistry: HOMO Lifting of Nitrile Imine Dipoles

Extremely fast fluorescence labeling (<1 min) of a recombinant alkene‐encoded protein in living Escherichia coli cells was observed with tetrazole 1 . The electron‐donating methoxy substituent raises the energy of the highest occupied molecular orbital of the nitrile–imine intermediate derived from 1 . This strategy greatly accelerates the functionalization of alkenes by 1,3‐dipolar cycloaddition in living systems.

     

Enhanced oxidase-like activity of g-C3N4 nanosheets supported Pd nanosheets for ratiometric fluorescence detection of acetylcholinesterase activity and its inhibitor

The undesirable enzymatic activity of nanozymes under near neutral p H condition and the traditional single signal output always restrict the analytical application of nanozyme-based biosensors.Herein,graphitic carbon nitride nanosheets supported palladium nanosheets composite （Pd/g-C₃N₄） with both oxidase-like activity and fluorescent property is synthesized.Notably,Pd/g-C₃N₄exhibits enhanced oxidase-like activity compared to Pd NSs under p H 7.4.By c...     

Cyclocondensation of amino-propargyl silanes

Amino-propargyl silanes condense with carbonyl compounds to form imines and subsequently cyclize to form allenylidene tetrahydroquinolines. The cyclocondensations are catalyzed by a variety of Br?nsted acids, among which phosphoric acids provide the highest yields. Subsequent intramolecular and intermolecular additions to the allene moiety provide complex polycyclic amines.     

红外导引头高速流场及其对光线传输影响的数值模拟

研究红外光线经过高速流场时由于折射产生的瞄视误差(BSE),对于红外末制导拦截弹的命中精度有重要意义。考虑高温真实气体效应,求解热化学非平衡Navier-Stokes(N-S)方程得到导引头的流场,采用光线追迹的方法,对红外光线经过流场后到达导引头光学窗口的瞄视误差进行了计算分析,研究了光线入射角、飞行马赫数、攻角、高度及红外导引头外形对瞄视误差的影响。     

An Integral Algorithm for Numerical Integration of One-Dimensional Additive Colored Noise Problems

We present an integral-closed algorithm for solving a Langevin equation driven by an additive colored noise. Both the mean first passage time in a bistable system and the diffusion current in a titled periodic potential are calculated and the comparison with existing algorithms is carried out. The dependence of the numerical results on the time steps is studied. Our algorithm is shown to have high accuracy and stability.     

序列脉冲倍频YAG激光器泵浦的氧气受激拉曼散射研究

对序列脉冲倍频ＹＡＧ激光器泵浦的氧气受激拉曼散射进行了研究。对氧气的受激拉曼散射池的热传导过程进行了数值模拟计算，实验研究了序列脉冲倍频ＹＡＧ激光器泵浦情况下氧气受激拉曼散射的热效应问题。