Metal-free catalytic enantioselective silylation of aromatic aldehydes in water

One-step access to chiral α-hydroxysilanes by metal-free catalytic enantioselective silylation of aromatic aldehydes in water was achieved for the first time.     

Cauchy Problem to a Type of Second Order Differential-iterative Equation

Abstract The paper studies the behavior and existence of strong solutions to the second or-der functional-iterative differential equation     

Double Diffractive Process Factorization from ηc and γ Associated Production at Tevatron and LHC

We present a study of associated ηc and γ double diffractive production in p-p collision based on Ingelman-Schlein model, and the framework of non-relativistic QCD factorization formalism for quarkonia production. The predic-tion of ηc and γ is more reliable than J/ψ production, because the associated ηc and γ production is a pure color-octetprocess, and the dominant contribution comes from color octet 1So(8) subprocess, which is related to the color octet matrixelement of 1So(8) of J/ψ by the heavy quark spin symmetry and the large PT J/ψ production data. We find that the ratioof diffractive to inclusive cross sections is independent of the values of color octet matrix elements, but is sensitive to thegluon factor of the Pomeron and renormalized Pomeron flux factors. So experimental measurement of this ratio can giveus more information of the nature of Pomeron and test the assumption of hard diffractive factorization in hadron-hadron collisions.     

Effect of Mo content in MoO3/g-Al2O3 on the catalytic activity for transesterification of dimethyl oxalate with phenol

The influence of molybdenum content on the catalytic performance in the transesterification of dimethyl oxalate (DMO) with phenol to methyl phenyl oxalate (MPO) and diphenyl oxalate (DPO) was investigated. The results indicated that the MoO₃/Al₂O₃ catalyst with 14 wt% Mo content gave maximal DPO yield with 6.1% and 75.1% DMO conversion. The component, structure and phase of MoO₃/Al₂O₃ catalysts were characterized by means of X-ray diffraction (XRD), BET specific surface area, temperature-programmed desorption of ammonia (NH₃-TPD), and FTIR analysis of adsorbed pyridine. This revised version was published online in June 2006 with corrections to the Cover Date.     

石墨炉原子吸收测定土壤中的Cd Pb

摘要：为了提升石墨炉原子吸收测定土壤样品中Cd和Pb的准确度和测试效率,对样品前处理和仪器测试等条件进行优化选择,确定了低温电热板消解样品时,硝酸、氢氟酸、高氯酸的三酸比例和复溶方式以及采用海光GGX-920型石墨炉原子吸收测定Cd和Pb的升温程序、样品和基体改进剂加入量等条件。应用选定方法条件分别对土壤标准物质GBW07403、GBW07449水系沉积物 GBW07309进行6次测定,测定值Cd的相对标准偏差RSD：2.49%~4.67%,相对误差RE：-2.31% ~ 2.22%,测定值Pb的相对标准偏差RSD：1.98%~ 2.54%,相对误差RE：-1.88% ~ 2.11%。此方法精密度和准确度均达到标准要求,是一种准确而快速的检测方法,适合大批量的环境样品检测。     

Enhanced stability of ZnTPPS by polymeric gold nanoparticles in acidic aqueous solutions

Novel kind of core-shell corona complex micelles were prepared, which enhanced both the hydrolytic stability and the photostability of water-soluble zinc tetrakis(4-sulfonatophenyl) porphyrin (ZnTPPS) in acidic aqueous solutions. The core-shell gold nanoparticles (AuNPS) were synthesized by reducing HAuCl₄ and di-thioester terminated block copolymer, poly(Nisopropylacrylamide)-block-poly(4-vinylpyridine) (PNIPAM-b-P4VP). The complex micelles with gold core, P4VP/ZnTPPS shell and PNIPAM corona were formed by simple mixing of gold nanoparticles and ZnTPPS. The photochemical properties of the complex micelles were studied by UV–Visiblespectroscopy and fluorescence spectroscopy. The results showed trapping of ZnTPPS in the positively charged micellar shell that effectively prevented demetallation of the ZnTPPS that would occur in acidic aqueous solutions. Furthermore, with appropriate concentration of gold nanoparticles, ZnTPPS in the complex micelle had excellent photostability by suppression of generation of reactive oxygen species (ROS). The enhanced stability of ZnTPPS in acidic aqueous media could be extensively used for photocatalysis and in solar cells.     

高职院校有机化学课程过程性评价方法探究

针对高职院校目前有机化学课程中过程性评价方法存在的问题,初步探索了由单元知识结构图、创新型作业、期中考试和日常考勤四部分组成的过程性评价方法。实践证明,该评价方案在客观地反映学生平时学习情况的同时,能很好地激励学生自主学习,提升学习效果,促进师生共同进步。     

分数阶微分方程多点边值问题的正解

本文研究了在边界条件中含有多个分数导数项的分数阶微分方程多点边值问题多个正解的存在性.运用Green函数的性质以及有白-葛推导出的一般形式的Leggett-Williams不动点定理,建立了边值问题至少有三个正解存在的充分条件.最后,给出了一个例子,用于说明所得主要结论具有广泛的适用性.     

热聚合法制备纳米级Li3V2(PO4)3/C作为锂离子电池正极材料的性能研究

通过热聚合法成功制备出纳米级Li₃V₂（PO₄）₃/C正极材料,中间产物和最终材料的Li₃V₂（PO₄）₃/C颗粒均小于200 nm,无定形碳的含量为4.6%,处于Li₃V₂（PO₄）₃颗粒表面和颗粒与颗粒之间.该材料在3.0sim4.3 V和0.1 C电流下放电比容量为124 mAh/g,100次循环之后无衰减,表现出较好的循环性能.其倍率性能优异,在3.0sim4.3 V和20 C的条件下放电比容量达到80 mAh/g,在3.0sim4.8 V和10 C的条件下放电比容量达到100 mAh/g.     

Synthesis and Characteristics of Electrodeposited CoxZn1-x Nanorods

CoxZn1-x nanorod arrays were fabricated by electrodeposition in porous anodic aluminum oxide templates at different electric potentials. X-ray diffraction and transmission electron microscopy indicate that highly-ordered and uniform nanorods have been fabricated. The amounts of Co and Zn contents are investigated using energy dispersive spectroscopy, which demonstrates that the atom ratio of the alloy nanorods changes with the deposition potential. In addition, magnetic measurements show that the magnetic isotropy Co-rich CoZn nanorods will change to magnetic anisotropy nanorods with the easy axis parallel to the rod long axis with decreasing Co content.